US2267343A - Electric discharge lamp - Google Patents

Electric discharge lamp Download PDF

Info

Publication number
US2267343A
US2267343A US209620A US20962038A US2267343A US 2267343 A US2267343 A US 2267343A US 209620 A US209620 A US 209620A US 20962038 A US20962038 A US 20962038A US 2267343 A US2267343 A US 2267343A
Authority
US
United States
Prior art keywords
tube
silver
electric discharge
coating
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US209620A
Inventor
William J Scott
Christopher J Milner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Application granted granted Critical
Publication of US2267343A publication Critical patent/US2267343A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • C23C14/046Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation

Definitions

  • This invention relates to. electric discharge lamps and more particularly to lamps of the cadmium or zinc type described in co-pending application Serial Number 190,842, filed February 16, 1938, and assignedto the assignee of the present application.
  • the lamp described in the co-, pending application is surrounded by a glass tube having thereon a thin coating of silver transparent inthe case of cadmium 'to 3,260 A and in the case of aim to 3,078 A radiations.
  • This coating must be uniform in thickness (approximately 0.01 micron) so that it will reflect heat radiation strongly'and also transmit the aboveultra violet radiations with little absorption.
  • a wire or tube consisting of silver is mounted along the axis of a (larger) evacuated glass tube, and heated to about 900 C. by a definite power input, for example by an electric current, silver evaporates and condenses as a film on the inner surface of the glass.
  • This film reflects back the heat radiated by the silver wire or tube, and raises its temperature, thus increasing the'evaporation.
  • the process is thus unstable; if one pat of the silver is initially hotter than the rest, silver will deposit first on the glass around this hotter part, the reflected heat will raise the temperature of this part, and the evaporation will be more, rapid from this part than from other parts. Since perfect uniformity of temperature in the silver vapor source cannot be attained, uniformity of the film over the wholetube or bulb is equally unobtainable.
  • the present invention avoids this difliculty by using,- instead of solid silver as the heated source of silver vapor; a tube or wire of metal which is non-volatile at the volatilizing temperature of silver, for example nickel, in whichthe heating current flows.
  • This tube or wire is previously electroplated uniformly, by known methods, with a quantity of silver just sufficient to coat the glass tube or bulb to the desired thickness. If.
  • this silver-plated nickel source is then used for the evaporation, it becomes immaterial. that the film forms first on -one part of theglassz, for
  • FIG. 1 illustrates. in a front elevational, partly sectional view one form of apparatus for carrying out the invention, suitable for preparing thin silver films on tubular vitreous jackets, for usein cadmium and zinc lamps, for example.
  • a nickel tube I plated on the outside with silver to the desired extent, is heated by a tungsten filament 2 within the tube, insulated from it by a quartz or steatite tube 3.
  • the nickel tube itself forms the return lead from the filament, being con- I nected to it at the top by a bridging wire 4.
  • An apparatus for producing a metal coating of uniform thickness on a hollow body comprising in combination a chamber adapted to be eX- hausted in which said body is mounted and a coating article mounted in said body, said article comprising a tube of insulating material, an electrical heater element in said tube, a metal tube surrounding said insulating tube, said heater element being electrically connected to said metal tube, a coating uniform on said metal tube, said coating consisting of the metal to be deposited on said hollow body, the quantity of metal in said coating in relation to the area of the surface of said hollow body to be coated being restricted to an'amount such that said surface has a'uniform' coating of desired thick ness thereon when said coating metal is all evaporated from said metal tube, the metal of said tube having a higher volatilizing temperature than the metal of said coating, a pair of current said chamber for connection with the terminals. of a current source.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Description

Dec. 23, 1941.
w. J. SCQTTY Er AL ELECTRIC DISCHARGE LAMl Filed May 23, 1938 Inventors: William J. Scott, Christopher J. Milner,
Then Attorney.
'ciently uniform to give the desired effects. .alternative method of vacuum evaporation from.
. Patented Dec. 23, 1941 UNITED STATES PATENT OFFICE ELECTRIC DISCHARGE LAMP William J. Scott and Christopher J. Mahler, Rugby, England, assignors to General Electric Company, a corporation of New York Application May 23, 1938, Serial No. 209,620 In Great Britain May 31, 1937 (c1. sip-12.2)
1 Claim.
This invention relates to. electric discharge lamps and more particularly to lamps of the cadmium or zinc type described in co-pending application Serial Number 190,842, filed February 16, 1938, and assignedto the assignee of the present application. The lamp described in the co-, pending application is surrounded by a glass tube having thereon a thin coating of silver transparent inthe case of cadmium 'to 3,260 A and in the case of aim to 3,078 A radiations. This coating must be uniform in thickness (approximately 0.01 micron) so that it will reflect heat radiation strongly'and also transmit the aboveultra violet radiations with little absorption.
- We have observed that such a uniform film cannot be prepared by chemical deposition, which is the method commonly employed forthick films. It appears that the particles of silver deposited in this way are too large, and the film is insufli- The solid silver is well known, but cannot be easily applied to the coating of a large surface, such as the inside of a tube or bulb. The following effect takes place, which it is the object of thepresent invention to avoid.
If a wire or tube consisting of silver is mounted along the axis of a (larger) evacuated glass tube, and heated to about 900 C. by a definite power input, for example by an electric current, silver evaporates and condenses as a film on the inner surface of the glass. This film reflects back the heat radiated by the silver wire or tube, and raises its temperature, thus increasing the'evaporation. The process is thus unstable; if one pat of the silver is initially hotter than the rest, silver will deposit first on the glass around this hotter part, the reflected heat will raise the temperature of this part, and the evaporation will be more, rapid from this part than from other parts. Since perfect uniformity of temperature in the silver vapor source cannot be attained, uniformity of the film over the wholetube or bulb is equally unobtainable.
The present invention avoids this difliculty by using,- instead of solid silver as the heated source of silver vapor; a tube or wire of metal which is non-volatile at the volatilizing temperature of silver, for example nickel, in whichthe heating current flows. This tube or wire is previously electroplated uniformly, by known methods, with a quantity of silver just sufficient to coat the glass tube or bulb to the desired thickness. If.
this silver-plated nickel source is then used for the evaporation, it becomes immaterial. that the film forms first on -one part of theglassz, for
when the silver on that part of the source has been volatilized, no further evaporation can take place to that part of the glass; and the temperature can be maintained so that the silver is evaporated from the remaining parts of the source The accompanying drawing illustrates. in a front elevational, partly sectional view one form of apparatus for carrying out the invention, suitable for preparing thin silver films on tubular vitreous jackets, for usein cadmium and zinc lamps, for example. In the drawing a nickel tube I, plated on the outside with silver to the desired extent, is heated by a tungsten filament 2 within the tube, insulated from it by a quartz or steatite tube 3. The nickel tube itself forms the return lead from the filament, being con- I nected to it at the top by a bridging wire 4.
Power is supplied through leads 5, 5 sealed by air tight joints through the metal baseplate 6. Onthis rests a bell-jar fl, sealed to it by vacuum plasticine 8, and, within thelatter, the
jacket 9 to be coated with silver. "The whole can be exhausted during evaporation by a pump connected to the tube Ill.
What we claim as new and desire to secure by Letters'Patent of the United States is:
An apparatus for producing a metal coating of uniform thickness on a hollow body comprising in combination a chamber adapted to be eX- hausted in which said body is mounted and a coating article mounted in said body, said article comprising a tube of insulating material, an electrical heater element in said tube, a metal tube surrounding said insulating tube, said heater element being electrically connected to said metal tube, a coating uniform on said metal tube, said coating consisting of the metal to be deposited on said hollow body, the quantity of metal in said coating in relation to the area of the surface of said hollow body to be coated being restricted to an'amount such that said surface has a'uniform' coating of desired thick ness thereon when said coating metal is all evaporated from said metal tube, the metal of said tube having a higher volatilizing temperature than the metal of said coating, a pair of current said chamber for connection with the terminals. of a current source.
,L sco'rr. cmrs'rornnn J. manna.
US209620A 1937-05-31 1938-05-23 Electric discharge lamp Expired - Lifetime US2267343A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2267343X 1937-05-31

Publications (1)

Publication Number Publication Date
US2267343A true US2267343A (en) 1941-12-23

Family

ID=10902640

Family Applications (1)

Application Number Title Priority Date Filing Date
US209620A Expired - Lifetime US2267343A (en) 1937-05-31 1938-05-23 Electric discharge lamp

Country Status (1)

Country Link
US (1) US2267343A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2976174A (en) * 1955-03-22 1961-03-21 Burroughs Corp Oriented magnetic cores
US3024761A (en) * 1958-07-01 1962-03-13 Ibm Vacuum evaporation apparatus
US3074811A (en) * 1957-04-22 1963-01-22 Radiation Res Corp Method for preparing sources of ionizing radiation
US3804059A (en) * 1971-01-22 1974-04-16 Cockerill Ougree Providence Es Device for the application of a metal coating on the internal cylindrical surface of a hollow body
US4759719A (en) * 1986-09-22 1988-07-26 Levenson Michael K Teaching device for the demonstration of scientific principles

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2976174A (en) * 1955-03-22 1961-03-21 Burroughs Corp Oriented magnetic cores
US3074811A (en) * 1957-04-22 1963-01-22 Radiation Res Corp Method for preparing sources of ionizing radiation
US3024761A (en) * 1958-07-01 1962-03-13 Ibm Vacuum evaporation apparatus
US3804059A (en) * 1971-01-22 1974-04-16 Cockerill Ougree Providence Es Device for the application of a metal coating on the internal cylindrical surface of a hollow body
US4759719A (en) * 1986-09-22 1988-07-26 Levenson Michael K Teaching device for the demonstration of scientific principles

Similar Documents

Publication Publication Date Title
US2161458A (en) Luminescent screen
US2732313A (en) Titanium
US2724663A (en) Plural metal vapor coating
US2267343A (en) Electric discharge lamp
US2948635A (en) Phosphor evaporation method and apparatus
US3130073A (en) Method of providing molybdenum wire with a carbon coating
US2844868A (en) Method of joining refractory metals
US2413731A (en) Manufacture of electron discharge devices
US2659678A (en) Transparent luminescent screen and method for preparing same
US2553289A (en) Method for depositing thin films
US1675120A (en) Deposition of thorium from its vaporizable compounds
US2723919A (en) Photochemical mirroring process
US2918595A (en) Coating composition for electric lamps
US2936246A (en) Burn-resistant phosphors and the method of preparation thereof
US3666533A (en) Deposition of polymeric coatings utilizing electrical excitation
US1841034A (en) Electrooptical apparatus
US4066819A (en) Method of bonding gold films to non-electrically conducting oxides and product thereby obtained
US2842463A (en) Vapor deposited metal films
US2996402A (en) Method for making zinc sulfide luminescent screens
US2733115A (en) Apparatus for evaporating chemicals
US2818355A (en) Method of producing a conductive layer of graphite on an insulating substratum
US2812411A (en) Means for vapor deposition of metals
US2744808A (en) Apparatus for evaporating chemicals
US3703456A (en) Method of making resistor thin films by reactive sputtering from a composite source
US1568694A (en) Photo-electric device