GB676944A - Process for the catalytic desulphurisation of hydrocarbons - Google Patents

Process for the catalytic desulphurisation of hydrocarbons

Info

Publication number
GB676944A
GB676944A GB4594/51A GB459451A GB676944A GB 676944 A GB676944 A GB 676944A GB 4594/51 A GB4594/51 A GB 4594/51A GB 459451 A GB459451 A GB 459451A GB 676944 A GB676944 A GB 676944A
Authority
GB
United Kingdom
Prior art keywords
metals
added
group
nitrate
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4594/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB676944A publication Critical patent/GB676944A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85—Chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

In a catalytic desulphurization of hydrocarbon mixtures containing alkenes by treatment with a gas containing hydrogen or a compound which yields or transfers hydrogen, the catalyst comprises alumina or bauxite impregnated with an oxide or sulphide of iron, nickel, or cobalt and an oxide or sulphide of chromium, molybdenum, or tungsten, the atomic ratio of the metals of the first group to the metals of the second group lying between 1:20 and 18:20 to which catalyst has been added a small quantity of a salt of an alkali metal. Potassium chloride or nitrate may be used as the alkali metal salt, preferably in a ratio of potassium to the metals of the second group of 0.5:2.0 to 5:2.0. Alumina, which has been activated by heating and treatment with 15 per cent hydrochloric acid, is impregnated with a solution containing cobalt nitrate, ammonium molybdate, and potassium nitrate, pulverized, graphite added, the catalyst made into tabloid form and heated in nitrogen. The oxides may be converted into sulphides by the passage of untreated gasoline at 400 DEG C. To suppress hydrogenation of the alkenes, the catalysts may be heated before use to 700 DEG -800 DEG C for 2-4 hours in air. In examples gasoline fractions obtained by catalytic cracking are treated with hydrogen at 2-50 atmospheres or higher at a temperature of 400 DEG -450 DEG C. Tetra-ethyl lead may be added to the product to increase the octane number.
GB4594/51A 1948-03-19 1951-02-26 Process for the catalytic desulphurisation of hydrocarbons Expired GB676944A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL657400X 1948-03-19

Publications (1)

Publication Number Publication Date
GB676944A true GB676944A (en) 1952-08-06

Family

ID=19795273

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4943/49A Expired GB657400A (en) 1948-03-19 1949-02-23 Process for the catalytic treatment of carbonaceous material
GB4594/51A Expired GB676944A (en) 1948-03-19 1951-02-26 Process for the catalytic desulphurisation of hydrocarbons

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB4943/49A Expired GB657400A (en) 1948-03-19 1949-02-23 Process for the catalytic treatment of carbonaceous material

Country Status (3)

Country Link
FR (1) FR981107A (en)
GB (2) GB657400A (en)
NL (1) NL67093C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1239424B (en) * 1961-05-19 1967-04-27 Oelwerke Julius Schindler G M Insulating oil
FR2538812A1 (en) * 1982-12-29 1984-07-06 Pro Catalyse Use of a supported catalyst for the hydrotreatment of a hydrocarbon feedstock
EP0582403A1 (en) * 1992-07-27 1994-02-09 Texaco Development Corporation Hydrotreating of cracked naptha

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1104097B (en) * 1954-12-08 1961-04-06 British Petroleum Co Process for the hydrocatalytic desulphurization of hydrocarbons
DE1064180B (en) * 1957-02-16 1959-08-27 Houdry Process Corp Process for the production of catalysts and alumina carriers for catalysts
DE1165185B (en) * 1959-02-25 1964-03-12 Leuna Werke Iawalter Ulbrichti Process for the catalytic hydrogenating refining of diesel oils
DE1266906B (en) * 1959-11-26 1968-04-25 Basf Ag Process for the pressure refining of hydrocarbon mixtures
DE3210756A1 (en) * 1982-03-24 1983-09-29 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING OLEFINS FROM METHANOL AND / OR DIMETHYL ETHER

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1239424B (en) * 1961-05-19 1967-04-27 Oelwerke Julius Schindler G M Insulating oil
FR2538812A1 (en) * 1982-12-29 1984-07-06 Pro Catalyse Use of a supported catalyst for the hydrotreatment of a hydrocarbon feedstock
EP0582403A1 (en) * 1992-07-27 1994-02-09 Texaco Development Corporation Hydrotreating of cracked naptha

Also Published As

Publication number Publication date
FR981107A (en) 1951-05-22
GB657400A (en) 1951-09-19
NL67093C (en)

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