GB701993A - Improvements in or relating to rust inhibiting agents and compositions - Google Patents
Improvements in or relating to rust inhibiting agents and compositionsInfo
- Publication number
- GB701993A GB701993A GB9768/51A GB976851A GB701993A GB 701993 A GB701993 A GB 701993A GB 9768/51 A GB9768/51 A GB 9768/51A GB 976851 A GB976851 A GB 976851A GB 701993 A GB701993 A GB 701993A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- mercapto
- carbon atoms
- reacting
- agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/084—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/34—Lubricating-sealants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/40—Generators or electric motors in oil or gas winning field
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/42—Flashing oils or marking oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
Abstract
The invention relates to rust inhibiting agents having the general formulae <FORM:0701993/IV (b)/1> wherein R is an alkyl, alkenyl or cycloaliphatic group preferably containing 2 to 21 carbon atoms, R1 is an alkylene group of preferably 2 to 6 carbon atoms and R11 and R111 are hydrogen or alkyl groups, the total number of carbon atoms in both R11 and R111 together preferably being not greater than 21. They may be prepared by esterifying a mono- or di-carboxylic acid with a mercapto alkanol and then reacting the ester thus formed with a fatty acid which contains one or two chlorine atoms in the a -position or the ester may be reacted with an alkali metal salt of such chlorinated acid and the resulting product converted into the free acid. The esterification may be effected with the aid of an esterification catalyst such as p-toluene sulphonic acid or sulpho salicylic acid and a solvent. The resulting mercapto alkanol is then preferably reacted with the chlorinated acid in a solvent in presence of a metallic base or the reactants are converted into their mercaptides and carboxylate salts and then reacted together, normally at about 10-90 DEG C. Suitable acids for the esterification are propionic, butyric, caproic, nonanoic, lauric, stearic, teracrylic, oleic, succinic, adipic, sebacic and erucic acids. Specified mercapto alkanols are mercapto-ethanol, mercapto-n-butanol, mercapto-isopropanol and mercapto-n-hexanol. The chlorinated acids include mono- and di-chloroacetic acids, a -chlor propionic acid, a -chloro-n-butyric acid, a -chloro isobutyric acid and a -chlorolauric acid. Suitable solvents are isopropyl alcohol, ethyl alcohol, acetone and methyl ethyl ketone, all with or without the addition of water. Examples describe products prepared by reacting mercapto-ethanol with oleic acid, lauric acid and nonanoic acid followed by reaction with mono-chlor acetic acid. The agents may be used in lubricants, liquid fuels, paints and polishes, (see Group III).ALSO:Lubricants, liquid fuels, polishes, paints and sprays comprise as rust-inhibiting agents compounds of the general formulae:- <FORM:0701993/III/1> wherein R is an alkyl, alkenyl or cyclo aliphatic group preferably containing 2 to 21 carbon atoms, R1 is an alkylene group of preferably 2 to 6 carbon atoms and R11 and R111 are hydrogen or alkyl groups, the total number of carbon atoms in both R11 and R111 together being preferably not greater than 21. The agents may be used in any petroleum hydrocarbon solvent, e.g. naphthas, spindle oils or light or heavy lubricating oil fractions. They may be used in lubricants in conjunction with detergents, pour depressants, thickeners, extreme pressure agents, plastic-type products, cut - back asphalt, microcrystalline waxes and synthetic waxes. They may be used in lubricating oils in amounts up to about 5 per cent., or in concentrates up to 50 per cent. Examples describe products obtained by reacting monochloracetic acid with intermediates obtained by reacting mercapto-ethanol with oleic acid, lauric acid and nonanoic acid respectively and their incorporation in solvent-extracted Mid-continent lubricating oil bases containing di-tert.-butyl-p-cresol as oxidation inhibitor to form turbine oils. Many other like reactants are mentioned.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US182421A US2644793A (en) | 1950-08-30 | 1950-08-30 | Rust inhibiting composition |
Publications (1)
Publication Number | Publication Date |
---|---|
GB701993A true GB701993A (en) | 1954-01-06 |
Family
ID=22668398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9768/51A Expired GB701993A (en) | 1950-08-30 | 1951-04-26 | Improvements in or relating to rust inhibiting agents and compositions |
Country Status (2)
Country | Link |
---|---|
US (1) | US2644793A (en) |
GB (1) | GB701993A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4737300A (en) * | 1984-05-15 | 1988-04-12 | Ciba-Geigy Corporation | Additives for materials |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL110620C (en) * | 1957-12-02 | |||
US3041284A (en) * | 1957-12-02 | 1962-06-26 | Shell Oil Co | Lubricating compositions |
US3920700A (en) * | 1971-07-19 | 1975-11-18 | Lubrizol Corp | Esters of sulfur-containing hydroxy acids |
US5599779A (en) * | 1996-03-20 | 1997-02-04 | R. T. Vanderbilt Company, Inc. | Synergistic rust inhibitors and lubricating compositions |
US5714441A (en) * | 1996-07-12 | 1998-02-03 | Exxon Research And Engineering Company | Additive combination to reduce deposit forming tendencies and improve antioxidancy of aviation turbine oils |
US6043199A (en) * | 1997-08-26 | 2000-03-28 | Exxon Research And Engineering Co. | Corrosion inhibiting additive combination for turbine oils |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2201535A (en) * | 1937-08-07 | 1940-05-21 | Benjamin R Harris | Lipophilic-hydrophilic derivatives of thio compounds |
US2462200A (en) * | 1945-09-06 | 1949-02-22 | Sinclair Refining Co | Process for making alpha, alphathiodialiphatic acids |
US2449996A (en) * | 1945-11-28 | 1948-09-28 | Goodrich Co B F | Preparation of sulfur containing dicarboxylic acids |
US2477356A (en) * | 1945-12-03 | 1949-07-26 | Sinclair Refining Co | Turbine oil |
US2451895A (en) * | 1946-06-08 | 1948-10-19 | Shell Dev | Synthetic grease |
US2503401A (en) * | 1949-03-26 | 1950-04-11 | Standard Oil Co | Lubricants |
-
1950
- 1950-08-30 US US182421A patent/US2644793A/en not_active Expired - Lifetime
-
1951
- 1951-04-26 GB GB9768/51A patent/GB701993A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4737300A (en) * | 1984-05-15 | 1988-04-12 | Ciba-Geigy Corporation | Additives for materials |
Also Published As
Publication number | Publication date |
---|---|
US2644793A (en) | 1953-07-07 |
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