GB790634A - Improvements in or relating to the curing of glycidyl ethers and the resulting curedproducts - Google Patents

Improvements in or relating to the curing of glycidyl ethers and the resulting curedproducts

Info

Publication number
GB790634A
GB790634A GB1064/55A GB106455A GB790634A GB 790634 A GB790634 A GB 790634A GB 1064/55 A GB1064/55 A GB 1064/55A GB 106455 A GB106455 A GB 106455A GB 790634 A GB790634 A GB 790634A
Authority
GB
United Kingdom
Prior art keywords
groups
parts
phenolic
glycidyl ether
addition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1064/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB790634A publication Critical patent/GB790634A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/66—Mercaptans
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

Glycidyl ethers soluble in organic solvents which can be cured at room temperatures to give resinous products having improved resistance to corrosion &c. when used as coating compositions are obtained by reacting the glycidyl ether at above 50 DEG C. with an organic compound having at least three active hydrogen atoms which are attached to the nitrogen atoms of an aromatic diamine or which are present in the form of alcoholic or phenolic hydroxyl groups of a phenol-aldehyde resin having at least three phenolic OH groups in the molecule or 2 phenolic hydroxyl groups and in addition at least one methylol group. The reaction is maintained until the viscosity is constant and the soluble product is cured by addition of the usual aliphatic polyamine curing agents, e.g. ethylene diamine, diethylene triamine or the adduct thereof with a glycidyl ether; reduced quantities of curing agent are required as compared with glycidyl ethers which have not been subjected to the solubilizing treatment. In examples 2 parts m-phenylenediamine were added to 100 parts of a glycidyl ether dissolved in toluene and the solution heated to 120-125 DEG C. for 2 hours. After cooling the solution was diluted with a mixture of equal parts of methyl isobutyl ketone cellosolve and toluene and after the addition of 1.5 parts ethylene diamine per 100 parts reaction product was sprayed on to steel panels; the film obtained after hardening for a week at 23 DEG C. was found to have a pencil hardness of 4H. In Example 2 a phenol-formaldehyde resin having an average per mol. of 6 phenolic OH groups, 4.2 CH2OH groups and 1.8 DH2OC4H9 groups was used as the solubilizing agent. Specification 691,543 is referred to.
GB1064/55A 1954-01-15 1955-01-13 Improvements in or relating to the curing of glycidyl ethers and the resulting curedproducts Expired GB790634A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL342372X 1954-01-15

Publications (1)

Publication Number Publication Date
GB790634A true GB790634A (en) 1958-02-12

Family

ID=19784755

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1064/55A Expired GB790634A (en) 1954-01-15 1955-01-13 Improvements in or relating to the curing of glycidyl ethers and the resulting curedproducts

Country Status (6)

Country Link
BE (1) BE534833A (en)
CH (1) CH342372A (en)
DE (1) DE1024708B (en)
FR (1) FR1117822A (en)
GB (1) GB790634A (en)
NL (2) NL87346C (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL219578A (en) * 1956-08-03 1900-01-01

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE445580A (en) * 1941-05-20
US2589245A (en) * 1945-12-03 1952-03-18 Devoe & Raynolds Co Amide-epoxide compositions, etc.
BE510201A (en) * 1949-10-25 1900-01-01
BE530703A (en) * 1953-07-29
FR96044E (en) * 1967-10-26 1972-05-19

Also Published As

Publication number Publication date
NL184358B (en)
DE1024708B (en) 1958-02-20
CH342372A (en) 1959-11-15
NL87346C (en)
FR1117822A (en) 1956-05-28
BE534833A (en)

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