GB772675A - Adhesion promoters - Google Patents
Adhesion promotersInfo
- Publication number
- GB772675A GB772675A GB24790/54A GB2479054A GB772675A GB 772675 A GB772675 A GB 772675A GB 24790/54 A GB24790/54 A GB 24790/54A GB 2479054 A GB2479054 A GB 2479054A GB 772675 A GB772675 A GB 772675A
- Authority
- GB
- United Kingdom
- Prior art keywords
- titanate
- solution
- coated
- polyethylene
- isopropanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/226—Non-corrosive coatings; Primers applied before welding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/056—Forming hydrophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D185/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/02—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving pretreatment of the surfaces to be joined
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/005—Glue sticks
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/12—Organo-metallic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2485/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon; Derivatives of such polymers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/04—Metal coatings applied as foil
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
In examples (IV) a mixture of tetraisopropyl titanate, butadiene-styrene copolymer and xylol is applied to a steel plate, and, after hydrolysis a slab of neoprene is hot-pressed and cured on the resulting film; (XI) polyethylene is dispersed in hot xylol, tetraisopropyl titanate added and the solution cooled to give a dispersion of polyethylene in the titanate solution, which may be diluted with such solvents as hexane, benzene, ethanol, isopropanol, mineral spirits and toluene.ALSO:In example (IX), glass fibres are passed through a solution in butanol of tetrabutyl zirconate, hexamethylene-tetramine, and tetraoleyl titanate, drained and baked; they are then incorporated in polyamide rods by casting.ALSO:A composition which on hydrolysis gives rise to an adhesion promoting film comprises a substantially non-aqueous fluid preparation of a hydroysable alcoholate of a metal having a valence of 3 to 5, each hydrolysable organic radical having from 1 to 8 carbon atoms, and at least one of the following: (1) normally solid hydrocarbons; (2) alcohols of more than 8 carbon atoms per molecule, and their alcoholates with the said metals; (3) compounds of the structure RO-(-R1O-)x-R11, wherein R and R1 are hydrocarbon radicals and R11 is a hydrocarbon radical or hydrogen, x is 1 to 10 when R and R1 are aliphatic radicals and R11 is an aliphatic radical or hydrogen and x is 0 to 1 when R or R11 is an aromatic radical; (4) organic amino compounds having not more than 6 carbon atoms per molecule and which are both water-miscible and miscible in organic solvents; and (5) polyhydroxy compounds having from 2 to 8 carbon atoms and present in amounts compatible with the said preparation. Solvents may also be included. The alcoholates may be e.g. methyl to octyl titanates, zirconates, antimonates, aluminates and ferrates, and may be in a partially condensed state. Acyloxy groups, unlimited as to the number of carbon atoms they contain, may replace a proportion of the alkoxy groups therein. The compositions are applied to surfaces, e.g. of metals, plastics, glass, polysulphide rubbers, paper and regenerated cellulose sheeting, and the alcoholate hydroysed by exposure to moist air, the other specified components modifying the rate of hydrolysis. Laminating substances, e.g. linseed oil, paints, varnishes and alkyd resins, polyethylene and monomeric acrylates or methacrylates may be applied over the coated surfaces. In examples (1) a mixture of tetrastearyl titanate and tetraisopropyl titanate was diluted with dry hexane and isopropyl alcohol and applied to an aged alkyd enamel paint surface, and a fresh coat of alkyd enamel paint applied over the resultant hydrolysed film; (2) the same composition was applied to part of an aluminium panel, part left uncoated and the remainder coated with a solution of tetraisopropyl titanate in a mixture of hexane and isopropanol, the coatings were cured at 70 DEG F. and 90 per cent relative humidity and an alkyd enamel applied to all three areas; (3) a mixture of tetrabutyl titanate and naphthalene was diluted with dry hexane and applied to steel test panels, the solvent allowed to evaporate at 70 DEG F. and 50 per cent relative humidity, the panels were then baked, cooled, and coated with an alkyd type baking enamel, dried and baked; (4) a mixture of tetraisopropyl titanate, butadienestyrene copolymer and xyol was applied to a steel plate; after hydrolysis a slab of neoprene was hot pressed against the resulting film, and cured; (5) two strips of aluminium were coated with a solution of isopropyl titanate, isopropyl aluminate and naphthalene in a mixture of isopropanol and hexane; after curing at 125 DEG C, the surfaces were soldered with a commercial aluminium soldering flux and lead-tin solder; (6) aluminium panels were coated with a solution of tetraisopropyl titanate and oleyl alcohol in hexane, and, after drying in moist air, coated with a vinyl chloride-vinyl acetate copolymer dissolved in methyl ethyl ketone; (7) a sheet of vinyl plastic was coated with a solution containing tetraisopropyl titanate, ethylene glycol monoethyl ether and isopropanol, and a pigmented nitro-cellulose ink applied to the film so produced; (8) aluminium was coated with a solution containing tetraisopropyl titanate, glycerol and isopropanol, and the resulting film coated, after hydrolysis, with a water base paint containing emulsified polyvinyl acetate; (9) glass fibres were passed through a solution in butanol of tetrabutyl zirconate, hexamethylene-tetramine and tetraoleyl titanate, drained and baked; they were then incorporated in polyamide rods by casting; (10) the inner surface of an aluminium aircraft fuel tank was treated with a solution of tetrapropyl titanate and naphthalene in xylol; after draining and drawing a slow current of air through the tank, it was treated with a solution in xylol of "Thiokol" (Registered Trade Mark) rubber, dried, and heat cured; (11) polyethylene was dispersed in hot xylol, tetraisopropyl titanate added and the solution cooled, with vigorous agitation, to give a dispersion of polyethylene in the titanate solution, which could be diluted with such solvents as hexane, benzene, ethanol, isopropanol, mineral spirits and toluene; (12) a dilution of the dispersion of Example 11 with isopropanol was used to treat kraft paper, to give an antiblocking paper of high wet strength, which was very adherent to polyethylene, and could be hot-coated with a solution thereof in xylol; the product could be heat-sealed to itself, or laminated with thicker sheets of polyethylene; (13) sheet aluminium was coated with a dilution of the product of Example 11, dried and baked, and could then be bonded to sheet polyethylene; multiple laminates could be so made; (14) moisture-proof "Cellophane" (Registered Trade Mark) having a coating of nitro-cellulose was coated with a dilution of the product of Example 11 in isopropanol, air dried, and passed, together with a sheet of polyethylene, between heated rolls, to give a laminate; (15) corrugated paper, dipped in a solution of tetraisopropyl titanate containing dispersed polyethylene, and sheet aluminium treated as in Example 13, after standing at room temperature, were laminated by heat to an interposed sheet of polyethylene; (16) a mixture of tetraisopropyl titanate and tetraoleyl titanate was diluted with mineral spirits and applied to old enamelled woodwork, which, after exposure to good ventilation, was coated with an oil base enamel.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US772675XA | 1953-09-02 | 1953-09-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB772675A true GB772675A (en) | 1957-04-17 |
Family
ID=22137073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24790/54A Expired GB772675A (en) | 1953-09-02 | 1954-08-25 | Adhesion promoters |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1112120A (en) |
GB (1) | GB772675A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4381945A (en) | 1981-08-03 | 1983-05-03 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions |
US4416932A (en) * | 1981-08-03 | 1983-11-22 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions |
EP0855434A2 (en) * | 1997-01-25 | 1998-07-29 | Ivoclar Ag | Adhesive compositon for adhesion of plastics to other materials |
EP1717855A1 (en) | 2005-04-25 | 2006-11-02 | E.I.Du pont de nemours and company | Thick film conductor compositions and the use thereof in LTCC circuits and devices |
EP2056352A2 (en) | 2007-10-29 | 2009-05-06 | Palo Alto Research Center Incorporated | Co-extruded compositions for high aspect ratio structures |
US7550319B2 (en) | 2005-09-01 | 2009-06-23 | E. I. Du Pont De Nemours And Company | Low temperature co-fired ceramic (LTCC) tape compositions, light emitting diode (LED) modules, lighting devices and method of forming thereof |
US7618704B2 (en) | 2003-09-29 | 2009-11-17 | E.I. Du Pont De Nemours And Company | Spin-printing of electronic and display components |
US7666328B2 (en) | 2005-11-22 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Thick film conductor composition(s) and processing technology thereof for use in multilayer electronic circuits and devices |
US8143326B2 (en) | 2004-09-28 | 2012-03-27 | E.I. Du Pont De Nemours And Company | Spin-printing of electronic and display components |
US10633496B2 (en) * | 2015-12-04 | 2020-04-28 | Resinoplast | Method for applying, to an inorganic surface, a PVC composition having improved adhesion to surfaces |
CN114806691A (en) * | 2022-05-25 | 2022-07-29 | 中国科学院兰州化学物理研究所 | Room-temperature curing dry film lubricant and preparation method and application thereof |
-
1954
- 1954-08-25 GB GB24790/54A patent/GB772675A/en not_active Expired
- 1954-09-02 FR FR1112120D patent/FR1112120A/en not_active Expired
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4381945A (en) | 1981-08-03 | 1983-05-03 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions |
US4416932A (en) * | 1981-08-03 | 1983-11-22 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions |
EP0855434A2 (en) * | 1997-01-25 | 1998-07-29 | Ivoclar Ag | Adhesive compositon for adhesion of plastics to other materials |
EP0855434A3 (en) * | 1997-01-25 | 2001-04-18 | Ivoclar Ag | Adhesive compositon for adhesion of plastics to other materials |
US6613439B1 (en) | 1997-01-25 | 2003-09-02 | Ivoclar Ag | Adhesion-promoting composition for bonds between plastic and other materials |
EP2256550A1 (en) | 2003-09-29 | 2010-12-01 | E. I. du Pont de Nemours and Company | Spin-printing of electronic and display components |
US7618704B2 (en) | 2003-09-29 | 2009-11-17 | E.I. Du Pont De Nemours And Company | Spin-printing of electronic and display components |
US8143326B2 (en) | 2004-09-28 | 2012-03-27 | E.I. Du Pont De Nemours And Company | Spin-printing of electronic and display components |
US7611645B2 (en) | 2005-04-25 | 2009-11-03 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions and the use thereof in LTCC circuits and devices |
EP1717855A1 (en) | 2005-04-25 | 2006-11-02 | E.I.Du pont de nemours and company | Thick film conductor compositions and the use thereof in LTCC circuits and devices |
US7550319B2 (en) | 2005-09-01 | 2009-06-23 | E. I. Du Pont De Nemours And Company | Low temperature co-fired ceramic (LTCC) tape compositions, light emitting diode (LED) modules, lighting devices and method of forming thereof |
US7808097B2 (en) | 2005-09-01 | 2010-10-05 | E.I. Du Pont De Nemours And Company | Low temperature co-fired ceramic (LTCC) tape compositions, light-emitting diode (LED) modules, lighting devices and methods of forming thereof |
US7666328B2 (en) | 2005-11-22 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Thick film conductor composition(s) and processing technology thereof for use in multilayer electronic circuits and devices |
EP2056352A2 (en) | 2007-10-29 | 2009-05-06 | Palo Alto Research Center Incorporated | Co-extruded compositions for high aspect ratio structures |
US10633496B2 (en) * | 2015-12-04 | 2020-04-28 | Resinoplast | Method for applying, to an inorganic surface, a PVC composition having improved adhesion to surfaces |
CN114806691A (en) * | 2022-05-25 | 2022-07-29 | 中国科学院兰州化学物理研究所 | Room-temperature curing dry film lubricant and preparation method and application thereof |
CN114806691B (en) * | 2022-05-25 | 2023-04-14 | 中国科学院兰州化学物理研究所 | Room temperature curing dry film lubricant and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
FR1112120A (en) | 1956-03-08 |
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