GB758577A - Process for purifying acrylonitrile from acetylene hydrocarbons - Google Patents

Process for purifying acrylonitrile from acetylene hydrocarbons

Info

Publication number
GB758577A
GB758577A GB18404/54A GB1840454A GB758577A GB 758577 A GB758577 A GB 758577A GB 18404/54 A GB18404/54 A GB 18404/54A GB 1840454 A GB1840454 A GB 1840454A GB 758577 A GB758577 A GB 758577A
Authority
GB
United Kingdom
Prior art keywords
acrylonitrile
polymers
acetylene hydrocarbons
purifying acrylonitrile
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18404/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA, Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montedison SpA
Publication of GB758577A publication Critical patent/GB758577A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/32Separation; Purification; Stabilisation; Use of additives
    • C07C253/34Separation; Purification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Acrylonitrile containing acetylene polymers (such as divinylacetylene and ethynylbutadiene) is purified by effecting selective catalytic hydrogenation of said polymers with a Raney metal or noble metal at temperature from 0 DEG to 50 DEG C. in an atmosphere of hydrogen under a pressure of from 1 to 20 atmospheres and separating pure acrylonitrile from the hydrogenation product by fractional distillation. The catalyst may comprise Raney nickel or cobalt suspended in the nitrile to be treated, or platinum or palladium supported upon an inert stationary carrier in a catalysis chamber. Specification 557,436, [Group IV], is referred to.
GB18404/54A 1953-07-08 1954-06-23 Process for purifying acrylonitrile from acetylene hydrocarbons Expired GB758577A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT758577X 1953-07-08

Publications (1)

Publication Number Publication Date
GB758577A true GB758577A (en) 1956-10-03

Family

ID=11315844

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18404/54A Expired GB758577A (en) 1953-07-08 1954-06-23 Process for purifying acrylonitrile from acetylene hydrocarbons

Country Status (1)

Country Link
GB (1) GB758577A (en)

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