GB682207A - Process for producing sulphonates from bisulphites and olefins and the sulphonates so produced - Google Patents

Process for producing sulphonates from bisulphites and olefins and the sulphonates so produced

Info

Publication number
GB682207A
GB682207A GB7041/50A GB704150A GB682207A GB 682207 A GB682207 A GB 682207A GB 7041/50 A GB7041/50 A GB 7041/50A GB 704150 A GB704150 A GB 704150A GB 682207 A GB682207 A GB 682207A
Authority
GB
United Kingdom
Prior art keywords
bisulphite
sodium
sulphonates
hydrocarbon
potassium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7041/50A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB682207A publication Critical patent/GB682207A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/20—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by addition of sulfurous acid or salts thereof to compounds having carbon-to-carbon multiple bonds

Abstract

682,207. Sulphonates. NAAMLOOZE VENNOOTSCHAP DE BATAAFSCHE PETROLEUM MAATSCHAPPIJ. March 21, 1950 [March 21, 1949], No. 7041/50. Class 2 (iii). Sulphonates are prepared by mixing an olefine hydrocarbon and a salt yielding bisulphite ions in a ratio of from 0.25 to 2 mols. of olefinic hydrocarbon to 1 mol. of bisulphite ion, in from 1 to 5 times the volume of olefinic hydrocarbon of aqueous methyl or ethyl alcohol containing 50-95 per cent (by volume) of the alcohol in the presence of an inorganic oxidizing agent present in an amount of 0.25 to 5 mols. per cent by weight based on the combined mols. of olefinic hydrocarbon and bisulphite ion-yielding compound and heating the mixture to a temperature hot exceeding 200‹ C. Preferably the reactants are mixed in a ratio of 0.5 to 1 mol. of olefinic hydrocarbon to 1 mol. of bisulphite ion. Ethylene or any of its hydrocarbon derivatives which are not conjugated dienes are suitable olefinic startng materials, e.g. propylene, butylene, tertiary amylene, 2-decene, cyclohexene, styrene, cyclopentene, vinyl-naphthalene, 1,4-hexadiene, 1,4- cyclohexadiene and 1-ercoseine. Suitable catalysts are sodium nitrate, sodium nitrate, nitric acid, potassium, lead, calcium, magnesium, cobalt, borium, nickel and silver nitrates and nitrites, sodium chlorate, potassium dichromate and perchloric acid. Suitable compounds for the production of bisulphite ions are sodium and potassium metabisulphite; sodium, ammonium, potassium and lithium bisulphite; sulphurous acid, methylamine bisulphite and calcium bisulphite. In the examples various olefines are treated with sodium metabisulphite in aqueous methyl alcohol solution in the presence of sodium nitrate.
GB7041/50A 1949-03-21 1950-03-21 Process for producing sulphonates from bisulphites and olefins and the sulphonates so produced Expired GB682207A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US682207XA 1949-03-21 1949-03-21

Publications (1)

Publication Number Publication Date
GB682207A true GB682207A (en) 1952-11-05

Family

ID=22081170

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7041/50A Expired GB682207A (en) 1949-03-21 1950-03-21 Process for producing sulphonates from bisulphites and olefins and the sulphonates so produced

Country Status (1)

Country Link
GB (1) GB682207A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3001948A (en) * 1957-11-26 1961-09-26 California Research Corp Synthetic detergent bar
US3084186A (en) * 1958-04-14 1963-04-02 Clifornia Res Corp Preparation of alkyl sulfonates
US3306931A (en) * 1965-02-17 1967-02-28 Chevron Res Production of alkali metal alkyl sulfonates
US3479397A (en) * 1965-09-09 1969-11-18 Marathon Oil Co Preparation of sulfonates by the reaction of olefins and bisulfite

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3001948A (en) * 1957-11-26 1961-09-26 California Research Corp Synthetic detergent bar
US3084186A (en) * 1958-04-14 1963-04-02 Clifornia Res Corp Preparation of alkyl sulfonates
US3306931A (en) * 1965-02-17 1967-02-28 Chevron Res Production of alkali metal alkyl sulfonates
US3479397A (en) * 1965-09-09 1969-11-18 Marathon Oil Co Preparation of sulfonates by the reaction of olefins and bisulfite

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