GB769691A - Improvements in and relating to fluorescent compositions - Google Patents
Improvements in and relating to fluorescent compositionsInfo
- Publication number
- GB769691A GB769691A GB2347053A GB2347053A GB769691A GB 769691 A GB769691 A GB 769691A GB 2347053 A GB2347053 A GB 2347053A GB 2347053 A GB2347053 A GB 2347053A GB 769691 A GB769691 A GB 769691A
- Authority
- GB
- United Kingdom
- Prior art keywords
- naphthaldazine
- pigment
- rhodamine
- inks
- dihydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Fluorescent coating compositions such as printing pastes and inks, textile and silk screen inks comprise a pigment dyed with a rhodamine dye and 221 dihydroxy-naphthaldazine or one of the fluorescent derivatives thereof, such as those with alkyl or halogen substituted directly in the naphthalene nucleus. The rhodamine and the naphthaldazine are in the ratio by weight of from 1 to 3.0 to 1 to 35. The pigment may be a metal resinate, the preparation and dyeing of which are described in Examples 1-3. In one example, glyceryl phthalate is dispersed in water and dissolved in ammonium hydroxide before being mixed at 55 DEG C. with a dye solution comprising Rhodamine B Extra and Rhodamine 6GDN Extra in methyl glycol and iso-octyl phenyl ether of polyethylene glycol. An aluminium sulphate precipitant solution is added slowly and then an oil-wetting agent, e.g. heptadecenyl imidazoline. Some of the resinate dispersion may be prepared undyed, to be used as an extender. The preparations of letter-press inks, a silk screen ink, a brushing and spraying composition, a paper coating composition and a textile printing composition are described in Examples 4-9. The 2,21 dihydroxy naphthaldazine and the dyed pigment with or without the extender, are mixed with materials such as alkyd printing varnish, paste driers, kerosene, aluminium stearate, metal naphthenate driers, methacrylate resin, naphtha, glycerine, butadiene-styrene, latex anti-foaming agent, pine oil, trisodium phosphate, vinylchloride polymer, melamine formaldehyde resin, cellosolve acetate and dioctyl phthalate in a variety of formul and methods. The yellow fluorescent pigment, 2,21 dihydroxy naphthaldazine is prepared by reacting 2-hydroxy naphthaldehyde with hydrazine sulphate. With pigment ratios of from 1 to 3 to 1 to 30, up to 60 per cent of total pigment may be included in printing inks. The Rhodamine dyed pigments may be made from urea formaldehyde resins, polyvinyl benzal resins, methylene urea and silica in addition to those already mentioned.ALSO:Fluorescent coating compositions such as printing pastes and inks, textile and silk screen inks (see Groups XL (a) and IV (a)) comprise a pigment dyed with a rhodamine dye and 2,21-dihydroxy-naphthaldazine or one of the fluorescent derivatives thereof, such as those with alkyl or halogen substituted directly in the naphthalene nucleus. The rhodamine and the naphthaldazine are in the ratio by weight of from 1 to 3.0 to 1 to 35. The yellow fluorescent pigment 2,21-dihydroxy naphthaldazine is prepared by reacting 2-hydroxy naphthaldehyde with hydrazine sulphate in methanol solution.ALSO:Fluorescent coating compositions such as printing pastes and inks, textile and silk screen inks (see Groups XL(a) and IV(a)) comprise a pigment dyed with a rhodamine dye and 2.21 dihydroxy-naphthaldazine or one of the fluorescent derivatives thereof, such as those with alkyl or halogen substituted directly in the naphthalene nucleus. The rhodamine and the naphthaldazine are in the ratio by weight of from 1 to 3.0 to 1 to 35. The yellow fluorescent pigment 2, 21 dihydroxy naphthaldazine is prepared by reacting 2 - hydroxy naphthaldehyde with hydrazine sulphate in methanol solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2347053A GB769691A (en) | 1953-08-25 | 1953-08-25 | Improvements in and relating to fluorescent compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2347053A GB769691A (en) | 1953-08-25 | 1953-08-25 | Improvements in and relating to fluorescent compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB769691A true GB769691A (en) | 1957-03-13 |
Family
ID=10196136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2347053A Expired GB769691A (en) | 1953-08-25 | 1953-08-25 | Improvements in and relating to fluorescent compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB769691A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113881426A (en) * | 2021-11-25 | 2022-01-04 | 南京市产品质量监督检验院 | Preparation method of Hongbao-rhodamine B composite fluorescent probe |
-
1953
- 1953-08-25 GB GB2347053A patent/GB769691A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113881426A (en) * | 2021-11-25 | 2022-01-04 | 南京市产品质量监督检验院 | Preparation method of Hongbao-rhodamine B composite fluorescent probe |
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