GB746521A - Improvements in method of treating arsenical sulphide cobalt ores - Google Patents

Improvements in method of treating arsenical sulphide cobalt ores

Info

Publication number
GB746521A
GB746521A GB3212953A GB3212953A GB746521A GB 746521 A GB746521 A GB 746521A GB 3212953 A GB3212953 A GB 3212953A GB 3212953 A GB3212953 A GB 3212953A GB 746521 A GB746521 A GB 746521A
Authority
GB
United Kingdom
Prior art keywords
cobalt
matte
iron
arsenic
roasted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3212953A
Inventor
Lyall John Lichty
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUEBEC METALLURG IND Ltd
Original Assignee
QUEBEC METALLURG IND Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUEBEC METALLURG IND Ltd filed Critical QUEBEC METALLURG IND Ltd
Priority to GB3212953A priority Critical patent/GB746521A/en
Publication of GB746521A publication Critical patent/GB746521A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/04Obtaining nickel or cobalt by wet processes
    • C22B23/0407Leaching processes
    • C22B23/0415Leaching processes with acids or salt solutions except ammonium salts solutions
    • C22B23/043Sulfurated acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/005Preliminary treatment of ores, e.g. by roasting or by the Krupp-Renn process
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/02Obtaining nickel or cobalt by dry processes
    • C22B23/025Obtaining nickel or cobalt by dry processes with formation of a matte or by matte refining or converting into nickel or cobalt, e.g. by the Oxford process
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Cobalt arsenical sulphide ores containing iron are treated to produce a solution containing most of the cobalt and having a ratio cobalt:iron of at least 4:1 by weight; the process comprising treating the material to form a matte containing not more than 3 per cent of arsenic preferably in an electric furnace at a temperature high enough to vaporize the arsenic and arsenic sulphides, crushing the matte until at least 80 per cent of it is minus 200 mesh and then subjecting it to an oxidizing roast to eliminate most of the sulphur, sulphating the roasted material and then subjecting it to a second roast in the presence of air between 575 DEG C. and 650 DEG C. until a solution obtained by leaching the roasted material with water has a ratio of cobalt:iron of at least 4:1. Roasted matte may be recycled by adding it to the ores supplied to the electric furnace, and the treatment of an ore concentrate containing also silver, nickel, and copper to produce a solution containing their sulphates is described. U.S.A. Specification 1,590,525 is referred to.ALSO:Cobalt arsenical sulphide ores containing iron are treated to produce a solution containing most of the cobalt and having a ratio cobalt: iron of at least 4:1 by weight; the process comprises treating the material to form a matte containing not more than 3 per cent of arsenic, preferably in an electric furnace at a temperature high enough to vaporise the arsenic and arsenical sulphides, crushing the matte until at least 80 per cent of it is minus 200 mesh and then subjecting it to an oxidising roast to eliminate most of the sulphur, sulphating the roasted material and then subjecting it to a second roast in the presence of air between 575 DEG C. and 650 DEG C. until a solution obtained by leaching the roasted material with water has a ratio cobalt: iron of at least 4:1. Roasted matte may be recycled by adding it to the ores supplied to the electric furnace, and the treatment of an ore concentrate containing also silver, nickel and copper is described. U.S.A. Specification 1,590,525 is referred to.
GB3212953A 1953-11-19 1953-11-19 Improvements in method of treating arsenical sulphide cobalt ores Expired GB746521A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3212953A GB746521A (en) 1953-11-19 1953-11-19 Improvements in method of treating arsenical sulphide cobalt ores

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3212953A GB746521A (en) 1953-11-19 1953-11-19 Improvements in method of treating arsenical sulphide cobalt ores

Publications (1)

Publication Number Publication Date
GB746521A true GB746521A (en) 1956-03-14

Family

ID=10333720

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3212953A Expired GB746521A (en) 1953-11-19 1953-11-19 Improvements in method of treating arsenical sulphide cobalt ores

Country Status (1)

Country Link
GB (1) GB746521A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3761565A (en) * 1968-09-17 1973-09-25 C Arrizaga Method of roasting sulphide ores
EP0139121A1 (en) * 1983-08-09 1985-05-02 Bayer Ag Method for the production of sulfur dioxide
GB2181421A (en) * 1985-09-23 1987-04-23 Eberhard Gock Process for the recovery of noble metals from ore-concentrates

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3761565A (en) * 1968-09-17 1973-09-25 C Arrizaga Method of roasting sulphide ores
EP0139121A1 (en) * 1983-08-09 1985-05-02 Bayer Ag Method for the production of sulfur dioxide
GB2181421A (en) * 1985-09-23 1987-04-23 Eberhard Gock Process for the recovery of noble metals from ore-concentrates
GB2181421B (en) * 1985-09-23 1989-11-29 Eberhard Gock Process for the recovery of noble metals from ore-concentrates

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