GB757740A - Stable aqueous emulsions of the oil-in-water type containing as binding agents hardenable aminoplasts and natural or synthetic rubber and process for making them - Google Patents
Stable aqueous emulsions of the oil-in-water type containing as binding agents hardenable aminoplasts and natural or synthetic rubber and process for making themInfo
- Publication number
- GB757740A GB757740A GB1313/54A GB131354A GB757740A GB 757740 A GB757740 A GB 757740A GB 1313/54 A GB1313/54 A GB 1313/54A GB 131354 A GB131354 A GB 131354A GB 757740 A GB757740 A GB 757740A
- Authority
- GB
- United Kingdom
- Prior art keywords
- urea
- emulsion
- water
- solution
- borax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title abstract 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 9
- 229920003180 amino resin Polymers 0.000 title abstract 4
- 229920003051 synthetic elastomer Polymers 0.000 title abstract 4
- 239000005061 synthetic rubber Substances 0.000 title abstract 4
- 229920003052 natural elastomer Polymers 0.000 title abstract 3
- 229920001194 natural rubber Polymers 0.000 title abstract 3
- 239000011230 binding agent Substances 0.000 title 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 12
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 12
- 239000002253 acid Substances 0.000 abstract 9
- 239000005018 casein Substances 0.000 abstract 9
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 9
- 235000021240 caseins Nutrition 0.000 abstract 9
- 239000004202 carbamide Substances 0.000 abstract 8
- 235000013877 carbamide Nutrition 0.000 abstract 8
- 229910021538 borax Inorganic materials 0.000 abstract 7
- 239000004328 sodium tetraborate Substances 0.000 abstract 7
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 7
- 239000000243 solution Substances 0.000 abstract 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 229910021529 ammonia Inorganic materials 0.000 abstract 6
- 229920001577 copolymer Polymers 0.000 abstract 6
- 239000000049 pigment Substances 0.000 abstract 6
- 239000004744 fabric Substances 0.000 abstract 5
- 229920000126 latex Polymers 0.000 abstract 5
- 239000004816 latex Substances 0.000 abstract 5
- 241000416162 Astragalus gummifer Species 0.000 abstract 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 4
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 239000004753 textile Substances 0.000 abstract 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229920001615 Tragacanth Polymers 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 3
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 3
- 239000008384 inner phase Substances 0.000 abstract 3
- 239000000196 tragacanth Substances 0.000 abstract 3
- 229940116362 tragacanth Drugs 0.000 abstract 3
- 235000010487 tragacanth Nutrition 0.000 abstract 3
- 229920000742 Cotton Polymers 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 abstract 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 abstract 2
- 229920006173 natural rubber latex Polymers 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- 239000008385 outer phase Substances 0.000 abstract 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical class O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 2
- 238000010025 steaming Methods 0.000 abstract 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 abstract 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 abstract 1
- 229920002955 Art silk Polymers 0.000 abstract 1
- 239000005696 Diammonium phosphate Substances 0.000 abstract 1
- 239000004640 Melamine resin Substances 0.000 abstract 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 abstract 1
- 239000004902 Softening Agent Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000019445 benzyl alcohol Nutrition 0.000 abstract 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019838 diammonium phosphate Nutrition 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N dimethyl-butadiene Natural products CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 230000003165 hydrotropic effect Effects 0.000 abstract 1
- 239000010985 leather Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000007764 o/w emulsion Substances 0.000 abstract 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 abstract 1
- 229950005308 oxymethurea Drugs 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/30—Proteins; Protein hydrolysates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
An aqueous emulsion of the oil-in-water type comprises (1) in one inner phase a natural or synthetic rubber, (2) in another inner phase a hardenable water-insoluble aminoplast soluble in organic solvents and modified with an alcohol whose solubility in water does not exceed that of n-butanol, and (3) an outer phase containing acid casein. The emulsion may be used for treating textile fabric, leather or paper or for applying pigment dyestuffs to textiles. Specified synthetic rubbers are aqueous emulsions obtained from butadiene, isoprene, dimethylbutadiene or chloroprene or copolymers of these compounds with acrylonitrile, methyl acrylate or styrene. Specified aminoplasts are condensates obtained from formaldehyde and urea, thiourea, guanidine, biuret, dicyandiamide, melamine or benzoguanamine and specified modifying alcohols are butanol, amyl alcohol, hexyl alcohol, cyclohexanol and benzyl alcohol. The casein may be solubilized with borax, ammonia, caustic soda, triethanolamine or morpholine and it may be protected against the action of formaldehyde by adding a hydro-tropic carbamide, e.g. urea, thiourea or formamide and/or by treating it with ethylene oxide. The emulsions may also contain pigments, filling materials, softening agents, vulcanizing agents, hardening agents, agents imparting hydrophobic properties, stabilizers, antioxidants or thickening agents, e.g. tragacanth. In examples (1) acid casein is dissolved in water containing borax, triethanolamine and ammonia and into this solution there is emulsified a solution in cyclo hexanol of dimethylol urea etherified with cyclohexanol; the emulsion is mixed with a latex containing a copolymer of butadiene and acrylonitrile; (2) a solution in butanol of a butylated melamineformaldehyde condensate is emulsified in an aqueous solution containing acid casein (free from lactalbumen), urea, thiourea and borax. After adding ammonia and water the emulsion is evaporated and added to a natural rubber latex. The product is diluted with water and ammonium thiocyanate solution and is used to impregnate cotton; (3) to the melamine resin emulsion of Example (2) is added an aqueous dispersion of a copolymer of butadiene and acrylonitrile. After adding a benzene-in-water emulsion or tragacanth the product may be used for fixing pigments, e.g. titanium white, iron oxide, carbon black, azo pigments or phthalocyanine derivatives on textiles; (4) a solution in butanol of a butylated urea-formaldehyde resin is emulsified with an aqueous solution of acid casein, urea, thiourea and borax and after adding ammonia and water the emulsion is evaporated and added to a latex of a copolymer of butadiene and acrylonitrile. The product is mixed with tragacanth, ammonium thiocyanate solution and a pigment dyestuff and is used to print fabrics; (5) an aqueous solution of acid casein, borax, and ammonia is treated with ethylene oxide and emulsified with a butylated melamine-formaldehyde condensate. The emulsion is mixed with a latex containing sodium oleate and a copolymer of butadiene and acrylonitrile and after adding diammonium phosphate dries to a hard film; (6) an aqueous solution containing acid casein, morpholine, urea and foramide is emulsified with a solution in butyl alcohol of a butylated urea-formaldehyde condensate and mixed with a latex containing a copolymer of butadiene and acrylonitrile.ALSO:Textile fabrics are treated with an oil-in-water emulsion comprising, in the inner phase, a natural or synthetic rubber and a hardenable water-insoluble aminoplast soluble in organic solvents and modified with an alcohol whose solubility in water does not exceed that of n-butanol and, in the outer phase acid caein. In examples (2) a cotton fabric is given a dressing which is fast to washing by first impregnating it with an aqueous emulsion containing natural rubber latex, a butanolmodified melamine-formaldehyde condensate, acid casein free from lactalbumen, urea, thiourea, borax, ammonia and ammonium thiocyanate, and thereafter drying and steaming the fabric; (4) artificial silk or staple film of regenerated cellulose is given a matt effected or coloured by first impregnating it with an aqueous emulsion containing a butadene-acrylonitrile latex, a butanol-modified urea-formaldehyde condensate, acid casein, urea, thiourea, borax, tragacanth, ammonium thiocyanate and either titan white or a coloured pigment, and thereafter steaming or heating to 140-200 DEG C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH757740X | 1953-01-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB757740A true GB757740A (en) | 1956-09-26 |
Family
ID=4534414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1313/54A Expired GB757740A (en) | 1953-01-16 | 1954-01-15 | Stable aqueous emulsions of the oil-in-water type containing as binding agents hardenable aminoplasts and natural or synthetic rubber and process for making them |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE525748A (en) |
| CH (1) | CH323921A (en) |
| FR (1) | FR1095071A (en) |
| GB (1) | GB757740A (en) |
| NL (2) | NL184366B (en) |
-
0
- BE BE525748D patent/BE525748A/xx unknown
- NL NL94772D patent/NL94772C/xx active
- NL NLAANVRAGE7613857,A patent/NL184366B/en unknown
-
1953
- 1953-01-16 CH CH323921D patent/CH323921A/en unknown
-
1954
- 1954-01-14 FR FR1095071D patent/FR1095071A/en not_active Expired
- 1954-01-15 GB GB1313/54A patent/GB757740A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL94772C (en) | |
| FR1095071A (en) | 1955-05-26 |
| BE525748A (en) | |
| CH323921A (en) | 1957-08-31 |
| NL184366B (en) |
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