GB731111A - Vinyltoluene-unsaturated ester interpolymers and method of making same - Google Patents

Vinyltoluene-unsaturated ester interpolymers and method of making same

Info

Publication number
GB731111A
GB731111A GB7902/53A GB790253A GB731111A GB 731111 A GB731111 A GB 731111A GB 7902/53 A GB7902/53 A GB 7902/53A GB 790253 A GB790253 A GB 790253A GB 731111 A GB731111 A GB 731111A
Authority
GB
United Kingdom
Prior art keywords
bodied
oil
linseed
soyabean
interpolymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7902/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB731111A publication Critical patent/GB731111A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/12Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F242/00Copolymers of drying oils with other monomers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/16Homopolymers or copolymers of alkyl-substituted styrenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Vinyl toluene (20-80 parts by weight) is interpolymerized with non-conjugated drying oils (80-20 parts by weight) by heating at 120-300 DEG C. in the substantial absence of added solvents and with or without catalysts such as cumene hydroperoxide and di-t-butyl peroxide. The drying oils may be linseed or soyabean oil, raw, refined, alkali-treated or heat-bodied, or modified with polyhydric alcohols, e.g. ethylene or propylene glycol, glycerine or pentaerythritol and polybasic acids, e.g. phthalic anhydride. In examples, vinyl toluene (60 per cent meta and 40 per cent para) mixed with cumene hydroperoxide is added portionwise to heat-bodied linseed oil heated under reflux to 230 DEG C.; un-bodied linseed, bodied and unbodied soyabean oils and a long-oil soyabean oil-modified glycerol phthalate alkyd resin are interpolymerized using t-butyl peroxide as catalyst to form clear ungelled resins, which may be dissolved in mineral spirits to give varnishes or further reacted to form alkyd resins. Specification 622,948 is referred to.
GB7902/53A 1952-04-30 1953-03-23 Vinyltoluene-unsaturated ester interpolymers and method of making same Expired GB731111A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US731111XA 1952-04-30 1952-04-30

Publications (1)

Publication Number Publication Date
GB731111A true GB731111A (en) 1955-06-01

Family

ID=22111800

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7902/53A Expired GB731111A (en) 1952-04-30 1953-03-23 Vinyltoluene-unsaturated ester interpolymers and method of making same

Country Status (4)

Country Link
BE (1) BE519236A (en)
FR (1) FR1079180A (en)
GB (1) GB731111A (en)
NL (2) NL177648B (en)

Also Published As

Publication number Publication date
NL82790C (en)
NL177648B (en)
FR1079180A (en) 1954-11-26
BE519236A (en)

Similar Documents

Publication Publication Date Title
GB675166A (en) Tall oil esters of synthetic resinous polyhydric alcohols
GB670119A (en) Improvements in or relating to the manufacture of styrene modified alkyd resins
GB428864A (en) Improved drying oils and their application
GB731111A (en) Vinyltoluene-unsaturated ester interpolymers and method of making same
GB709011A (en) Improvements in or relating to the production of polymeric products from styrene andunsaturated fatty compounds
GB859467A (en) Improvements in or relating to drying oils
US2518497A (en) Unsaturated fatty acid modified rosin esters and process of preparing same
GB963969A (en) Process for producing oil-modified alkyd resins
GB796355A (en) Oil-modified alkyd resins
US2411111A (en) Treatment of polyene compounds
GB572823A (en) Improvements in or relating to coating compositions
US2307794A (en) Process for producing synthetic
GB837876A (en) Oil-modified resins
GB987191A (en) Epoxy modified alkyd resins
GB961611A (en) Improvements in and relating to alkyd resins
GB795501A (en) Alkyd resin
GB647352A (en) Improvements in and relating to styrene copolymers
GB640836A (en) Improvements in or relating to the manufacture of interpolymers of styrene with unsaturated fatty acids and derivatives thereof
GB599546A (en) Improvements in or relating to coating compositions
GB696379A (en) Improvements in or relating to backing members for machine sanding apparatus
GB316914A (en) Process for the manufacture of new resin-like products
GB672224A (en) Modified alkyd resins
GB744273A (en) Improvements in or relating to the production of modified alkyd resins
US2118926A (en) Synthetic resin and method of producing
GB679144A (en) Improvements in styrene-drying oil modified alkyd resins