GB777200A - Direct-dyeing trisazo-dyestuffs of the diphenyl series and process for their manufacture - Google Patents
Direct-dyeing trisazo-dyestuffs of the diphenyl series and process for their manufactureInfo
- Publication number
- GB777200A GB777200A GB30548/55A GB3054855A GB777200A GB 777200 A GB777200 A GB 777200A GB 30548/55 A GB30548/55 A GB 30548/55A GB 3054855 A GB3054855 A GB 3054855A GB 777200 A GB777200 A GB 777200A
- Authority
- GB
- United Kingdom
- Prior art keywords
- groups
- phenyl
- methyl
- acid
- diphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/36—Trisazo dyes of the type
- C09B35/366—D is diphenyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises dyestuffs of formula <FORM:0777200/IV(b)/1> where R1 is a 4,41- diphenyl residue containing 3,31- substituents which with the OH groups present in the adjacent residues in position vicinal to the azo groups are capable of forming metal complexes, R2 is a residue of a coupling component bound to the azo group through a ketomethylene group R3 is a residue of the benzene series which contains a sulphonic acid group and of which the carbon atoms bound to the NH group and the -N=N-group are separated from one another by at least two carbon atoms, and R4 is a residue of an 8 - oxyquinoline. They are made by coupling an 8 - oxyquinoline, advantageously in an alkaline medium with the addition of an organic base such as pyridine or picoline, with a diazo-compound of an appropriate amino-disazo dyestuff which has preferably been diazotized by the indirect method. The amino-disazo dyestuff is made by coupling tetrazotized diphenyl compounds with appropriate keto-methylene and J-acid components, optionally in the presence of alcohol or pyridine. Preferably the 3,31- diphenyl substituents are capable of forming stable metal complexes directly with the necessary hydroxy groups e.g. carboxymethoxy, carboxy and hydroxy, substituents the latter being preferred. Specified keto-methylene components are listed from acylacetylaminoaryl compounds and pyrazolones. The phenyl radicles of the pyrazolones may contain halogens e.g. chlorine and bromine, atoms, alkyl and alkoxy groups such as methyl, ethyl, methoxy and ethoxy groups and particularly groups imparting solubility in water such as sulphonamide and sulphonic and carboxylic acid groups. Pyrazolones mentioned are 1 - phenyl -, 3 - methyl- and 1 - phenyl-, and (21-, 31-, and 41- chloro - and methyl - phenyl) - 3 - methyl - 5 - pyrazolones, 1 - phenyl - 5 - pyrazolone - 3 - carboxylic acid, 1 - phenyl - 3 - methyl - 5 - pyrazolone - 31 - and - 41 - sulphonic or carboxylic acid and - 31 - sulphonamide, 1 - (41 - oxyphenyl) - 3 - methyl - 5 - pyrazolone - 31 - carboxylic acid and aceto - and benzoyl - acetylamino - benzene. J-acid derivatives mentioned as coupling components are 2 - [411 - amino - 11, 111 - diphenylamino(41)] - 5 - naphthol - 7.311 - disulphonic acid and 2 - (41 - aminophenylamino) - 5 - naphthol - 7,31 - disulphonic acid. 8 - Oxyquinoline and its 7 - sulphonic acid are specified end components. Desirably the products contain 2 - 3 sulphonic acid groups per mol. The dyestuffs dye animal and especially cellulosic fibres e.g. wool, silk, leather, cotton, linen, artificial silk and regenerated cellulose. The dyeings may be metallized on the fibre or in the dyebath advantageously with copper-yielding agents, those dyestuffs being especially suitable which have no sulphonic acid groups other than those indicated in the above formula. The one bath metallization of Specification 455,274 [Group IV] may be adapted. The dyeings may be after-treated with a basic condensation product of formaldehyde as in Specification 619,969. In examples which illustrate the preparation of the dyestuffs and their use in dyeing cotton in navy blue tints by an after-coppering process an additional diphenyl component used to certain of those specified above is 3,31 - dimethoxy - 4,41-diamino - diphenyl.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH777200X | 1954-10-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB777200A true GB777200A (en) | 1957-06-19 |
Family
ID=4535904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30548/55A Expired GB777200A (en) | 1954-10-26 | 1955-10-25 | Direct-dyeing trisazo-dyestuffs of the diphenyl series and process for their manufacture |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB777200A (en) |
-
1955
- 1955-10-25 GB GB30548/55A patent/GB777200A/en not_active Expired
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB716338A (en) | Manufacture of compounds containing two 1:2:3-triazole rings | |
GB777200A (en) | Direct-dyeing trisazo-dyestuffs of the diphenyl series and process for their manufacture | |
GB1033917A (en) | Water-insoluble monoazo dyestuffs and processes for their manufacture and use | |
GB630452A (en) | Manufacture of new polyazo-dyestuffs | |
GB896042A (en) | Water-soluble phthalocyanine dyestuffs and process for their manufacture | |
GB654744A (en) | Manufacture of new trisazo-dyestuffs | |
GB643535A (en) | Manufacture of new tetrakisazo-dyestuffs | |
GB560451A (en) | Manufacture of azo-dyestuffs | |
GB457825A (en) | Manufacture of azo-dyestuffs insoluble in water | |
GB1438051A (en) | Water-soluble monoazo dyestuffs process for preparing them and their use | |
GB820950A (en) | New disazo-dyestuffs of the stilbene series, complex metal compounds thereof and process for making them | |
GB697416A (en) | Manufacture of cupriferous disazo-dyestuffs | |
GB821029A (en) | New disazo-dyestuffs and process for their manufacture | |
GB797046A (en) | New complex chromium compounds of benzene-monoazo-pyrazolone dyestuffs and process for making them | |
GB756599A (en) | Manufacture of cupriferous disazo-dyestuffs | |
GB660196A (en) | Manufacture of new monoazo-dyestuffs | |
GB695330A (en) | Manufacture of trisazo-dyestuffs | |
GB815737A (en) | New polyazo-dyestuffs derived from 3,3-dihydroxydiphenylamine and processes for their manufacture | |
GB778233A (en) | New tetrakisazo-dyestuffs and process for making them | |
GB838341A (en) | New monoazo dyestuffs containing a triazine residue | |
GB781086A (en) | New metalliferous disazo-dyestuffs containing a fused thiazole ring and process for making them | |
GB597414A (en) | Manufacture of azo-dyestuffs | |
GB717000A (en) | Dischargeable azo dyestuffs and a process for making same | |
GB633790A (en) | Process for the manufacture of new disazo-dyestuffs | |
GB684527A (en) | New disazo-dyestuffs and process for their manufacture |