GB777545A - Improvements in or relating to resinous composition - Google Patents
Improvements in or relating to resinous compositionInfo
- Publication number
- GB777545A GB777545A GB26551/55A GB2655155A GB777545A GB 777545 A GB777545 A GB 777545A GB 26551/55 A GB26551/55 A GB 26551/55A GB 2655155 A GB2655155 A GB 2655155A GB 777545 A GB777545 A GB 777545A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- allyl
- ketone
- polymers
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
Abstract
Polymers of compounds of the form: <FORM:0777545/IV(a)/1> where R is halogen or a methyl or ethyl radical and n is an integer from 0 to 2 are plasticized by 0.2 to 4.0 per cent of a 1,1-diarylethane containing 1 or 2 methyl or ethyl nuclear substituents. Specified plasticizers are 1,1-ditolylethane, 1,1-dixylylethane and 1,1-bis-(ethylbenzene) ethane. The polymers may be of styrene, chlorostyrene, bromostyrene, dichlorostyrene, di-iodostyrene, methylstyrene, ethylstyrene, dimethylstyrene and diethylstyrene, and may contain acrylonitrile, methacrylonitrile, ethacrylonitrile, acrylamide, methacrylamide, ethacrylamide, vinyl formate, vinyl acetate, vinyl chloroacetate, vinyl propionate, vinyl bromopropionate, vinyl stearate, allyl acetate, allyl propionate, allyl chloroacetate, allyl benzoyl benzoate, methallyl acetate, allyl laurate, diallyl phthalate, diallyl succinate, diallyl maleate, methyl isopropenyl ketone, ethylvinyl ketone, propylvinyl ketone, phenylvinyl ketone, vinyl chloride and vinyl bromide. The plasticizers may be added to the monomers before bulk polymerization in one or more stages, e.g. at 100 DEG and 130 DEG C., in the presence of catalysts, e.g. hydrogen peroxide, benzoyl peroxide and tertiary butyl hydroperoxide, and modifiers, e.g. decyl mercaptan. Dyes, pigments and other additives may be present. The polymers may be cast or moulded.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US777545XA | 1954-10-11 | 1954-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB777545A true GB777545A (en) | 1957-06-26 |
Family
ID=22139869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB26551/55A Expired GB777545A (en) | 1954-10-11 | 1955-09-16 | Improvements in or relating to resinous composition |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1018621B (en) |
FR (1) | FR1138825A (en) |
GB (1) | GB777545A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5489646A (en) * | 1994-01-10 | 1996-02-06 | Koch Industries, Inc. | Lower alkyl biphenyls as plasticizers |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3156741A (en) * | 1959-01-12 | 1964-11-10 | L I R C Lab Italiani Di Ricerc | Copolymers of styrene, dimethyl itaconate and acrylonitrile and a process for their manufacture |
NL126038C (en) * | 1960-12-19 | |||
NL272376A (en) * | 1960-12-19 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2273822A (en) * | 1937-05-18 | 1942-02-24 | Union Carbide & Carbon Corp | Treatment of polystyrene |
NL72222C (en) * | 1950-07-15 |
-
1955
- 1955-09-16 GB GB26551/55A patent/GB777545A/en not_active Expired
- 1955-10-04 DE DEA23513A patent/DE1018621B/en active Pending
- 1955-10-06 FR FR1138825D patent/FR1138825A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5489646A (en) * | 1994-01-10 | 1996-02-06 | Koch Industries, Inc. | Lower alkyl biphenyls as plasticizers |
US5696184A (en) * | 1994-01-10 | 1997-12-09 | Koch Industries, Inc. | Lower alkyl biphenyls as plasticizers |
US5847040A (en) * | 1994-01-10 | 1998-12-08 | Koch Industries, Inc. | Lower alkyl biphenyls as plasticizers for polyurethane |
Also Published As
Publication number | Publication date |
---|---|
DE1018621B (en) | 1957-10-31 |
FR1138825A (en) | 1957-06-20 |
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