GB772978A - Soluble and fusible copolymers which can be converted into infusible and insoluble resins - Google Patents

Soluble and fusible copolymers which can be converted into infusible and insoluble resins

Info

Publication number
GB772978A
GB772978A GB23050/55A GB2305055A GB772978A GB 772978 A GB772978 A GB 772978A GB 23050/55 A GB23050/55 A GB 23050/55A GB 2305055 A GB2305055 A GB 2305055A GB 772978 A GB772978 A GB 772978A
Authority
GB
United Kingdom
Prior art keywords
soluble
polymerization
resin
converted
infusible
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23050/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay SA filed Critical Solvay SA
Publication of GB772978A publication Critical patent/GB772978A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/065—PVC together with other resins except polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/08—Vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
    • C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A soluble and fusible resin capable of being converted into an insoluble and infusible resin which does not support combustion comprises a copolymer containing 80 to 90 per cent of vinyl chloride and/or vinylidene chloride and 1 to 20 per cent of an allyl ester of acrylic, methacrylic or a -chloroacrylic acid. The resin may be prepared by subjecting to polymerization conditions a mixture of vinyl chloride and/or vinylidene chloride with an allyl ester of acrylic, methacrylic, or a -chloroacrylic acid dissolved in appropriate proportions in a solvent, such as acetone, dioxane or carbon tetrachloride, which dissolves both the monomeric materials and the soluble and fusible resin obtained therefrom, and terminating the polymerization before gelation sets in, preferably by the addition of a non-solvent for the polymer,such as methanol. The allyl ester is preferably introduced into the polymerization vessel as the polymerization proceeds, the rate of addition being so regulated that the ratio of the proportions of monomers is maintained constant. 2-azodi-isobutyronitrile may be used as catalyst. The resin may be converted to the insoluble, infusible state by prolonged heating, or by heating in the presence of a polymerization catalyst such as tertiary butyl perbenzoate or benzoyl peroxide and/or another mono- or poly-functional monomer such as diallyl phthalate. Solutions of the soluble fusible polymers in acetone, carbon tetrachloride or dioxane may be used for impregnating fabrics or as lacquers.
GB23050/55A 1954-08-25 1955-08-10 Soluble and fusible copolymers which can be converted into infusible and insoluble resins Expired GB772978A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE338606X 1954-08-25

Publications (1)

Publication Number Publication Date
GB772978A true GB772978A (en) 1957-04-17

Family

ID=3867966

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23050/55A Expired GB772978A (en) 1954-08-25 1955-08-10 Soluble and fusible copolymers which can be converted into infusible and insoluble resins

Country Status (5)

Country Link
BE (1) BE531404A (en)
CH (1) CH338606A (en)
FR (1) FR1128845A (en)
GB (1) GB772978A (en)
NL (2) NL199647A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4022849A (en) * 1971-01-21 1977-05-10 Stauffer Chemical Company Crosslinked vinyl halide polymers as flame retardant additives for thermoplastics
US4118440A (en) * 1973-09-10 1978-10-03 Stauffer Chemical Company Crosslinked vinyl halide polymers as flame retardant additives for thermoplastic polyester

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0297781A3 (en) * 1987-06-30 1991-03-27 Imperial Chemical Industries Plc Curable coating compositions and their preparation and use

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4022849A (en) * 1971-01-21 1977-05-10 Stauffer Chemical Company Crosslinked vinyl halide polymers as flame retardant additives for thermoplastics
US4118440A (en) * 1973-09-10 1978-10-03 Stauffer Chemical Company Crosslinked vinyl halide polymers as flame retardant additives for thermoplastic polyester

Also Published As

Publication number Publication date
NL199647A (en)
CH338606A (en) 1959-05-31
NL89768C (en)
BE531404A (en)
FR1128845A (en) 1957-01-10

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