GB774078A - Improvements in textile decoration and compositions therefor - Google Patents

Improvements in textile decoration and compositions therefor

Info

Publication number
GB774078A
GB774078A GB1198753A GB1198753A GB774078A GB 774078 A GB774078 A GB 774078A GB 1198753 A GB1198753 A GB 1198753A GB 1198753 A GB1198753 A GB 1198753A GB 774078 A GB774078 A GB 774078A
Authority
GB
United Kingdom
Prior art keywords
water
oil
emulsions
added
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1198753A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB1198753A priority Critical patent/GB774078A/en
Publication of GB774078A publication Critical patent/GB774078A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

A pasty pigmented colour concentrate is an aqueous emulsion of a solution of an ester of a drying oil acid and a condensate from epihalohydrin or dihalohydrin with a polyhydric polynuclear phenol. It contains 15-40 per cent non-volatile constituents, and 3-15 per cent of a pigment toner (the pigment toner being less than 50 per cent of the non-volatile constituents and having a high tinting power). The colour concentrates may be oil-in-water or water-in-oil emulsions and on dilution with clear extender emulsions yield textile printing compositions which give prints with good crocking and laundry resistance. The esters used thermoset at temperatures below 105 DEG C. They are preferably prepared from condensates of epichlorhydrin with bis-phenol. The drying oil acid may be a naturally occurring mixture containing semi- and non-drying acids. Part of the acid may be replaced by rosin acids. Lists of suitable emulsifying agents and of pigments which may be either organic or inorganic are given. Organic solvent soluble alkylated urea- or melamine-formaldehydresins or ethyl cellulose may be added to the esters. Nitrocellulose may be added with a melamine-aldehyde resin, the latter then setting at low temperature. Extender pigments may be added in addition to the pigment toner. The pigment toner may be dispersed in the resin solution or in water. Dispersions or solutions of rubber or synthetic elastomers may be added to the colour concentrates. For discharge printing compositions, sodium sulphoxylate may be added to the emulsions, or if the emulsion is acid, zinc sulphoxylate. The emulsions of the esters may be aggregated by an oxygenation treatment as described in U.S.A. Specification 2,530,370 to give prints of better toughness and ageing qualities. Bodying agents may be added to emulsions of the oil-in-water type. Flushing agents, e.g. mono- or di-amylamine oleates, as described in U.S.A. Specification 2,126,925, or cationic flushing agents, as described in U.S.A. Specification 2,192,954, may be added to aqueous pigment suspensions to produce flushed colours. In the examples, the resinous ester, used as a solution in mineral spirits or xylol, was derived from a condensate of epichlorhydrin or a chlorhydrin with p,p1-di-hydroxydiphenyldimethylmethane and either a mixture of rosin with linseed oil acids (Polyester A) or dehydrated castor oil acids (Polyester B). Example 1 is typical of a water-in-oil emulsion colour concentrate; phthalocyanine green, china clay, kaolin, polyester B, high-flash naphtha, a non-ionic surface-active ethylene oxide-cresols condensate, soya lecithin in soyabean oil, and zinc naphthenate are mixed in a turbo-mixer and ground. The resulting pigment grind, more polyester B, pine oil, a petroleum-aromatic solvent mixture, butyl alcohol and water are mixed in a turbo-mixer to form a colour concentrate. A number of other similar examples are given. Examples are also given of emulsions for diluting these water-in-oil colour concentrates. A typical one is as follows:-polyester B, pine oil, rubber solution in xylol, aqueous solubilized quebracho extract, acetic acid, sodium chloride, petroleum aromatic solvent and water are homogenized in a turbomixer, the water and solvent being added alternately. An example is also given of a discharge, cut back emulsion H, which can be added to colour concentrates to form discharge pigment printing pastes. It contains sodium sulphoxylate. Example IX is typical of an oil-in-water pigmented printing colour concentrate. Polyester B, mixed naphthenate driers, aqueous sodium lauryl sulphate, aqueous casein containing conventional antifouling agents, ammonium hydroxide, sodium carboxymethyl cellulose and water are emulsified together and mixed with an aqueous phthalocyanine pigment dispersion, a polychloroprene latex, pine oil and water. The proportion of organic solvents is lower and of water higher than is the case with the water-in-oil emulsions. Examples are also given of cut-back emulsions J-M for the oil-in-water emulsions. Oil-in-water colour concentrates may be diluted with water with or without some cut-back emulsion to provide pigment padding compositions. Specifications 774,079, [Group IV (c)], and 774,080 are referred to.ALSO:A pasty pigmented colour concentrate is an aqueous emulsion of a solution of an ester of a drying oil acid and a condensate from epihalohydrin or dihalohydrin with a polyhydric polynuclear phenol. It contains 15-40 per cent non-volatile constituents, and 3-15 per cent of a pigment toner (the pigment toner being less than 50 per cent of the non-volatile constituents and having a high tinting power). The colour concentrates may be oil-in-water or water-in-oil emulsions and on dilution with clear extender emulsions yield textile printing compositions which give prints with good washing and laundry resistance. The esters used thermoset at temperatures below 105 DEG C. They are preferably prepared from condensates of epichlorhydrin with bis-phenol. The drying oil acid may be a naturally occurring mixture containing semi- and non-drying acids. Part of the acid may be replaced by rosin acids. Lists of suitable emulsifying agents and of pigments, which may be either organic or inorganic, are given. Organic solvent-soluble alkylated urea- or melamine-formaldehyde resins or ethyl cellulose may be added to the esters. Nitrocellulose may be added with a melamine-aldehyde resin, the latter then setting at low temperature. Extender pigments may be added in addition to the pigment toner. The pigment toner may be dispersed in the resin solution or in water. Dispersions or solutions of rubber or synthetic elastomers may be added to the colour concentrates. For discharge printing compositions, sodium sulphoxylate may be added to the emulsions, or, if the emulsion is acid, zinc sulphoxylate. The emulsions of the esters may be aggregated by an oxygenation treatment as described in U.S.A. Specification 2,530,370 to give prints of better toughness and ageing qualities. Bodying agents may be added to emulsions of the oil-in-water type. Flushing agents, e.g. mono- or diamyl-amine oleates as described in U.S.A. Specification 2,126,925 or cationic flushing agents as described in U.S.A. Specification 2,192,954 may be added to aqueous pigment suspensions to produce flushed colours. In the examples, the resinous ester used as a solution in mineral spirits or xylol, was derived from a condensate of epichlorhydrin or a chlorhydrin with p.p1 - di - hydroxydiphenyldimethylmethane and either a mixture of rosin with linseed oil acids (Polyester A) or dehydrated castor oil acids (Polyester B). Ex. 1 is typical of a water-in-oil emulsion colour concentrate; phthalocyanine green, china clay, kaolin, polyester B, high-flash naphtha, a non-ionic surface active ethylene oxide-cresols condensate, soya lecithin in soya-bean oil, and zinc naphthenate are mixed in a turbo-mixer and ground. The resulting pigment grind, more polyester B, pine oil, a petroleum-aromatic solvent mixture, butyl alcohol and water are mixed in a turbo-mixer to form a colour concentrate. A number of other similar examples are given. Examples are also given of emulsions for diluting these water-in-oil colour concentrates. A typical one is a follows:-polyester B, pine oil, rubber solution in xylol, aqueous solubilized quebracho extract, acetic acid, sodium chloride, petroleum aromatic solvent and water are homogenized in a turbo-mixer, the water and solvent being added alternately. An example is also given of a discharge, cut back emulsion H, which can be added to colour concentrates to form discharge pigment printing pastes. It contains sodium sulphoxylate. Ex. IX is typical of an oil-in-water pigmented printing colour concentrate. Polyester B, mixed naphthenate driers, aqueous sodium lauryl sulphate, aqueous casein containing conventional antifouling agents, ammonium hydroxide, sodium carboxymethyl cellulose and water are emulsified together and mixed with an aqueous phthalocyanine pigment dispersion, a polychloroprene latex, pine oil and water. The proportion of organic solvents is lower and of water higher than is the case with the water-in-oil emulsions. Examples are also given of cut-back emulsions J-M for the oil-in-water emulsions. Oil-in-water colour concentrates may be diluted with water with or without some cut back emulsion to provide pigment padding compositions. Specifications 774,079 and 774,080 are referred to.
GB1198753A 1953-04-30 1953-04-30 Improvements in textile decoration and compositions therefor Expired GB774078A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1198753A GB774078A (en) 1953-04-30 1953-04-30 Improvements in textile decoration and compositions therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1198753A GB774078A (en) 1953-04-30 1953-04-30 Improvements in textile decoration and compositions therefor

Publications (1)

Publication Number Publication Date
GB774078A true GB774078A (en) 1957-05-08

Family

ID=9996351

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1198753A Expired GB774078A (en) 1953-04-30 1953-04-30 Improvements in textile decoration and compositions therefor

Country Status (1)

Country Link
GB (1) GB774078A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006133169A2 (en) * 2005-06-07 2006-12-14 S. C. Johnson & Son, Inc. Composition for application to a surface
US7727289B2 (en) 2005-06-07 2010-06-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US7776108B2 (en) 2005-06-07 2010-08-17 S.C. Johnson & Son, Inc. Composition for application to a surface
US8061269B2 (en) 2008-05-14 2011-11-22 S.C. Johnson & Son, Inc. Multilayer stencils for applying a design to a surface
US8557758B2 (en) 2005-06-07 2013-10-15 S.C. Johnson & Son, Inc. Devices for applying a colorant to a surface
US8846154B2 (en) 2005-06-07 2014-09-30 S.C. Johnson & Son, Inc. Carpet décor and setting solution compositions
WO2017066974A1 (en) * 2015-10-23 2017-04-27 揭东巴黎万株纱华纺织有限公司 Process for preparing colour masterbatch

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006133169A2 (en) * 2005-06-07 2006-12-14 S. C. Johnson & Son, Inc. Composition for application to a surface
WO2006133169A3 (en) * 2005-06-07 2007-05-31 Johnson & Son Inc S C Composition for application to a surface
US7727289B2 (en) 2005-06-07 2010-06-01 S.C. Johnson & Son, Inc. Composition for application to a surface
US7776108B2 (en) 2005-06-07 2010-08-17 S.C. Johnson & Son, Inc. Composition for application to a surface
US8557758B2 (en) 2005-06-07 2013-10-15 S.C. Johnson & Son, Inc. Devices for applying a colorant to a surface
US8734533B2 (en) 2005-06-07 2014-05-27 S.C. Johnson & Son, Inc. Composition for application to a surface
US8747487B2 (en) 2005-06-07 2014-06-10 S.C. Johnson & Son, Inc. Composition for application to a surface
US8846154B2 (en) 2005-06-07 2014-09-30 S.C. Johnson & Son, Inc. Carpet décor and setting solution compositions
US8061269B2 (en) 2008-05-14 2011-11-22 S.C. Johnson & Son, Inc. Multilayer stencils for applying a design to a surface
US8499689B2 (en) 2008-05-14 2013-08-06 S. C. Johnson & Son, Inc. Kit including multilayer stencil for applying a design to a surface
WO2017066974A1 (en) * 2015-10-23 2017-04-27 揭东巴黎万株纱华纺织有限公司 Process for preparing colour masterbatch

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