GB694795A - Improvements in or relating to a process of treating steep liquor and the product resulting therefrom - Google Patents

Improvements in or relating to a process of treating steep liquor and the product resulting therefrom

Info

Publication number
GB694795A
GB694795A GB25363/50A GB2536350A GB694795A GB 694795 A GB694795 A GB 694795A GB 25363/50 A GB25363/50 A GB 25363/50A GB 2536350 A GB2536350 A GB 2536350A GB 694795 A GB694795 A GB 694795A
Authority
GB
United Kingdom
Prior art keywords
steep liquor
lactic acid
calcium
water
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25363/50A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corn Products Refining Co
Original Assignee
Corn Products Refining Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corn Products Refining Co filed Critical Corn Products Refining Co
Publication of GB694795A publication Critical patent/GB694795A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/48Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process of treating corn steep liquor or sorghum grain steep liquor comprises incubating the steep liquor to form lactic acid therein, adding sulphuric acid to decrease the pH to a value not exceeding 2.0, removing the lactic acid, adding an alkaline earth metal hydroxide to adjust the pH to about 5.5 to 7.5, autoclaving the entire mixture at about 10 to 20 pounds per square inch steam pressure, separating the liquid and solid phases and drying the liquid phase. Either light steep liquor, i.e. that drawn directly from the steeps, or heavy steep liquor, i.e. that concentrated to about 30 DEG B<\>e, is satisfactory. The lactic acid may be removed by extraction with butanol or any alcohol selected from butyl, amyl or hexyl alcohols, thus butanol may be added to the acidified steep liquor and the mixture agitated to extract the lactic acid or the extraction may be effected in continuous countercurrent manner. The extracting alcohol may be anhydrous or water-laden. The extract containing the lactic acid is then separated and treated to convert the lactic acid therein to the ester, e.g. by concentrating under vacuum and then refluxing, or by evaporating at atmospheric pressure until essentially all of the water is removed and then either evaporating or refluxing at atmospheric pressure to complete the esterification. The esterified liquor is then cooled and the pH adjusted to 4.5 to 6.0 to prevent hydrolysis and steam is then passed through rapidly until the distillate layer no longer separates into two phases; the lactic acid ester is recovered from the upper layer of the distillate by fractional distillation. The acidified steep liquor is then treated for the recovery of a nutrient for micro-organisms by first removing residual extract by means of steam and then adding an alkaline earth metal hydroxide, especially calcium hydroxide, to adjust the pH to 5.5 to 7.5 and the material is then autoclaved as with steam as described above. The autoclaved material is then filtered, e.g. by centrifugation, preferably at 80-90 DEG C., and the cake obtained consisting mainly of calcium phytate and calcium sulphate is washed with water and the centrifugates combined and spray dried to yield a nutrient soluble in water and containing nitrogeneous materials, together with inorganic material and small amounts of carbohydrates and salts of lactic acid. The filter cake containing calcium phytate and calcium sulphate is then treated for recovery of purified calcium phytate by dissolving the latter in hydrochloric acid at a pH of about 1.0 to 2.0 and filtering or centrifuging the suspension to leave the undissolved calcium sulphate as filter cake. The filtrate is then treated with calcium hydroxide suspension to adjust the pH to 5.0 to 5.5 so as to precipitate the calcium phytate which is then separated and dried. An example is given in which corn steep liquor is employed as starting material, and butanol is used as the lactic acid extractant, butyl lactate, calcium phytate and nutrient material being recovered as above.ALSO:Nitrogenous materials useful as nutrients for certain micro organisms are recovered from corn steep liquor or sorghum grain steep liquor by incubating the steep liquor to form lactic acid therein, adding sulphuric acid to decrease the pH to a value not exceeding 2.0, removing the lactic acid, adding an alkaline earth metal hydroxide to adjust the pH to about 5.5 to 7.5, autoclaving the entire mixture at about 10 to 20 pounds per square inch steam pressure, separating the liquid and solid phases and drying the liquid phase. Either light steep liquor, i.e. that drawn directly from the steeps, or heavy steep liquor, i.e. that concentrated to about 30 DEG B<\>ae. is satisfactory. The lactic acid may be removed by extraction with an alcohol selected from butyl, amyl, or hexyl alcohols; thus butanol may be added to the acidified steep liquor and the mixture agitated to extract the lactic acid. The extraction may also be effected in continuous countercurrent manner. The extracting alcohol may be anhydrous or water-laden. The acidified steep liquor is then treated for the recovery of the nutrient material by first removing any residual extractant by passing steam through the liquor, adding an alkaline earth metal hydroxide especially calcium hydroxide to adjust the pH to 5.5 to 7.5 and then autoclaving the entire mixture with steam as described above. The autoclaved material is then filtered, e.g. by centrifugation, preferably at 80-90 DEG C., and the cake obtained is washed with water and the centrifugates washed and spray dried to yield the nutrient material which is soluble in water and contains nitrogenous materials together with inorganic material and small amounts of carbohydrates and salts of lactic acid. An example is given in which nutrient material is recovered from corn steep liquor, butanol being employed as the lactic acid extractant and calcium hydroxide as the alkaline earth metal hydroxide.
GB25363/50A 1950-06-17 1950-10-18 Improvements in or relating to a process of treating steep liquor and the product resulting therefrom Expired GB694795A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US694795XA 1950-06-17 1950-06-17

Publications (1)

Publication Number Publication Date
GB694795A true GB694795A (en) 1953-07-29

Family

ID=22089262

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25363/50A Expired GB694795A (en) 1950-06-17 1950-10-18 Improvements in or relating to a process of treating steep liquor and the product resulting therefrom

Country Status (1)

Country Link
GB (1) GB694795A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711269A1 (en) * 1993-07-26 1996-05-15 A.E. Staley Manufacturing Company Process for recovering organic acids
US5766439A (en) * 1996-10-10 1998-06-16 A. E. Staley Manufacturing Co. Production and recovery of organic acids

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711269A1 (en) * 1993-07-26 1996-05-15 A.E. Staley Manufacturing Company Process for recovering organic acids
EP0711269A4 (en) * 1993-07-26 1996-05-29
US5766439A (en) * 1996-10-10 1998-06-16 A. E. Staley Manufacturing Co. Production and recovery of organic acids

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