GB739883A - Improvements relating to the production of alkyl tin chlorides - Google Patents
Improvements relating to the production of alkyl tin chloridesInfo
- Publication number
- GB739883A GB739883A GB13377/54A GB1337754A GB739883A GB 739883 A GB739883 A GB 739883A GB 13377/54 A GB13377/54 A GB 13377/54A GB 1337754 A GB1337754 A GB 1337754A GB 739883 A GB739883 A GB 739883A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tin
- monochloride
- trichloride
- reaction mixture
- chlorides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 alkyl tin chlorides Chemical class 0.000 title abstract 4
- 239000011541 reaction mixture Substances 0.000 abstract 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 2
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 abstract 2
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 abstract 2
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 2
- RGINKKCBAWYXBX-UHFFFAOYSA-K C(CCCCCCCC)[Sn](Cl)(Cl)Cl Chemical class C(CCCCCCCC)[Sn](Cl)(Cl)Cl RGINKKCBAWYXBX-UHFFFAOYSA-K 0.000 abstract 1
- FVFLIQMADUVDSP-UHFFFAOYSA-M chloro(tripropyl)stannane Chemical compound CCC[Sn](Cl)(CCC)CCC FVFLIQMADUVDSP-UHFFFAOYSA-M 0.000 abstract 1
- BITGXQXJJKVDRX-UHFFFAOYSA-M chloro-tris(3,3,5-trimethylhexyl)stannane Chemical compound CC(CC[Sn](CCC(CC(C)C)(C)C)(CCC(CC(C)C)(C)C)Cl)(CC(C)C)C BITGXQXJJKVDRX-UHFFFAOYSA-M 0.000 abstract 1
- WCTXJBYIXVVFCF-UHFFFAOYSA-M chlorotin Chemical compound [Sn]Cl WCTXJBYIXVVFCF-UHFFFAOYSA-M 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 abstract 1
- 238000001640 fractional crystallisation Methods 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- 238000001256 steam distillation Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 abstract 1
- WNPANDSCCONHNH-UHFFFAOYSA-K trichloro(3,3,5-trimethylhexyl)stannane Chemical compound CC(CC[Sn](Cl)(Cl)Cl)(CC(C)C)C WNPANDSCCONHNH-UHFFFAOYSA-K 0.000 abstract 1
- CCCDVPNBEHCRRA-UHFFFAOYSA-K trichloro(pentyl)stannane Chemical compound CCCCC[Sn](Cl)(Cl)Cl CCCDVPNBEHCRRA-UHFFFAOYSA-K 0.000 abstract 1
- NFJGHYXSHMSYFA-UHFFFAOYSA-K trichloro(propyl)stannane Chemical compound CCC[Sn](Cl)(Cl)Cl NFJGHYXSHMSYFA-UHFFFAOYSA-K 0.000 abstract 1
- YSCVYRUCAPMZFG-UHFFFAOYSA-K trichlorotin Chemical compound Cl[Sn](Cl)Cl YSCVYRUCAPMZFG-UHFFFAOYSA-K 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Alkyl tin chlorides are prepared by reacting equimolar quantities of an alkyl tin and tin tetrachloride without application of external heat. The reaction mixture is maintained between 0 DEG and 100 DEG C. and preferably between 0 DEG and 20 DEG C. by cooling, thus increasing the yield of the monoalkyl tin trichloride and the trialkyl tin monochloride. Specified compounds which may be prepared include propyl tin trichloride, tripropyl tin monochloride, butyl tin trichloride, tributyl tin monochloride, amyl tin trichloride, triamyl tin monochloride, nonyl tin chlorides such as 3,3,5-trimethylhexyl tin trichloride and tri(3,3,5 - trimethylhexyl)tin monochloride. The reaction mixture may be separated by vacuum fractionation, fractional crystallization, or steam distillation. In an example tin tetrachloride is added to tetrabutyl tin with stirring at room temperature. The reaction mixture after standing is vacuum fractionated at 100 mm. pressure to give a fraction comprising substantially pure butyl tin trichloride. The still residue is refrigerated and centrifuged to remove a portion of the dichloride, leaving an impure tributyl tin monochloride contaminated with the dibutyl tin dichloride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US739883XA | 1953-06-10 | 1953-06-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB739883A true GB739883A (en) | 1955-11-02 |
Family
ID=22117024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB13377/54A Expired GB739883A (en) | 1953-06-10 | 1954-05-07 | Improvements relating to the production of alkyl tin chlorides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB739883A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1161893B (en) * | 1961-03-28 | 1964-01-30 | Studiengesellschaft Kohle Mbh | Process for the conversion of highly alkylated to lower alkylated tin compounds |
| US3251871A (en) * | 1961-11-15 | 1966-05-17 | Hoechst Ag | Process for the isolation of pure, watersoluble alkyl tin trihalides |
| US3459779A (en) * | 1962-12-18 | 1969-08-05 | Studiengesellschaft Kohle Mbh | Process for the production of alkyltin trihalides |
| US4379878A (en) | 1978-06-08 | 1983-04-12 | M&T Chemicals Inc. | Food-grade vinyl halide polymer compositions stabilized with monoalkyltin compounds |
| CN110423248A (en) * | 2019-08-09 | 2019-11-08 | 南通名泰化工有限公司 | A kind of preparation method of high purity glass hot-end coating liquid monobutyl-tin-trichloride |
-
1954
- 1954-05-07 GB GB13377/54A patent/GB739883A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1161893B (en) * | 1961-03-28 | 1964-01-30 | Studiengesellschaft Kohle Mbh | Process for the conversion of highly alkylated to lower alkylated tin compounds |
| US3248411A (en) * | 1961-03-28 | 1966-04-26 | Studiengesellschaft Kohle Mbh | Process for the conversion of highly alkylated tin compounds into lower alkylated tin halides |
| US3251871A (en) * | 1961-11-15 | 1966-05-17 | Hoechst Ag | Process for the isolation of pure, watersoluble alkyl tin trihalides |
| US3459779A (en) * | 1962-12-18 | 1969-08-05 | Studiengesellschaft Kohle Mbh | Process for the production of alkyltin trihalides |
| US4379878A (en) | 1978-06-08 | 1983-04-12 | M&T Chemicals Inc. | Food-grade vinyl halide polymer compositions stabilized with monoalkyltin compounds |
| CN110423248A (en) * | 2019-08-09 | 2019-11-08 | 南通名泰化工有限公司 | A kind of preparation method of high purity glass hot-end coating liquid monobutyl-tin-trichloride |
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