GB709941A - Process for the production of undecimposed cellulose oxidation products, including their alkali and alkaline earth metal salts, and the use of such products as detergents, soaking agents, cation-exchangers, and filter aids - Google Patents

Process for the production of undecimposed cellulose oxidation products, including their alkali and alkaline earth metal salts, and the use of such products as detergents, soaking agents, cation-exchangers, and filter aids

Info

Publication number
GB709941A
GB709941A GB17175/51A GB1717551A GB709941A GB 709941 A GB709941 A GB 709941A GB 17175/51 A GB17175/51 A GB 17175/51A GB 1717551 A GB1717551 A GB 1717551A GB 709941 A GB709941 A GB 709941A
Authority
GB
United Kingdom
Prior art keywords
product
sodium
oxidation
oxidized
washed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17175/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Original Assignee
Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO filed Critical Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Publication of GB709941A publication Critical patent/GB709941A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/223Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin oxidised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16Organic material
    • B01J39/18Macromolecular compounds
    • B01J39/22Cellulose or wood; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • C08B15/04Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Detergent Compositions (AREA)

Abstract

Cellulose containing lignin or resin is subjected to a controlled oxidation until the product contains from 0.5 to 5.5 milligram equivalents of base binding groups per gram of dry oxidation product so as to obtain a product which is suitable for use as a washing, cleaning, soaking, or cation-exchange agent, or as a filter aid. The product may be used for decreasing the pH in chemical processes without causing any harmful colouring of the materials treated. The product has substantially the same molecular chain length as the original cellulose and substantially the same fibrous appearance. The cellulosic material may be wood, straw, flax scutchings, algae, sea weeds, sawdust, wood pulp, chips or shavings. The oxidation product may be soluble in alkali solutions. If a product of a light colour is desired, the raw material may be submitted to a preliminary boiling with water, digestion with acids, or treatment with a decolourizing agent. The oxidized material may be subjected to a bleaching treatment. Oxidation may be effected with oxides of nitrogen or with nitric acid. After the oxidation, the excess of reagents and inorganic reaction products may be removed from the material before it is used for washing or other purposes. Thus after oxidation with nitrogen dioxide or nitrogen monoxide the reaction product, which contains nitric acid, nitrous acid and nitrogen oxides, is washed with water containing no ions with which the cellulose product will form water-insoluble compounds, or with water containing such ions but also containing a sufficient concentration of hydrogen ions to prevent such insoluble compounds from being formed. If desired the crude cellulose oxidation product may be added directly to soaking, cleaning, or detergent baths, provided that the potential alkalinity thereof is such that the ultimate pH of the baths is at least 5. The crude product may be neutralized, or washed with a neutral salt solution, and then added to a detergent agent or bath. Oxidation may be effected with nitrogen dioxide dissolved in an organic solvent, e.g. carbon tetrachloride, or with nitric acid and nitrogen dioxide or nitric acid and a nitrite in presence of water. In an example, wood shavings are treated with nitrogen dioxide vapour at room temperature and in presence of air for 91 hours, and then washed. The product has a content of 3.0 milligram equivalents of base-binding groups per gram of dry substance. It dissolves in a 2 per cent. caustic soda solution. In another example, wood sawdust is treated for 48 hours at room temperature with a solution of 5 kilograms of sodium nitrite in 11 litres of 65 per cent. nitric acid, until a product containing 2.0 milligram equivalents of base-binding groups per gram of dry substance is obtained. Other examples describe the application of the oxidized cellulose product to washing, soaking, and base-exchanging operations. Specifications 531,283, 605,367, and 653,702, [Group III], and U.S.A. Specification 2,232,990 are referred to.ALSO:Textiles are soaked or washed with the aid of compositions containing a lignin-or resin-containing cellulose material which has been subjected to controlled oxidation until the product contains 0.5-5.5 milligram equivalents of base-binding groups per gram of dry oxidation product (see Group IV(a)). The product may be used in the form of an alkali-metal or other salt. In an example, a cotton fabric is washed at 60 DEG C. in water of 1 French degree of hardness containing, per litre 0.8 grams of sodium soap, 6 gm. of sodium carbonate and 0.1 gm. of oxidized coniferous wood powder. In another example, body, table, and kitchen linen is washed with a soapy liquid comprising a sodium soap with a fatty acid content of 85 per cent, sodium carbonate, sodium metasilicate, and a product obtained by oxidizing oak wood shavings with nitrogen dioxide. Soiled household and body linen is soaked in water of 24 French degrees of hardness containing as soaking agent a mixture of sodium carbonate, water glass, and oxidized wood dust. The laundry is then washed at 95 DEG C. in water containing a condensation product of the sodium salt of methyl taurine with the acid chlorides of olein, sodium carbonate, sodium sulphate, sodium trisilicate, and oxidized wood dust. Fillers, perfumes, colouring matter, fluorescent substances, bleaching agents such as perborates or percarbonates, or ethers, esters or oxidation products of higher polyoses may be included in the detergent compositions.ALSO:A lignin- or resin-containing cellulose material is subjected to controlled oxidation until the product contains from 0.5 to 5.5 milligram equivalents of base-binding groups per gram of dry oxidation product (see Group IV (a)), and the product is incorporated in soaking, washing and cleansing compositions. The product may be used in the form of a salt, e.g. an alkali-metal salt. Preferably the cellulose oxidation product is washed free from excess of reagents and other reaction products, formed during the oxidation treatment, before it is used as a washing agent. Fillers, perfumes, colouring matter, fluorescent substances, bleaching agents such as perborates and percarbonates, or derivatives of higher polyoses may be included in the compositions. In an example a cotton fabric is washed at 60 DEG C. in water of 1 French degree of hardness containing, per litre, 0.8 gm. of a sodium soap with a fatty acid content of 85 per cent. 6 gm. of sodium carbonate and 0.1 gm. of oxidized coniferous wood powder. In another example body, table, and kitchen linen is washed with a soapy liquid comprising a sodium soap with a fatty acid content of 85 per cent, sodium carbonate, sodium metasilicate, and a product obtained by oxidizing oak wood shavings with nitrogen dioxide. In another example a detergent for household purposes comprises the sodium salt of dodecyl toluene sulphonic acid, oxidized flax scutchings, sodium trisilicate, sodium perborate, sodium sulphate, the sodium salt of ethylenediamine - tetramethyl carboxylic acid, and the sodium salt of 4.41-bis-(2-chloro-4-ethanolamine) - 1.3.5 - triazyl (6) - diaminostil - bene-2.21\h -disulphonic acid. In another example, soiled household and body linen is soaked in water of 24 French degrees of hardness containing, as soaking agent, a mixture of sodium carbonate, water glass and oxidized wood dust. The laundry is then washed at 95 DEG C. in water containing a condensation product of the sodium salt of methyl taurine with the acid chlorides of olein, sodium carbonate, sodium sulphate, sodium trisilicate and oxidized deciduous wood dust. In another example a washing and cleansing agent comprises sodium salts of sulphonic acids of high molecular weight hydrocarbons, sodium salts of fatty acids of high molecular weight, common salt, sodium carbonate, sodium salt of carboxymethyl cellulose and oxidized straw.ALSO:An oxidation product of a lignum-containing or resin-containing cellulose material, in which oxidation has proceeded until the product contains from 0.5 to 5.5 milligram equivalents of base-binding groups per gram of dry oxidation product (see Group IV(a)), is used as a cationexchanging material or as a filter-aid. When used as a filter-aid it simultaneously reduces the content of di- and poly-valent ions, such as calcium ions, in the filtrate. In an example, oxidized deciduous wood shavings are put into a column 10 c.m. in height, and water of a hardness of 19 French degrees is passed through the column and thereby softened. The base-exchanging material may be regenerated by a solution of common salt.
GB17175/51A 1950-07-22 1951-07-19 Process for the production of undecimposed cellulose oxidation products, including their alkali and alkaline earth metal salts, and the use of such products as detergents, soaking agents, cation-exchangers, and filter aids Expired GB709941A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL307604X 1950-07-22

Publications (1)

Publication Number Publication Date
GB709941A true GB709941A (en) 1954-06-02

Family

ID=19783534

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17175/51A Expired GB709941A (en) 1950-07-22 1951-07-19 Process for the production of undecimposed cellulose oxidation products, including their alkali and alkaline earth metal salts, and the use of such products as detergents, soaking agents, cation-exchangers, and filter aids

Country Status (2)

Country Link
CH (1) CH307604A (en)
GB (1) GB709941A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010076292A1 (en) 2008-12-29 2010-07-08 Unilever Plc Structured aqueous detergent compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010076292A1 (en) 2008-12-29 2010-07-08 Unilever Plc Structured aqueous detergent compositions
US8450260B2 (en) 2008-12-29 2013-05-28 Conopco, Inc. Structured aqueous detergent compositions

Also Published As

Publication number Publication date
CH307604A (en) 1955-06-15

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