GB736100A - Improvements in detergent compositions - Google Patents

Improvements in detergent compositions

Info

Publication number
GB736100A
GB736100A GB2938752A GB2938752A GB736100A GB 736100 A GB736100 A GB 736100A GB 2938752 A GB2938752 A GB 2938752A GB 2938752 A GB2938752 A GB 2938752A GB 736100 A GB736100 A GB 736100A
Authority
GB
United Kingdom
Prior art keywords
acids
detergent
substituted
amino
hydroxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2938752A
Inventor
Allan Alsbury
Olavi Harva
Thomas Gwilym Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Publication of GB736100A publication Critical patent/GB736100A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

2 - Hydroxy - 4 - amino - 1,3,5 - triazines, substituted in the 6-position with a hydrocarbon or substituted hydrocarbon radical, are prepared by heating a monocarboxylic acid with dicyandiamide to 120-250 DEG C., preferably 140-200 DEG C. In an example, 2-hydroxy-4-amino - 6 - hendecyl - 1,3,5 - triazine is prepared by heating equimolecular proportions of lauric acid and dicyandiamide in nitrogen to 185 DEG C. for 2 hours, and extracting the product with aqueous caustic soda solution and ether. Other specified monocarboxylic acids which may be used are acetic, butyric, caprylic, stearic, oleic and benzoic acids, the monochlorinated acids of palm-kernel oil, the acids of palm oil, palm-kernel oil and hardened rape oil, tall oil and rosin. Some of the above triazine derivatives are also obtainable by reacting an aliphatic carboxylic acid chloride with potassium hydrosulphide, treating the product with dicyandiamide to yield a 2-mercapto - 4 - amino - 6 - alkyl - 1,3,5 - triazine, and oxidizing the latter with hydrogen peroxide. Triazine derivatives of the formula XRX, where each X is a 2-hydroxy-4-amino-1,3,5-triazinyl residue linked at the 6-position to R, which is a divalent hydrocarbon or substituted hydrocarbon radical, are obtained by heating a dicarboxylic acid with 2 mols. of dicyandiamide. The use of succinic, sebacic and terephthalic acids in this reaction is mentioned. U.S.A. Specification 2,431,644 is referred to. The products are intended for use in detergent compositions (see Group III).ALSO:To reduce the tendency of aqueous detergent solutions to tarnish certain metals and alloys, e.g. German silver, there is included in the detergent compositions (1) a 2-hydroxy-4-amino-1,3,5-triazine substituted in the 6-position with a hydrocarbon group of 1-25 carbon atoms; or (2) a compound of the formula XRX, where each X is a 2-hydroxy-4-amino-1,3,5-triazinyl residue linked at the 6-position to R, which is a divalent hydrocarbon group of 1-25 carbon atoms; the hydrocarbon group in each case may be substituted. These additives are obtainable by heating a mono- or di-carboxylic acid with dicyandiamide (see Group IV (b)), and the crude product of this reaction may be used as such, without isolating the additives therefrom. Specified carboxylic acids from which suitable additives are so obtainable include acetic, caprylic, lauric, stearic, oleic, benzoic, succinic, sebacic and terephthalic acids, the acids derived from palm oil, monochlorinated acids from palm-kernel oil, and tall oil or rosin. The proportion of additive may be 0.05-10 per cent, preferably 0.5-2.5 per cent, based on the detergent. The detergent compositions may have a basis of condensed phosphates, e.g. of sodium or potassium tripolyphosphate, pyrophosphate or hexametaphosphate, or they may contain a non-ionic detergent, e.g. a condensation product of an alkylphenol with ethylene oxide, or a sulphated or sulphonated detergent, e.g. an alkylaryl sulphonate such as a dodecylbenzene sulphonate, or an alkyl sulphate such as sodium lauryl sulphate, or a substituted alkyl sulphonate such as a fatty acid ester of N-hydroxyethyl sulphoacetamide. The compositions may also contain alkali-metal sulphates, chlorides, silicates, borates, carbonates and meta- and ortho-phosphates, magnesium chloride, salts of carboxymethyl cellulose, fluorescent whitening agents and perfumes; peroxy compounds, e.g. sodium perborate, are preferably not included. Specific compositions are described, and comparative experimental results are given. U.S.A. Specification 2,431,644 is referred to.ALSO:To reduce the tendency of aqueous detergent solutions to tarnish certain metals and alloys, e.g. German silver, there is included in the detergent compositions (1) a 2-hydroxy-4-amino-1,3,5-triazine substituted in the 6-position with a hydrocarbon group of 1-25 carbon atoms; or (2) a compound of the formula XRX, where each X is a 2-hydroxy-4-amino-1,3,5-triazinyl residue linked at the 6-position to R, which is a divalent hydrocarbon group of 1-25 carbon atoms; the hydrocarbon group in each case may be substituted. These additives are obtainable by heating a mono- or di-carboxylic acid with dicyandiamide (see Group IV (b)), and the crude product of this reaction may be used as such, without isolating the additives therefrom. Specified carboxylic acids from which suitable additives are so obtainable include acetic, caprylic, lauric, stearic, oleic, benzoic, succinic, sebacic and terephthalic acids, the acids derived from palm oil, monochlorinated acids from palm-kernel oil, and tall oil or rosin. The proportion of additive may be 0.05-10 per cent, preferably 0.5-2.5 per cent, based on the detergent. The detergent compositions may have a basis of condensed phosphates, e.g. of sodium or potassium tripolyphosphate, pyrophosphate or hexametaphosphate, or they may contain a nonionic detergent, e.g. a condensation product of an alkylphenol with ethylene oxide, or a sulphated or sulphonated detergent, e.g. an alkylaryl sulphonate such as a dodecylbenzene sulphonate, or an alkyl sulphate such as sodium lauryl sulphate, or a substituted alkyl sulphonate such as a fatty acid ester of N-hydroxyethyl sulphoacetamide. The compositions may also contain alkali-metal sulphates, chlorides, silicates, borates, carbonates and meta- and ortho-phosphates, magnesium chloride, salts of carboxymethyl cellulose, fluorescent whitening agents and perfumes; peroxy compounds, e.g. sodium perborate, are preferably not included. Specific compositions are described, and comparative experimental results are given. U.S.A. Specification 2,431,644 is referred to.
GB2938752A 1953-11-20 1952-11-20 Improvements in detergent compositions Expired GB736100A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL182995 1953-11-20

Publications (1)

Publication Number Publication Date
GB736100A true GB736100A (en) 1955-08-31

Family

ID=19750631

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2938752A Expired GB736100A (en) 1953-11-20 1952-11-20 Improvements in detergent compositions

Country Status (6)

Country Link
BE (1) BE524454A (en)
CH (1) CH337288A (en)
DE (1) DE1006105B (en)
FR (1) FR1143530A (en)
GB (1) GB736100A (en)
NL (1) NL81069C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0854183A1 (en) * 1997-01-15 1998-07-22 Henkel Kommanditgesellschaft auf Aktien Automatic dishwashing compositon with silver protection agent
EP0928828A1 (en) * 1997-12-31 1999-07-14 Henkel KGaA Alkylaminotriazole-containing granular components for automatic dishwashing compositions and process for preparing them

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0854183A1 (en) * 1997-01-15 1998-07-22 Henkel Kommanditgesellschaft auf Aktien Automatic dishwashing compositon with silver protection agent
EP0928828A1 (en) * 1997-12-31 1999-07-14 Henkel KGaA Alkylaminotriazole-containing granular components for automatic dishwashing compositions and process for preparing them

Also Published As

Publication number Publication date
CH337288A (en) 1959-03-31
NL81069C (en) 1955-01-15
FR1143530A (en) 1957-10-02
BE524454A (en)
DE1006105B (en) 1957-04-11

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