GB776664A - Process for removing acids from aqueous solutions of organic solutes with ion exchange resins - Google Patents

Process for removing acids from aqueous solutions of organic solutes with ion exchange resins

Info

Publication number
GB776664A
GB776664A GB13773/54A GB1377354A GB776664A GB 776664 A GB776664 A GB 776664A GB 13773/54 A GB13773/54 A GB 13773/54A GB 1377354 A GB1377354 A GB 1377354A GB 776664 A GB776664 A GB 776664A
Authority
GB
United Kingdom
Prior art keywords
resin
water
solution
acid
absorbed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13773/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB776664A publication Critical patent/GB776664A/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04Processes using organic exchangers
    • B01J41/05Processes using organic exchangers in the strongly basic form

Abstract

Organic solutes having ionization constants not exceeding 1.75 X 10-5 at 25 DEG C. are recovered from their aqueous solutions containing a strong acid having an ionization constant of at least 1.4 X 10-3 at 25 DEG C. by feeding the solution into contact with a bed of an anion-exchange resin in the sulphate form, whereby at least the strong acid solute is absorbed by the resin and thus converts at least a portion of the resin to the bisulphate form, separating therefrom the treated solution and eluting the loaded resin with water to remove, firstly, any absorbed organic solute and thereafter the absorbed strong acid solute, whereby the anion exchange resin is regenerated to the sulphate form. In the process, the strong acid is chemically absorbed; the organic solute is only physically absorbed and remains wholly or in part in the solution surrounding the resin granules. The solution of solutes is preferably fed to a water-immersed bed of the resin with consequent displacement of an equal volume of water and then water is fed to elute the loaded resin; the water first displaces a solution of the organic solute and then displaces the chemically absorbed strong acid solute, the two effluents being collected in separate fractions, with consequent regeneration of the resin. Specified organic solutes include various lower aliphatic water-soluble alcohols, glycols, mono-ethers of ethylene and polyethylene glycols, polyhydric alcohols, carboxylic acids, ketones and amides. Strong acids mentioned are sulphuric, hydrochloric, hydrobromic, nitric, phosphoric, pyrophosphoric, ethylene disulphonic, benzene sulphonic, toluene sulphonic, naphthalene sulphonic and the chloracetic acids. Suitable anion-exchange resins are those described in Specifications 654,706 and 679,850, [both in Group IV (a)], and U.S.A. Specification 2,341,907; the preferred resins are those concess is normally effected at from about room temperature to about 90 DEG F., under substantially atmospheric pressure. The method may be used to recover the organic solutes from their aqueous solutions containing salts of the strong acids by passing the solution through a cation-exchange resin in hydrogen form to convert the salts into the corresponding free acids and then treating the acid solutions as above. Thus, the salt solution may be passed down a column, the upper portion of which contains the cation exchanger and the lower portion, the anion-exchanger; the treated solution is eluted with water to recover the organic solute and the column then is regenerated by an upward flow of water so removing the strong acid. According to examples: (1) an anion-exchange resin obtained by condensation of trimethylamine with a copolymer of styrene with ethyl vinyl benzene and divinyl benzene is converted into its sulphate form by treatment with aqueous sulphuric acid and then washed with water in a column; then a quantity of an aqueous solution of ethylene glycol and HCl is fed down the column of water-immersed resin and thereafter water is passed downwardly to displace aqueous glycol and then upwardly to displace aqueous HCl and so regenerate the resin; in like manner the solutes are separately recovered as solutions from aqueous solutions of (2) acrylamide and sulphuric acid, (4) glycerine and sulphuric acid, (5) ethylene glycol and sulphuric acid, (6) ethylene glycol and ethylene disulphonic acid, (8) ethanol and sulphuric acid, (9) acetic acid and sulphuric acid, (10) acetic and chloracetic acids and (11) methyl ethyl ketone and phosphoric acid using the same or similar exchange resin. Another Example (7) relates to the separation of solutes from aqueous sucrose containing sodium chloride (see Group VI). Methanol, isopropyl alcohol, penta-erythritol, propylene glycol, butylene glycol, polyethylene glycol, propionic acid, acetone and acetamide are other organic solutes mentioned.ALSO:Strong acids having ionization constants of at least 1.4 X 10-3 at 25 DEG C. are recovered from their aqueous solutions containing organic substances having ionization constants not exceeding 1.75 X 10-5 at 25 DEG C. by feeding the solution into contact with a bed of an anion-exchange resin in the sulphate form, whereby at least the strong acid is absorbed by the resin and thus converts at least a portion of the resin to the bisulphate form, separating therefrom the treated solution and eluting the loaded resin with water to remove firstly any absorbed organic substance and thereafter the absorbed strong acid substance, whereby the anion exchange resin is regenerated to the sulphate form. In the process, the strong acid is chemically absorbed; the organic substance is only physically absorbed and remains wholly or in part in the solution surrounding the resin granules. The solution is preferably fed to a water-immersed bed of the resin with consequent displacement of an equal volume of water and then water is fed to elute the loaded resin; the water first displaces a solution of the organic substance and then displaces the chemically absorbed strong acid, the two effluents being collected in separate fractions, with consequent regeneration of the resin. Specified organic substances include various lower aliphatic water-soluble alcohols, glycols, mono ethers of ethylene and polyethylene glycols, polyhydric alcohols, carboxylic acids, ketones and amides, methanol, ethanol, isopropyl alcohol, penta-erythritol, propylene glycol, butylene glycol, polyethylene glycol, propionic, acetic and chloroacetic acid, acetone, acetamide, acrylamide, glycerine, methyl ethyl ketone trimethylamine and sucrose. Strong acids mentioned are sulphuric, hydrochloric, hydrobromic, nitric, phosphoric and pyrophosphoric acids. Suitable anion-exchange resins are those described in Specifications 654,706 and 679,850 [both in Group IV(a)] and U.S.A. Specification 2,341,907; the preferred resins are those containing quaternary nitrogen groups. The process is normally effected at from about room temperature to about 90 DEG F., under substantially atmospheric pressure. The method may be used to recover the organic solutes from their aqueous solutions containing salts of the strong acids by passing the solution through a cation-exchange resin in hydrogen form to convert the salts into the corresponding free acid and then treating the acid solutions as above. Thus, the salt solution may be passed down a column, the upper portion of which contains the cation exchanger and the lower portion, the anion-exchanger; the treated solution is eluted with water to recover the organic solute and the column then is regenerated by an upward flow of water so removing the strong acid.ALSO:Sucrose is recovered from its aqueous solution containing a strong acid having an ionisation constant of at least 1.4 x 10-3 at 25 DEG C. by feeding the solution into contact with a bed of an anion-exchange resin in the sulphate form, whereby at least the strong acid solute is absorbed by the resin and thus converts at least a portion of the resin to the bisulphate form, separating therefrom the treated solution and eluting the loaded resin with water to remove firstly any absorbed sucrose and thereafter the absorbed strong acid solute, whereby the anion exchange resin is regenerated to the sulphate form (see Group IV(b). In the process, the strong acid is chemically absorbed; the sucrose is only physically absorbed and remains wholly or in part in the solution surrounding the resin granules. In Example 7, an aqueous solution of sucrose, containing sodium chloride is passed down a column containing a bed of a cation-exchanger on a bed of anion exchanger in sulphate form as above described to give an aqueous effluent of sucrose free from acid.
GB13773/54A 1953-05-12 1954-05-11 Process for removing acids from aqueous solutions of organic solutes with ion exchange resins Expired GB776664A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US776664XA 1953-05-12 1953-05-12

Publications (1)

Publication Number Publication Date
GB776664A true GB776664A (en) 1957-06-12

Family

ID=22139384

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13773/54A Expired GB776664A (en) 1953-05-12 1954-05-11 Process for removing acids from aqueous solutions of organic solutes with ion exchange resins

Country Status (1)

Country Link
GB (1) GB776664A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2471599A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Method for inhibiting nitrosamine formation in anion exchange resins
EP2471747A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Method for inhibiting nitrosamine formation in anion exchange resins
EP2471598A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Anion exchange resins having controlled nitrosamine formation
CN110938099A (en) * 2019-12-23 2020-03-31 南通市常海食品添加剂有限公司 Method for removing acetate in sucralose
CN111795884A (en) * 2020-06-12 2020-10-20 广东省测试分析研究所(中国广州分析测试中心) Grading separation treatment method for analyzing soluble organic matters in chemical wastewater

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2471599A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Method for inhibiting nitrosamine formation in anion exchange resins
EP2471747A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Method for inhibiting nitrosamine formation in anion exchange resins
EP2471598A1 (en) * 2010-12-29 2012-07-04 Dow Global Technologies LLC Anion exchange resins having controlled nitrosamine formation
US20120172465A1 (en) * 2010-12-29 2012-07-05 Chris Raymond Eicher Anion exchange resins having controlled nitrosamine formation
US20120172463A1 (en) * 2010-12-29 2012-07-05 Chris Raymond Eicher Method for inhibiting nitrosamine formation in anion exchange resins
US20120172464A1 (en) * 2010-12-29 2012-07-05 Chris Raymond Eicher Method for inhibiting nitrosamine formation in anion exchange resins
CN102553661A (en) * 2010-12-29 2012-07-11 陶氏环球技术有限公司 Method for inhibiting nitrosamine formation in anion exchange resins
US9138739B2 (en) * 2010-12-29 2015-09-22 Dow Global Technologies Llc Method for inhibiting nitrosamine formation in anion exchange resins
US9216411B2 (en) * 2010-12-29 2015-12-22 Dow Global Technologies Llc Method for inhibiting nitrosamine formation in anion exchange resins
CN110938099A (en) * 2019-12-23 2020-03-31 南通市常海食品添加剂有限公司 Method for removing acetate in sucralose
CN111795884A (en) * 2020-06-12 2020-10-20 广东省测试分析研究所(中国广州分析测试中心) Grading separation treatment method for analyzing soluble organic matters in chemical wastewater

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