GB776548A - Improvements in or relating to methods for the preparation of organic metal salts - Google Patents

Improvements in or relating to methods for the preparation of organic metal salts

Info

Publication number
GB776548A
GB776548A GB10841/54A GB1084154A GB776548A GB 776548 A GB776548 A GB 776548A GB 10841/54 A GB10841/54 A GB 10841/54A GB 1084154 A GB1084154 A GB 1084154A GB 776548 A GB776548 A GB 776548A
Authority
GB
United Kingdom
Prior art keywords
shear
subjected
oil
reactants
high rate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB10841/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB776548A publication Critical patent/GB776548A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00—Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/081—Inorganic acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Abstract

Organic metal salts are prepared by reaction between an inorganic metallic base and a saponifiable or neutralizable organic material, the process comprising subjecting the reactants to a rate of shear of at least 50,000 reciprocal seconds. The process is applicable to the neutralization of alkyl phenol sulphides, fatty acids having at least 12 carbon atoms in the molecule and sulphonic acids and to the preparation of soaps by saponification of fats and fatty oils. Calcium and barium hydroxides are specified bases. The reactants may be subjected to the high rate of shear in a Gaulin homogenizer, a paint or ink mill, a Morehouse mill or a pressure viscosimeter. The mixture of reactants may be subjected to the high rate of shear in the reaction zone or the mixture may be continuously circulated between the reaction zone and a treating zone, subjection to the high rate of shear taking place in the treating zone. Alternatively, separate streams of the reactants may be subjected to the high rate of shear and then mixed or a partially reacted mixture of the reactants may be subjected to the high rate of shear to complete the reaction. The preparation of the barium salt of p-iso-octyl phenol sulphide is described wherein a slurry of hydrated barium hydroxide crystals in oil and a separate stream of the alkyl phenol sulphide in oil are mixed and subjected to a rate of shear of about 50,000-500,000 reciprocal seconds at about 175-225 DEG F.ALSO:A lubricating grease composition is prepared by mixing together an inorganic metallic base and a soap-forming organic acid or an ester thereof in a lubricating oil and subjecting the mixture to a rate of shear at least 50,000 reciprocal seconds prior to the substantial completion of the soap-forming reaction. Suitable, soap-forming organic acids and esters thereof are high molecular weight fatty acids, such as stearic, behenic, erucic, oleic and hydrogenated fish oil fatty acids, and animal and vegetable fats and oils, such as lard, tallow, rapeseed oil and hydrogenated fish oil. The mixture may be subjected to the high rate of shear in a Gaulin homogenizer, a paint or ink mill, a Morehouse mill or a pressure viscosimeter. Apparatus for the preparation of lubricating greases according to the method is described. In the examples, lubricating greases are prepared according to the method from (1) hydrated lime, hydrogenated fish oil fatty acids, acetic acid, di- 2 - ethylhexyl sebacate and phenyl alpha - naphthylamine, (2) hydrated lime, hydrogenated fish oil fatty acids, acetic acid and mineral oil (3) hydrated lime, oleic acid and mineral oil and (4) hydrated lime, tallow, mineral oil, calcium chloride and water.
GB10841/54A 1953-05-28 1954-04-13 Improvements in or relating to methods for the preparation of organic metal salts Expired GB776548A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US776548XA 1953-05-28 1953-05-28

Publications (1)

Publication Number Publication Date
GB776548A true GB776548A (en) 1957-06-12

Family

ID=22139307

Family Applications (1)

Application Number Title Priority Date Filing Date
GB10841/54A Expired GB776548A (en) 1953-05-28 1954-04-13 Improvements in or relating to methods for the preparation of organic metal salts

Country Status (2)

Country Link
FR (1) FR1102681A (en)
GB (1) GB776548A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999042541A1 (en) * 1998-02-17 1999-08-26 Exxon Research And Engineering Company Lubricating grease composition and preparation
WO2002004579A1 (en) * 2000-07-11 2002-01-17 Exxonmobil Research And Engineering Company Lubricating grease composition and preparation
EP3031888A1 (en) * 2013-08-06 2016-06-15 Idemitsu Kosan Co., Ltd Method for manufacturing grease
DE102023108177A1 (en) 2023-03-30 2024-10-02 Fuchs SE Production of polyurea-thickened lubricating greases with improved lubrication properties and aging stability
DE102023004246A1 (en) 2023-03-30 2024-10-02 Fuchs SE Production of polyurea-thickened lubricating greases with improved lubrication properties and aging stability

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999042541A1 (en) * 1998-02-17 1999-08-26 Exxon Research And Engineering Company Lubricating grease composition and preparation
AU743979B2 (en) * 1998-02-17 2002-02-14 Exxon Research And Engineering Company Lubricating grease composition and preparation
US6407043B1 (en) 1998-02-17 2002-06-18 Exxonmobil Research And Engineering Company Lubricating grease composition and preparation
WO2002004579A1 (en) * 2000-07-11 2002-01-17 Exxonmobil Research And Engineering Company Lubricating grease composition and preparation
US6498130B2 (en) 2000-07-11 2002-12-24 Exxonmobil Research And Engineering Company Lubricating grease composition and preparation
AU2001271634B2 (en) * 2000-07-11 2005-04-07 Exxonmobil Research And Engineering Company Lubricating grease composition and preparation
EP3031888A1 (en) * 2013-08-06 2016-06-15 Idemitsu Kosan Co., Ltd Method for manufacturing grease
EP3031888A4 (en) * 2013-08-06 2017-03-29 Idemitsu Kosan Co., Ltd Method for manufacturing grease
US9994787B2 (en) 2013-08-06 2018-06-12 Idemitsu Kosan Co., Ltd. Method for manufacturing grease
TWI648391B (en) * 2013-08-06 2019-01-21 出光興產股份有限公司 Manufacturing method of grease
DE102023108177A1 (en) 2023-03-30 2024-10-02 Fuchs SE Production of polyurea-thickened lubricating greases with improved lubrication properties and aging stability
DE102023004246A1 (en) 2023-03-30 2024-10-02 Fuchs SE Production of polyurea-thickened lubricating greases with improved lubrication properties and aging stability
WO2024200526A1 (en) 2023-03-30 2024-10-03 Fuchs SE Producing polyurea-thickened lubricating greases having improved lubrication properties and aging stability

Also Published As

Publication number Publication date
FR1102681A (en) 1955-10-25

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