GB724714A - Propylene glycol bis(bromoacetate) - Google Patents
Propylene glycol bis(bromoacetate)Info
- Publication number
- GB724714A GB724714A GB8447/53A GB844753A GB724714A GB 724714 A GB724714 A GB 724714A GB 8447/53 A GB8447/53 A GB 8447/53A GB 844753 A GB844753 A GB 844753A GB 724714 A GB724714 A GB 724714A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propylene glycol
- bromoacetate
- glycol bis
- solvent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/62—Halogen-containing esters
- C07C69/63—Halogen-containing esters of saturated acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises a -propylene glycol bis-(bromoacetate) The compound is prepared by reacting one molecular proportion of a -propylene glycol with at least two molecular proportions of monobromoacetic acid, preferably at a temperature between 50 DEG and 150 DEG C. and in the presence of an esterification catalyst. Concentrated phosphoric and sulphuric acids and toluene sulphonic acid are the catalysts mentioned. Preferably the reactants and catalyst are mixed in a water-immiscible solvent, e.g. toluene or ethylene dichloride and conveniently the reaction is carried out at the boiling point of the reaction mixture when the water produced and the solvent are distilled off and the latter is recycled. In an example a -propylene glycol and monobromoacetic acid are dissolved in ethylene dichloride, and heated with a sulphuric acid catalyst water, solvent being distilled off and the latter recycled. The product may be used in plastic or herbicidal compositions (see Group VI).ALSO:a -Propylene glycol bis (bromoacetate) (see Group IV (b)) is soluble in organic solvents and an active ingredient in contact herbicidal compositions.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US724714XA | 1952-05-01 | 1952-05-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB724714A true GB724714A (en) | 1955-02-23 |
Family
ID=22107811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8447/53A Expired GB724714A (en) | 1952-05-01 | 1953-03-26 | Propylene glycol bis(bromoacetate) |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB724714A (en) |
-
1953
- 1953-03-26 GB GB8447/53A patent/GB724714A/en not_active Expired
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