GB703005A - Emulsion copolymerization of vinyl monomers and mono-esters of unsaturated dicarboxylic acids - Google Patents
Emulsion copolymerization of vinyl monomers and mono-esters of unsaturated dicarboxylic acidsInfo
- Publication number
- GB703005A GB703005A GB6025/51A GB602551A GB703005A GB 703005 A GB703005 A GB 703005A GB 6025/51 A GB6025/51 A GB 6025/51A GB 602551 A GB602551 A GB 602551A GB 703005 A GB703005 A GB 703005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- sodium
- mono
- copolymer
- unsaturated dicarboxylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/12—Esters of phenols or saturated alcohols
- C08F222/16—Esters having free carboxylic acid groups, e.g. monoalkyl maleates or fumarates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
A polymerizable organic monomer having within its structure the group H2C=C<, excluding substituted styrenes, is reacted with a monoester of an alpha, beta-unsaturated dicarboxylic acid in the presence of a polymerization catalyst, an emulsifying agent and water, to produce an aqueous emulsion of the copolymer. The monomer may be vinyl acetate, an acrylate or methacrylate, styrene or vinylidene chloride and the mono-ester may be formed by the reaction of maleic, fumaric, itaconic, citraconic or chlormaleic acid with methyl, ethyl, propyl, isopropyl, butyl, lauryl, benzyl, chlorethyl or cyanoethyl alcohol, or a glycol. Catalysts specified are benzoyl and hydrogen peroxides, tertiary butyl hydroperoxide and ammonium and potassium persulphates, which may be activated with compounds of vanadium, chromium, iron or copper, such as potassium dichromate, ferrous sulphate, ferric chloride and chromium nitrate, or with sodium or potassium bisulphite or thioglycollic acid. The emulsifying agent may be polyvinyl alcohol, carboxymethyl cellulose, raw or partially converted starch, a styrene-maleic anhydride copolymer or the sodium salt of alkyl aryl polyether sulphonate, which may be used with the addition of wetting agents such as the dioctyl ester of sodium sulphosuccinic acid, sodium lauryl sulphate, sulphated fatty esters, polyethylene glycol dioleate, cholesterol, sodium salt of condensed alkyl aryl sulphonic acid, monooleate of sorbitan polyoxyethylene, and sorbiton monopalmitate. Calcium carbonate may be added to maintain pH near neutral and sodium carbonate may be added as a buffer when using thioclycollic acid as activator. The copolymer emulsions may be used as adhesives and as coating materials. Specifications 593,519, 688,291, [Group IV (b)], 691,364 and 697,604 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US703005XA | 1950-08-31 | 1950-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB703005A true GB703005A (en) | 1954-01-27 |
Family
ID=22094460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6025/51A Expired GB703005A (en) | 1950-08-31 | 1951-03-13 | Emulsion copolymerization of vinyl monomers and mono-esters of unsaturated dicarboxylic acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB703005A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2914495A (en) * | 1956-04-17 | 1959-11-24 | Borden Co | Water paint comprising pigment and aqueous emulsion of polyvinyl acetate and waxy maize starch |
DE1108908B (en) * | 1959-04-02 | 1961-06-15 | Dynamit Nobel Ag | Process for the polymerization of vinyl compounds |
US3061472A (en) * | 1959-04-23 | 1962-10-30 | Staley Mfg Co A E | Sizing hydrophobic fibers with acrylate polymers and gelatinized starch or graft copolymers thereof |
US3061471A (en) * | 1959-04-23 | 1962-10-30 | Staley Mfg Co A E | Sizing hydrophobic fibers with graft copolymers of gelatinized starch and acrylates |
US3133890A (en) * | 1958-09-26 | 1964-05-19 | Borden Co | Water resistant starch adhesive |
US4940741A (en) * | 1988-06-17 | 1990-07-10 | National Starch And Chemical Investment Holding Corporation | Process for the production of hardboard |
US5536779A (en) * | 1991-10-07 | 1996-07-16 | Basf Aktiengesellschaft | Aqueous polymer dispersions |
-
1951
- 1951-03-13 GB GB6025/51A patent/GB703005A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2914495A (en) * | 1956-04-17 | 1959-11-24 | Borden Co | Water paint comprising pigment and aqueous emulsion of polyvinyl acetate and waxy maize starch |
US3133890A (en) * | 1958-09-26 | 1964-05-19 | Borden Co | Water resistant starch adhesive |
DE1108908B (en) * | 1959-04-02 | 1961-06-15 | Dynamit Nobel Ag | Process for the polymerization of vinyl compounds |
US3061472A (en) * | 1959-04-23 | 1962-10-30 | Staley Mfg Co A E | Sizing hydrophobic fibers with acrylate polymers and gelatinized starch or graft copolymers thereof |
US3061471A (en) * | 1959-04-23 | 1962-10-30 | Staley Mfg Co A E | Sizing hydrophobic fibers with graft copolymers of gelatinized starch and acrylates |
US4940741A (en) * | 1988-06-17 | 1990-07-10 | National Starch And Chemical Investment Holding Corporation | Process for the production of hardboard |
US5536779A (en) * | 1991-10-07 | 1996-07-16 | Basf Aktiengesellschaft | Aqueous polymer dispersions |
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