GB767033A - Polymerisation process - Google Patents
Polymerisation processInfo
- Publication number
- GB767033A GB767033A GB11631/54A GB1163154A GB767033A GB 767033 A GB767033 A GB 767033A GB 11631/54 A GB11631/54 A GB 11631/54A GB 1163154 A GB1163154 A GB 1163154A GB 767033 A GB767033 A GB 767033A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alcohols
- esters
- acids
- lorol
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
Abstract
Terpolymers are made by copolymerizing at a temperature between 140 DEG and 170 DEG F. in the presence of a polymerization catalyst a mixture comprising (a) an ester of an alpha, betaethylenically unsaturated monocarboxylic acid with a saturated C1-C18 monohydric aliphatic alcohol, e.g. esters of acrylic, methacrylic, crotonic, isocrotonic, angelic and tiglic acids; (b) a neutral ester of an ethylenically unsaturated dicarboxylic acid containing the group <FORM:0767033/IV(a)/1> with a C1-C18 saturated monohydric aliphatic alcohol, e.g. esters of maleic, fumaric, citraconic and mesaconic acids; and (c) a compound of the formula <FORM:0767033/IV(a)/2> wherein X is hydrogen, methyl or a halogen, and Y is RCOO-, wherein R is a C1-C18 hydrocarbon group, or Y is a cyanide radical, or Y is a monocyclic aromatic group, e.g. vinyl, isopropenyl and alpha-chlorvinyl acetates, acrylonitrile and styrene. Alcohols used in preparing the esters of the unsaturated acids are lauryl and 2-ethylhexyl alcohols, palm kernel alcohols and the alcohols sold under the Registered Trade Marks "Lorol" and "Lorol B". Since the terpolymers are desirably oil-soluble the alcohols preferably have more than 8 carbon atoms in the molecule. Catalysts specified are benzoyl, lauroyl and hydrogen peroxides, cumene and urea hydroperoxides, tert.-butyl perbenzoate, ammonium or potassium persulphates and redox systems such as persulphate-thiosulphate and persulphate-aldehyde systems. Also present during polymerization may be modifiers such as thiols, sulphuric acid, hydrochloric acid, petroleum sulphonic acids and alcohol. Polymerization may be carried out in bulk, in solution in solvents such as naphtha, lubricating oil fractions, white oils, benzene, toluene, ethers, carbon tetrachloride or chloroform, or in emulsion in water containing an emulsifier such as soap. The terpolymers are added to lubricating oils pour-point depressants and viscosity index improvers.ALSO:Lubricating compositions comprise a mineral or synthetic lubricating oil and, as a viscosity index improver and pour-point depressant, a terpolymer obtained by the copolymerization of (a) an ester of an alpha, beta-ethylenically unsaturated monocarboxylic acid with a saturated C1-C18 monohydric aliphatic alcohol, e.g. esters of acrylic, methacrylic, crotonic, isocrotonic, angelic and tiglic acids, (b) a neutral ester of an ethylenically unsaturated dicarboxylic acid containing the group:- <FORM:0767033/III/1> with a C1-C18 saturated monohydric aliphatic alcohol, e.g. esters of maleic, fumaric, citraconic and mesaconic acids, and (c) a compound of the general formula:- <FORM:0767033/III/2> wherein X is hydrogen, methyl or a halogen and Y is R COO- wherein R is a C1-C18 hydrocarbon group, or Y is a cyanide radical, or Y is a monocyclic aromatic group, e.g. vinyl, isopropenyl, and alpha-chlorvinyl acetates and acrylonitrile. Alcohols specified which are used in preparing the esters of the unsaturated acids are lauryl and 2 - ethylhexyl alcohols, palm kernel alcohols and the alcohols sold under the Registered Trade Marks "Lorol" and "Lorol B," the preferred alcohols being those having more than 8 carbon atoms in the molecule. Synthetic lubricating oils mentioned are those comprising esters and/or complex esters.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB11631/54A GB767033A (en) | 1954-04-22 | 1954-04-22 | Polymerisation process |
DEE10558A DE1032460B (en) | 1954-04-22 | 1955-04-15 | Lubricating oil |
FR1129999D FR1129999A (en) | 1954-04-22 | 1955-04-22 | Combined agent for improving the viscosity index and lowering the de-icing point |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB11631/54A GB767033A (en) | 1954-04-22 | 1954-04-22 | Polymerisation process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB767033A true GB767033A (en) | 1957-01-30 |
Family
ID=9989840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11631/54A Expired GB767033A (en) | 1954-04-22 | 1954-04-22 | Polymerisation process |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1032460B (en) |
FR (1) | FR1129999A (en) |
GB (1) | GB767033A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1133848B (en) * | 1960-02-26 | 1962-07-26 | Exxon Research Engineering Co | Lubricating oil |
DE1245526B (en) * | 1960-09-15 | 1967-07-27 | Exxon Research Engineering Co | Lubricating oil additive |
GB2160536A (en) * | 1984-06-21 | 1985-12-24 | Elf Aquitaine | Polymeric additives usable for inhibition of the deposit of paraffins in crude oils |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3003987A (en) * | 1957-11-14 | 1961-10-10 | Alco Oil & Chemical Corp | Copolymer of acrylic acid ester, method of making, and use of said polymer to coat textile fabrics |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE692989C (en) * | 1936-01-17 | 1940-06-29 | I G Farbenindustrie Akt Ges | Process for the production of shaped articles |
-
1954
- 1954-04-22 GB GB11631/54A patent/GB767033A/en not_active Expired
-
1955
- 1955-04-15 DE DEE10558A patent/DE1032460B/en active Pending
- 1955-04-22 FR FR1129999D patent/FR1129999A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1133848B (en) * | 1960-02-26 | 1962-07-26 | Exxon Research Engineering Co | Lubricating oil |
DE1245526B (en) * | 1960-09-15 | 1967-07-27 | Exxon Research Engineering Co | Lubricating oil additive |
GB2160536A (en) * | 1984-06-21 | 1985-12-24 | Elf Aquitaine | Polymeric additives usable for inhibition of the deposit of paraffins in crude oils |
Also Published As
Publication number | Publication date |
---|---|
DE1032460B (en) | 1958-06-19 |
FR1129999A (en) | 1957-01-29 |
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