GB768238A - Simultaneous metal ion concentration and ph control in chemical and biological media - Google Patents

Simultaneous metal ion concentration and ph control in chemical and biological media

Info

Publication number
GB768238A
GB768238A GB32683/53A GB3268353A GB768238A GB 768238 A GB768238 A GB 768238A GB 32683/53 A GB32683/53 A GB 32683/53A GB 3268353 A GB3268353 A GB 3268353A GB 768238 A GB768238 A GB 768238A
Authority
GB
United Kingdom
Prior art keywords
salts
alkali metal
mono
metal salts
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32683/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB768238A publication Critical patent/GB768238A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0086Processes carried out with a view to control or to change the pH-value; Applications of buffer salts; Neutralisation reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fertilizers (AREA)

Abstract

Predetermined metal ion and hydrogen ion concentrations are controlled simultaneously in a medium having a pH value in the range approximately 5 to 10, by adding to such medium a composition consisting essentially of two different alkali metal salts of a single chelating agent together with a metal complex of such chelating agent, the molar ratios of the two salts and the metal complex in such composition being in the range 1 : 1 : 4 to 1 : 4 : 1 to 4 : 1 : 1, the metal of such complex being that whose concentration is to be maintained in said medium and said chelating agent having the following general formula <FORM:0768238/IV(b)/1> where X is -CH2COOH or -CH2.CH2.COOH; A is -CH2COOH, -CH2.CH2.COOH, hydrogen, alkyl, hydroxy-alkyl, aralkyl, sulfhydryl (-CH2.SH), or an alkyl, hydroxy-alkyl, aralkyl or sulfhydryl group carrying a functional substituent which effects the ionization of the chelating agent without destroying its chelating power; B is -CH2COOH, -CH2.CH2COOH, hydrogen, alkyl, hydroxyalkyl, aralkyl, sulfhydryl, or an alkyl, hydroxyalkyl, aralkyl or sulfhydryl group carrying a functional substituent which effects the ionization of the chelating agent without destroying its chelating power; and alkylene is -CH2.CH2-, -CH(CH3) CH2- or -CH2.CH2.CH2-. Specified functional substituent groups are hydroxyl, carboxyl, ester phosphonic or sulphonic acid. The medium necessarily contains water and is preferably an aqueous solution or suspension, but the water may be present in small quantities, e.g. in distillery mashes, agar gels and soils. Specified media are (a) aqueous chemical reaction solutions or suspensions; (b) nutrient media for the growth of micro-organisms in the production of antibiotics, e.g. penicillin, vitamins and yeast; (c) hydroponic solutions for cultivating plants; and (d) aqueous solutions of iron for applying to soil or spraying plants for the treatment of iron chlorosis in plants. The examples are confined to aqueous solutions containing the compositions of the invention with complexes of various polyvalent metals and illustrate the control of pH and metal ion concentration when a portion of the said metal is removed from solution. Metals which can be "buffered" are magnesium, calcium, strontium, barium, manganese, ferrous iron, ferric iron, cobaltous cobalt, nickel, copper, zinc, cadmium, lead, rare earths, and transuranic metals. The alkali metals which are used to form the alkali metal salts of the chelating agent are sodium, potassium, lithium, rubidium and caesium. Specified chelating agents are (a) ethylene diamine tetra-acetic acid, the salts being the di-and tri-alkali metal salts; (b) dihydroxyethylethylene diamine diacetic acid, the salts being the mono- and di-alkali metal salts; (c) monobutyl ethylene diamine triacetic acid, the salts being the mono- and di-alkali metal salts; (d) monobenzyl ethylene diamine triacetic acid, the salts being the mono- and di-alkali metal salts; (e) ethylene diamine-N,N1-diacetic acid, the salts being the mono- and di-alkali metal salts; (f) diethyl ethylene diamine-N,N1-diacetic acid, the salts being the mono- and di-alkali metal salts; (g) ethylene diamine diacetic-N,N1-dipropionic acid, the salts being the mono- and di-alkali metal salts; (h) ethylene diamine-N,N1-dipropionic acid, the salts being the mono- and di-alkali metal salts; (i) monobutyl ethylene diamine-N,N1-dipropionic acid, the salts being the mono- and di-alkali metal salts; (j) ethylene diamine tetrapropionic acid, the salts being the mono- and di-alkali metal salts; (k) trimethylene diamine tetra-acetic acid, the salts being the mono- and di-alkali metal salts; and (l) propylene diamine tetra-acetic acid, the salts being the mono- and di-alkali metal salts.ALSO:Predetermined metal ion and hydrogen ion concentrations are controlled simultaneously in a medium having a pH value in the range approximately 5 to 10, by adding to such medium a composition consisting essentially of two different alkali metal salts of a single chelating agent together with a metal complex of such chelating agent, the molar ratios of the two salts and the metal complex in such composition being in the range 1:1:4 to 1:4:1 to 4:1:1 the metal of such complex being that whose concentration is to be maintained in said medium and said chelating agent having the following general formula <FORM:0768238/III/1> Where X is -CH2 COCH or -CH2 . CH3 . COOH. A is -CH2 COOH, -CH2 . CH3 . COOH, hydrogen, alkyl, hydroxy-alkyl, aralkyl, sulphydryl -CH2 . SH, or an alkyl, hydroxy-alkyl, aralkyl or sulfhydryl group carrying a functional substituent which affects the ionization of the chelating agent without destroying its chelating power; B is -CH2 COOH, -CH2 . CH2 COOH, hydrogen, alkyl, hydroxy-alkyl, aralkyl, sulfhydryl, or an alkyl, hydroxyalkyl, aralkyl or sulfhydryl group carrying a functional substituent which effects the ionization of the chelating agent without destroying its chelating power; and alkylene is -CH2 . CH3-, -CH(CH3)CH2- or CH2 . CH2 . CH2-. Specified functional substituent groups are hydroxyl, carboxyl, ester, phosphonic or sulphonic acid. The medium necessarily contains water and is preferably an aqueous solution or suspension, but the water may be present in small quantities, e.g. in distillery mashes, agar gels and soils. Specified media are (a) aqueous chemical reaction solutions or suspensions (b) nutrient media for the growth of micro-organisms in the production of antibiotics e.g. penicillin, vitamins and yeast (c) hydroponic solutions for cultivating plants, and (d) aqueous solutions of iron for applying to soil or spraying plants for the treatment of iron chlorosis in plants. The examples are confined to aqueous solutions containing the compositions of the invention with complexes of various polyvalent metals and illustrate the control of pH and metal ion concentration when a portion of the said metal is removed from solution. Metals which can be "buffered" are magnesium, calcium, strontium, barium, manganese, ferrous iron, ferric iron, cobaltous cobalt, nickel, copper, zinc, cadmium, lead, rare earths, and transuranic metals. The alkali metals which are used to form the alkali metal salts of the chelating agent are sodium, potassium, lithium, rubidium and caesium. Specified chelating agents are (a) ethylene diamine tetraacetic acid, the salts being the di- and tri-alkali metal salts (b) dihydroxyethyl-ethylene diamine diacetic acid, the salts being the mono- and dialkali metal salts (c) monobutyl ethylene diamine triacetic acid, the salts being the mono- and di-alkali metal salts, (d) monobenzyl ethylene diamine triacetic acid, the salts being the mono and di-alkali metal salts (e) ethylene diamine -N, N1-diacetic acid, the salts being the mono- and di-alkali metal salts (f) diethyl ethylene diamine -N, N1-diacetic acid, the salts being the mono- and di-alkali metal salts (g) ethylene diamine diacetic -N, N1-dipropionic acid, the salts being the mono- and di-alkali metal salts (h) ethylene diamine-N, N1-dipropionic acid, the salts being the mono and di-alkali metal salts (i) monobutyl-ethylene diamine N, N1-dipropionic acid, the salts being the mono- and di-alkali metal salts (j) ethylene diamine tetraproprionic acid, the salts being the mono- and di-alkali metal salts (k) trimethylene diamine tetraacetic acid, the salts being the mono- and di-alkali metal salts, and (1) propylene diamine tetraacetic acid, the salts being the mono- and di-alkali metal salts.ALSO:Predetermined metal ion and hydrogen ion concentrations are controlled simultaneously in a medium having a pH value in the range approximately 5 to 10, by adding to such medium a composition consisting essentially of two different alkali metal salts of a single chelating agent together with a metal complex of such chelating agent, the molar ratios of the two salts and the metal complex in such composition being in the range 1 : 1 : 4 to 1 : 4 : 1 to 4 : 1 : 1 the metal of such complex being that whose concentration is to be maintained in said medium and said chelating agent having the following general formula: <FORM:0768238/I/1> Where X is -CH2 COOH or -CH2.CH2.COOH A is -CH2 COOH, -CH2.CH2.COOH, hydrogen, alkly, hydroxyalkyl, aralkyl, sulfhydryl -CH2.SH, or an alkyl, hydroxyalkyl, aralkyl or sulfhydryl groups carrying a functional substituent which affects the ionization of the chelating agent without destroying its chelating power; B is -CH2 COOH, -CH2 COOH, hydrogen, alkyl, hydroxyalkyl, aralkyl, sulfhydryl, or an alkyl, hydroxyalkyl, aralkyl or sulfhydryl groups carrying a functional substituent which effects the ionization of the chelating agent without destroying its chelating power; and alkylene is -CH2. CH2-, -CH(CH3)CH3- or -CH2.CH2.CH2. Specified functional substituent groups are hydroxyl, carboxyl, ester phosphonic or sulphonic acid. The medium necessarily contains water and is preferably an aqueous solution or suspension, but the water may be present in small quantities e.g. in distillery meshes, agar gels and soils. Specified media are (a) aqueous chemical reaction solutions or suspensions, (b) nutrient media for the growth of microorganisms in the production of antibiotics e.g. penicillin, vitamins and yeast (c) hydroponic solutions for cultivating plants, and (d) aqueous solutions of iron for applying to soil or spraying plants for the treatment of iron chlorosis in plants. The examples are confined to aqueous solutions containing the compositions of the invention with complexes of various polyvalent metals and illustrate the control of pH and metal ion concentration when a portion of the said metal is removed from solution. Metals which can be "buffered" are magnesium, calcium, strontium, barium, manganese, ferrous iron, ferric iron, cobaltous cobalt, nickel, copper, zinc, cadmium, lead, rare earths, and transuranic metals. The alka
GB32683/53A 1952-11-25 1953-11-25 Simultaneous metal ion concentration and ph control in chemical and biological media Expired GB768238A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US768238XA 1952-11-25 1952-11-25

Publications (1)

Publication Number Publication Date
GB768238A true GB768238A (en) 1957-02-13

Family

ID=22134404

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32683/53A Expired GB768238A (en) 1952-11-25 1953-11-25 Simultaneous metal ion concentration and ph control in chemical and biological media

Country Status (1)

Country Link
GB (1) GB768238A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7903303A (en) * 1978-05-05 1979-11-07 Baensch Tetra Werke METHOD FOR THE PROCESSING OF WATER, IN PARTICULAR WATER OF AQUARIA.
FR2506286A1 (en) * 1981-05-25 1982-11-26 Crouzat Sa Ets Preparing water free from heavy metals - by use of cation exchange resin, free of calcium and organic residues, used for haemodialysis
FR2552675A1 (en) * 1983-09-30 1985-04-05 Asahi Chemical Ind PROCESS FOR SEPARATING AND PURIFYING METALLIC ELEMENTS BY DISPLACEMENT CHROMATOGRAPHY
CN115109596A (en) * 2022-07-21 2022-09-27 湖南有色金属研究院有限责任公司 Soil heavy metal stabilizer and preparation method and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7903303A (en) * 1978-05-05 1979-11-07 Baensch Tetra Werke METHOD FOR THE PROCESSING OF WATER, IN PARTICULAR WATER OF AQUARIA.
FR2424880A1 (en) * 1978-05-05 1979-11-30 Baensch Tetra Werke WATER TREATMENT PROCESS, ESPECIALLY WATER FOR AQUARIUMS
FR2506286A1 (en) * 1981-05-25 1982-11-26 Crouzat Sa Ets Preparing water free from heavy metals - by use of cation exchange resin, free of calcium and organic residues, used for haemodialysis
FR2552675A1 (en) * 1983-09-30 1985-04-05 Asahi Chemical Ind PROCESS FOR SEPARATING AND PURIFYING METALLIC ELEMENTS BY DISPLACEMENT CHROMATOGRAPHY
CN115109596A (en) * 2022-07-21 2022-09-27 湖南有色金属研究院有限责任公司 Soil heavy metal stabilizer and preparation method and application thereof
CN115109596B (en) * 2022-07-21 2023-11-24 湖南有色金属研究院有限责任公司 Soil heavy metal stabilizer and preparation method and application thereof

Similar Documents

Publication Publication Date Title
Waris The Significance for Algae of Chelating Substances in the Nutrient Solutions.
GB1304979A (en)
US2961311A (en) Metal ion control
GR67232B (en)
GB1394416A (en) Cyclopropanecarboxylates processes for producing them and compositions containing them
GB1320449A (en) T2-phosphonobutane 1,2,4-tricarboxylic acid compounds process for their preparation and their use as complex formers
AU558802B2 (en) Anionic phosphate detergent composition
GB1389621A (en) Salts of 3-hydroxy-2-hydroxy-methyl-propanesulphonic acid-1 and a process for their preparation
GB768238A (en) Simultaneous metal ion concentration and ph control in chemical and biological media
GB1437022A (en) Antimicrobial agents for the conservation of water
US4699644A (en) Plant nutrient composition
GB1456156A (en) Trace element fertilizers
GB1286837A (en) Production of metal chelates
GB1277325A (en) METHOD OF PREPARING SELENO-DERIVATIVES OF alpha-AMINO ACIDS
GB550751A (en) Improvements in or relating to the application of phosphate coatings to ferrous metal surfaces
GB1451352A (en) Method of suppressing mildew using a composition containing an alkanoic acid salt
ES8302631A1 (en) Esters of propanoic acid, preparation of these compounds, weed killers containing these compounds as active ingredients, use of such compounds and compositions for the control of weeds.
GB1244909A (en) Microbiological oxidation process
GB1224589A (en) Complex iron salts
IE33810B1 (en) 3-quinoline-carboxylic acid compounds,process for their manufacture and compositions containing them
FR2278655A1 (en) Phosphonocarboxylic acids and-chelates - useful as micronutrients for plants
GB1276589A (en) 0-alkyl-6-azauracil compounds and compositions containing the same
GB983920A (en) Improvements in or relating to the coating of seeds
GB827523A (en) New organic copper compounds and solutions and mixtures containing the same, and processes for the preparation of such compounds
JPS5611796A (en) Preparation of dicarboxylic acid by fermentation