GB752508A - Improvements in or relating to resins from steam-cracked petroleum fractions - Google Patents

Improvements in or relating to resins from steam-cracked petroleum fractions

Info

Publication number
GB752508A
GB752508A GB16175/54A GB1617554A GB752508A GB 752508 A GB752508 A GB 752508A GB 16175/54 A GB16175/54 A GB 16175/54A GB 1617554 A GB1617554 A GB 1617554A GB 752508 A GB752508 A GB 752508A
Authority
GB
United Kingdom
Prior art keywords
fraction
steam
dimers
boiling
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16175/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US366061A external-priority patent/US2773051A/en
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB752508A publication Critical patent/GB752508A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B04—CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04C—APPARATUS USING FREE VORTEX FLOW, e.g. CYCLONES
    • B04C5/00—Apparatus in which the axial direction of the vortex is reversed
    • B04C5/12—Construction of the overflow ducting, e.g. diffusing or spiral exits
    • B04C5/13—Construction of the overflow ducting, e.g. diffusing or spiral exits formed as a vortex finder and extending into the vortex chamber; Discharge from vortex finder otherwise than at the top of the cyclone; Devices for controlling the overflow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B04—CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04C—APPARATUS USING FREE VORTEX FLOW, e.g. CYCLONES
    • B04C5/00—Apparatus in which the axial direction of the vortex is reversed
    • B04C5/20—Apparatus in which the axial direction of the vortex is reversed with heating or cooling, e.g. quenching, means
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/002—Cooling of cracked gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Cyclones (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Soluble petroleum resins are prepared by blending a C5 steam-cracked petroleum fraction, relatively free of cyclopentadienes and dimers and boiling up to 38 DEG C., with from 10 to 50 per cent of cyclopentadiene dimers, and polymerizing the blend in liquid phase at from -20 DEG to 90 DEG C., preferably 0 DEG to 75 DEG C., in the presence of a Friedel-Crafts catalyst. The C5 fraction may be obtained from a C5 to C9 fraction boiling up to 140 DEG C., obtained from a steam-cracked unsaturated petroleum oil by heating the fraction, e.g. between 100 DEG and 220 DEG F., to dimerise the cyclopentadiene, separating the dimers, for example as the bottom fraction of a distillation tower and distilling to obtain a mixture of the C5 fraction boiling at up to 38 DEG C., and isoprene, which may then be separated, e.g. by extractive distillation with acetone. In the polymerization, which may be continuous, the catalyst may be added continuously or batchwise and the products washed with water, caustic or dilute sulphuric acid, or the catalyst residues precipitated as a methanol complex and filtered off. The polymeric resin, stripped free of unreacted components or low molecular weight products, may be used as a base for paints, varnishes, inks and floor tiles.
GB16175/54A 1953-07-03 1954-06-01 Improvements in or relating to resins from steam-cracked petroleum fractions Expired GB752508A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US366061A US2773051A (en) 1953-07-03 1953-07-03 Preparation of resins from c5 fractions and cyclopentadiene dimers
US751667XA 1953-07-21 1953-07-21

Publications (1)

Publication Number Publication Date
GB752508A true GB752508A (en) 1956-07-11

Family

ID=26756505

Family Applications (2)

Application Number Title Priority Date Filing Date
GB16175/54A Expired GB752508A (en) 1953-07-03 1954-06-01 Improvements in or relating to resins from steam-cracked petroleum fractions
GB16935/54A Expired GB751667A (en) 1953-07-03 1954-06-09 Improvements in or relating to process and apparatus for separating and quenching oil products

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB16935/54A Expired GB751667A (en) 1953-07-03 1954-06-09 Improvements in or relating to process and apparatus for separating and quenching oil products

Country Status (4)

Country Link
DE (1) DE955889C (en)
FR (2) FR1102843A (en)
GB (2) GB752508A (en)
NL (1) NL90669C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112851836A (en) * 2020-12-31 2021-05-28 华东理工大学 Emission reduction and consumption reduction method and device for cold polymerization production of C5 resin
CN112851857A (en) * 2020-12-31 2021-05-28 华东理工大学 Separation, consumption reduction and emission reduction method and device in C5 petroleum resin production process

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2668720B1 (en) * 1990-11-07 1993-06-11 Stein Industrie CYCLONE FOR SEPARATION BY CENTRIFUGATION OF A MIXTURE OF GASES AND SOLID PARTICLES WITH HEAT RECOVERY.
FR2985900A1 (en) 2012-01-24 2013-07-26 Frederic Hehn IMPROVED INTRAOCULAR LENS AND METHOD FOR MANUFACTURING THE SAME

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1911476A (en) * 1933-05-30 Apparatus for converting hydrocarbon oils
GB409875A (en) * 1933-03-09 1934-05-10 Standard Oil Co Indiana Improvements in and relating to the cracking of hydrocarbon oils
DE859444C (en) * 1943-05-27 1952-12-15 Basf Ag Process and device for the continuous pressure hydrogenation of coals, tars and mineral oils in the liquid phase
DE879091C (en) * 1944-10-08 1953-06-11 Basf Ag Process for the continuous pressure hydrogenation of carbons, tars and mineral oils in the liquid phase

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112851836A (en) * 2020-12-31 2021-05-28 华东理工大学 Emission reduction and consumption reduction method and device for cold polymerization production of C5 resin
CN112851857A (en) * 2020-12-31 2021-05-28 华东理工大学 Separation, consumption reduction and emission reduction method and device in C5 petroleum resin production process
CN112851836B (en) * 2020-12-31 2022-05-17 华东理工大学 Emission reduction and consumption reduction method and device for cold polymerization production of C5 resin
CN112851857B (en) * 2020-12-31 2022-06-21 华东理工大学 Separation, consumption reduction and emission reduction method and device in C5 petroleum resin production process

Also Published As

Publication number Publication date
NL90669C (en)
FR1102842A (en) 1955-10-26
GB751667A (en) 1956-07-04
FR1102843A (en) 1955-10-26
DE955889C (en) 1957-01-10

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