GB757333A - Improvements in and relating to the production of hydrogen and carbon monoxide synthesis gas - Google Patents

Improvements in and relating to the production of hydrogen and carbon monoxide synthesis gas

Info

Publication number
GB757333A
GB757333A GB19213/53A GB1921353A GB757333A GB 757333 A GB757333 A GB 757333A GB 19213/53 A GB19213/53 A GB 19213/53A GB 1921353 A GB1921353 A GB 1921353A GB 757333 A GB757333 A GB 757333A
Authority
GB
United Kingdom
Prior art keywords
oxygen
oil
steam
reaction
synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19213/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA, Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montedison SpA
Publication of GB757333A publication Critical patent/GB757333A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

In the production of synthesis gas comprising essentially hydrogen and carbon monoxide from fuel oils containing hydrocarbons by reaction with steam and oxygen, the oil is introduced into the reaction chamber by atomization with steam, and a catalyst is mixed with the oil prior to or during its introduction. The oxygen may be introduced separately, e.g. as air mixed with additional steam, and may be given a whirling motion to assist mixing. The amount of oxygen used may be regulated to control the reaction temperature, e.g. at 1100 DEG -1200 DEG C. The steam and oxygen are preheated, e.g. to 600-700 DEG C. The oil is heated to 100 DEG -150 DEG C. to increase fluidity and is injected together with superheated steam at a pressure of several atmospheres through nozzles having diverging jets. Suitable catalysts are salts of alkaline earth metals, e.g. calcium or magnesium nitrate in an amount of at least 1 gram per litre of oil. The catalyst is suspended in the oil or added as an aqueous solution. An example describes the reaction of heavy fuel oil with oxygen and steam. If air is used instead of oxygen, a nitrogen-containing gas suitable for the synthesis of ammonia is obtained. Reference is also made to the use of the gas for the synthesis of methanol.
GB19213/53A 1952-07-11 1953-07-10 Improvements in and relating to the production of hydrogen and carbon monoxide synthesis gas Expired GB757333A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT757333X 1952-07-11

Publications (1)

Publication Number Publication Date
GB757333A true GB757333A (en) 1956-09-19

Family

ID=11315820

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19213/53A Expired GB757333A (en) 1952-07-11 1953-07-10 Improvements in and relating to the production of hydrogen and carbon monoxide synthesis gas

Country Status (1)

Country Link
GB (1) GB757333A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2421844A1 (en) * 1978-04-03 1979-11-02 Basf Ag PROCESS FOR THE PRODUCTION OF GAS CONTAINING HYDROGEN AND CARBON OXIDE
WO2013117854A1 (en) * 2012-02-09 2013-08-15 Cotaver Process, system and installation for treating liquid and/or pasty hydrocarbon materials
US9284854B2 (en) 2010-02-01 2016-03-15 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for producing a source of thermodynamic energy by CO2 conversion from carbon-containing raw materials
US9327986B2 (en) 2010-02-01 2016-05-03 SEE—Soluções, Energia e Meio Ambiente Ltda. Method for recycling carbon dioxide CO2
US9340735B2 (en) 2010-02-01 2016-05-17 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for producing hydrogen from carbon-containing raw materials
US9505997B2 (en) 2010-02-01 2016-11-29 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for supplying thermal energy to a thermal processing system from the gasification of dry, carbon-containing raw materials, followed by oxidation, and installation for operating this system

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2421844A1 (en) * 1978-04-03 1979-11-02 Basf Ag PROCESS FOR THE PRODUCTION OF GAS CONTAINING HYDROGEN AND CARBON OXIDE
GB2022128A (en) * 1978-04-03 1979-12-12 Basf Ag Manufacture of gas containing hydrogen and carbon monoxide
US9284854B2 (en) 2010-02-01 2016-03-15 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for producing a source of thermodynamic energy by CO2 conversion from carbon-containing raw materials
US9327986B2 (en) 2010-02-01 2016-05-03 SEE—Soluções, Energia e Meio Ambiente Ltda. Method for recycling carbon dioxide CO2
US9340735B2 (en) 2010-02-01 2016-05-17 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for producing hydrogen from carbon-containing raw materials
US9505997B2 (en) 2010-02-01 2016-11-29 SEE—Soluções, Energia e Meio Ambiente Ltda. Method and system for supplying thermal energy to a thermal processing system from the gasification of dry, carbon-containing raw materials, followed by oxidation, and installation for operating this system
WO2013117854A1 (en) * 2012-02-09 2013-08-15 Cotaver Process, system and installation for treating liquid and/or pasty hydrocarbon materials
FR2986800A1 (en) * 2012-02-09 2013-08-16 Cotaver PROCESS, SYSTEM AND SYSTEM FOR TREATING LIQUID AND / OR PASSIZED HYDROCARBON MATERIALS
US9327971B2 (en) 2012-02-09 2016-05-03 See-Soluções, Energia E Meio Ambiente Ltda Process, system and installation for treating liquid and/or pasty hydrocarbon materials

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