GB770803A - Improvements in rubber treatment - Google Patents
Improvements in rubber treatmentInfo
- Publication number
- GB770803A GB770803A GB15530/55A GB1553055A GB770803A GB 770803 A GB770803 A GB 770803A GB 15530/55 A GB15530/55 A GB 15530/55A GB 1553055 A GB1553055 A GB 1553055A GB 770803 A GB770803 A GB 770803A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- azo
- carbon black
- methyl
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/23—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A vulcanizate of low-torsional hysteresis and high electrical resistivity is prepared by mixing synthetic rubber with a large amount of carbon black and a small amount of a solely aliphatic azo compound having bonded to each nitrogen of the azo group an aliphatic carbon atom having bonded to it a cyano group, an alkyl group with 1 to 5 carbon atoms, and a hydrogen atom or a methyl or ethyl radical, heating the mixture at a temperature of at least 275 DEG F., but below that at which the rupber would be harmed by thermal decomposition, masticating the mixture either during, subsequent to, or alternately with the heat treatment, incorporating vulcanizing and other ingredients, shaping and vulcanizing. To avoid premature decomposition of the azo compound or premature reaction thereof with the synthetic rubber, the azo compound is mixed with the carbon black and the rubber at a relatively low temperature, e.g. below 250 DEG F. The azo compound may comprise a ,a 1-azo bis-isobutyronitrile, a ,a 1-azo bis - (2 - methyl - butyronitrile), a ,a 1-azo bis - (2 - methylheptanonitrile), a ,a 1-azo bis - (a ,g ,g - tri - methylvaleronitrile), a 1,a 1 - azo bis - (a - ethy - butyronitrile), or a ,a 1-azo bis-(propionitrile). The synthetic rubber may comprise a polymer of a conjugated diolefin, e.g. butadiene or isoprene, or copolymers thereof with styrene, a -methylstyrene, acrylonitrile, a monovinylpyridine, ethyl or methyl acrylate, methyl vinyl ketone, methyl isopropenyl ketone, or methyl methacrylate. Preferably 1 to 5 parts by weight of azo compound and 40 to 100 parts of carbon black are mixed with 100 parts of rubber. U.S.A. Specification 2,118,601 is referred to.ALSO:A vulcanizate of low torsional hysteresis and high electrical resistivity is prepared by mixing natural or synthetic rubber with a large amount of carbon black and a small amount of a solely aliphatic azo compound having bonded to each nitrogen of the azo group an aliphatic carbon atoms having bonded to it a cyano group, an alkyl group with 1 to 5 carbon atoms, and a hydrogen atom or a methyl or ethyl radical, heating the mixture at a temperature of at least 275 DEG F. but below that at which the rubber would be harmed by thermal decomposition, masticating the mixture either during, subsequent to, or alternately with the heat treatment, incorporating vulcanizing and other ingredients, shaping and vulcanizing. To avoid premature decomposition of the azo compound or premature reaction thereof with the natural or synthetic rubber the azo compound is mixed with the carbon black and the rubber at a relatively low temperature, e.g. below 250 DEG F. The azo compound may comprise a , a 1-azobis-isobutyronitrile, a , a 1-azo bis-(2-methyl-butyronitrile), a , a 1-bis bis (2-methylheptanonitrile), a , a 1-azo bis (a , g , g , trimethylvaleronitrile), a , a 1-azo bis (a -ethylbutyronitrile), or a , a 1-azo bis-(propionitrile). The synthetic rubber may comprise a polymer of a conjugated diolefin, e.g. butadiene or polyisoprene, or copolymers thereof with styrene, a -methylstyrene, acrylonitrile, a monovinylpyridine, ethyl or methyl acrylate, methyl vinyl ketone, methyl isopropenyl ketone, or methyl methacrylate. Preferably 1 to 5 parts by weight of azo compound and 40 to 100 parts of carbon black are mixed with 100 parts of rubber. In examples vulcanizates are prepared using (1) 100 parts natural rubber, 50 parts carbon black, 1,5 parts a , a 1 azobix-isobutyronitrile, (2) 100 parts butadiene-styrene, 52 parts carbon black, 6 parts hydrocarbon oil, 1 part stearic acid, 2,5 parts a , a 1-azobis-isobutyronitrile, (3) 100 parts butadiene-acrylonitrile, 50 parts carbon black, 6 parts hydrocarbon oil, 1 part stearic acid, and 2,5 parts a , a 1-azobis-isobutyronitrile, (4) 100 parts butadiene-styrene, 37,5 parts hydrocarbon oil, 72 parts carbon black, 3 parts a , a 1-azobis-isobutyronitrile, vulcanizing and other ingredients being added after the heat treatment. U.S.A. Specification 2,118,601 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US770803XA | 1954-08-31 | 1954-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB770803A true GB770803A (en) | 1957-03-27 |
Family
ID=22135957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15530/55A Expired GB770803A (en) | 1954-08-31 | 1955-05-31 | Improvements in rubber treatment |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB770803A (en) |
-
1955
- 1955-05-31 GB GB15530/55A patent/GB770803A/en not_active Expired
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