GB771165A - Resins from steam-cracked streams copolymerized with fulvene-type compounds - Google Patents

Resins from steam-cracked streams copolymerized with fulvene-type compounds

Info

Publication number
GB771165A
GB771165A GB18622/55A GB1862255A GB771165A GB 771165 A GB771165 A GB 771165A GB 18622/55 A GB18622/55 A GB 18622/55A GB 1862255 A GB1862255 A GB 1862255A GB 771165 A GB771165 A GB 771165A
Authority
GB
United Kingdom
Prior art keywords
fulvene
per cent
dimethyl
catalyst
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18622/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB771165A publication Critical patent/GB771165A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A steam-cracked petroleum fraction, boiling in the range 20 DEG to 170 DEG C., is polymerized in the presence of from 2 to 25 per cent of one or more fulvenes using an aluminium halide as catalyst. Specified fulvenes are dimethyl fulvene, the dimethyl fulvene of indene, g -phenyl-benzofulvene and g -methyl-g -vinyl-benzofulvene. The petroleum fraction may have the composition 10-25 per cent diolefins, 20-50 per cent aromatics, 24-66 per cent olefins and 1-4 per cent paraffins. The catalyst may be added to the petroleum fraction before the addition of the fulvene, while the fulvene may be added in the form of a solution in a hydrocarbon fraction. Batch or continuous operations may be employed and the catalyst may be added over a period.ALSO:Fulvenes are prepared by reacting ketones or aldehydes with cyclic compounds containing active methylene groups, such as in cyclopentadienes, in the presence of a basic catalyst such as an alkali alcoholate solution in alcohol. Thus dimethyl fulvene is prepared from acetone and cyclopentadiene while the dimethyl fulvene of indene is prepared by reacting acetone with indene in the presence of sodium methoxide and methanol. Other specified ketones and aldehydes are methyl ethyl ketone, acetophenone, methyl vinyl ketone, acrolein, benzaldehyde and cinnamaldehyde while methyl and dimethyl cyclopentadiene may be used as the other reactant.
GB18622/55A 1954-08-02 1955-06-28 Resins from steam-cracked streams copolymerized with fulvene-type compounds Expired GB771165A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US771165XA 1954-08-02 1954-08-02

Publications (1)

Publication Number Publication Date
GB771165A true GB771165A (en) 1957-03-27

Family

ID=22136152

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18622/55A Expired GB771165A (en) 1954-08-02 1955-06-28 Resins from steam-cracked streams copolymerized with fulvene-type compounds

Country Status (3)

Country Link
DE (1) DE1030027B (en)
FR (1) FR1134120A (en)
GB (1) GB771165A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1486211A (en) * 1974-03-04 1977-09-21 Exxon Research Engineering Co Petroleum resins

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2628955A (en) * 1950-06-08 1953-02-17 Goodrich Co B F Olefinic interpolymers and method of making same

Also Published As

Publication number Publication date
DE1030027B (en) 1958-05-14
FR1134120A (en) 1957-04-08

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