GB675654A - Improvements in and relating to the manufacture of light-sensitive emulsions - Google Patents
Improvements in and relating to the manufacture of light-sensitive emulsionsInfo
- Publication number
- GB675654A GB675654A GB2770747A GB2770747A GB675654A GB 675654 A GB675654 A GB 675654A GB 2770747 A GB2770747 A GB 2770747A GB 2770747 A GB2770747 A GB 2770747A GB 675654 A GB675654 A GB 675654A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- methyl
- naphthylbenzoxazole
- anilinovinyl
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
41 - Methoxy - 3 - amino - 4 - hydroxydiphenyl is prepared by reducing 41-methoxy-3-nitro-4-hydroxydiphenyl with stannous chloride and HCl at boiling temperature. 2 - Methyl - 5 - p - methoxyphenylbenzoxazole is prepared by refluxing 41-methoxy-3-amino-4-hydroxydiphenyl with acetic anhydride. 2-methyl-5-b -naphthylbenzoxazole is similarly prepared. 2 - (b - ethyl : b - anilinovinyl) - 5 - p - methoxybenzoxazole dimethylsulphate is prepared by fusing 2 - methyl - 5 - p - methoxyphenylbenzoxazole dimethylsulphate with S-methyl-isothiopropionanilide. 2 - Nitro - 5 - (b - naphthyl) - phenol is prepared by nitrating p-(b -naphthyl)-phenol in acetic acid. 4-Methyl-31-nitro-41-hydroxydiphenyl is similarly prepared. 2-Amino-4-(b -naphthyl)-phenol is prepared by reducing 2 - nitro - 4 - (b - naphthyl) - phenol with stannous chloride and HCl. 4-Methyl-31-amino-4-hydroxydiphenyl is similarly prepared. 2 - b - Anilinovinyl - 5 - b - naphthylbenzoxazole benzyl bromide is prepared by fusing 2-methyl - 5 - b - naphthylbenzoxazole benzyl bromide with diphenylformamidine. 2-b -anilinovinyl - 5 - p - methoxyphenylbenzoxazole benzyl bromide is similarly prepared. 2 - Methyl - 5 - p - tolylbenzoxazole is prepared by heating 4 - methyl - 31 - amino - 41 - hydroxydiphenyl with acetyl chloride in benzene. 2 - (b - Propyl : b - anilinovinyl) - 5 - p - tolylbenzoxazole diethylsulphate is prepared by fusing 2 - methyl - 5 - p - tolylbenzoxazole diethylsulphate with ethylthiobutyrylisoanilide. 2 - Mercapto - 5 - b - naphthylbenzoxazole is prepared by refluxing 2-amino-4-b -naphthylphenol with CS2 in alcohol containing KOH. 2 - Methylmercapto - 5 - b - naphthylbenzoxazole is prepared by reacting 2-mercapto-5-b -naphthylbenzoxazole with dimethyl sulphate in alcoholic NaOH.ALSO:3 : 31 - Dimethyl - 9 - ethyl - 5 : 51 - di - p - methoxyphenyloxacarbocyanine iodide is prepared by condensing together in pyridine 2-(b -ethyl : b - anilinovinyl) - 5 - p - methoxyphenylbenzoxazole dimethylsulphate and 2-methyl-5-p-methoxyphenylbenzoxazole dimethylsulphate and treating with aqueous KI solution. 3 : 31 - Dibenzyl - 5 : 51 - di - p - methoxyphenyloxacarbocyanine bromide is prepared by reacting 2 - methyl - 5 - p - methoxyphenylbenzoxazole benzyl bromide with ethyl orthoformate in acetic anhydride. 3 - Benzyl - 31 - ethyl - 5 - b - naphthyloxathiazolinocarbocyanine iodide is prepared by condensing 2 - (b - anilinovinyl) - 5 - b - naphthylbenzoxazole benzyl bromide with 2-methylthiazoline ethyl bromide in pyridine, and treating with aqueous KI solution. 3 : 31-Dibenzyl - 41 - methyl - 5 - b - naphthyloxathiazolocarbocyanine bromide is similarly prepared. 3 : 31 - Diethyl - 9 - n - propyl - 5 : 51 - di - p - tolyloxacarbocyanine ethylsulphate is prepared by condensing 2-(b -n-propyl : b -anilinovinyl)-5-p-tolylbenzoxazole diethylsulphate and 2-methyl-5-p-tolylbenzoxazole diethylsulphate in pyridine. 11 : 3 - Diethyl - 5 - p - tolyloxa - 21 - cyanine iodide is prepared by condensing 2-methyl-5-p-tolylbenzoxazole diethylsulphate and 2-methyl-mercaptoquinoline ethyl iodide in pyridine. A hemicyanine dye is prepared by fusing together 2-methyl-5-p-tolylbenzoxazole diethylsulphate, ethyl orthoformate, and p-phenylenediamine, and converting to the iodide. A complex merocyanine dye is prepared by fusing together 5-[(1-ethylquinolylidene)-ethylidene] - 3 - allylrhodanine, 2 - methyl - 5 - p - methoxyphenylbenzoxazole, and methyl p-toluenesulphonate and converting to the iodide. 3 - Benzyl - 5 - p - methoxyphenyl - 41 - p - tolyl - 10 - acetyloxaoxodiazolocarbocyanine base is prepared by condensing 2-b -anilinovinyl-5-p-methoxyphenylbenzoxazole benzyl bromide and 2-acetylmethyl-4-p-tolyl-1 : 3 : 5-oxodiazole in acetic anhydride containing triethylamine. 5 - [(3 - Benzyl - 5 - b - naphthylbenzoxazolylidene) - ethylidene] - 3 - allylrhodanine is prepared by refluxing together 2-(b -anilinovinyl)-5-(b -naphthyl)-benzoxazole benzyl bromide, 3-allylrhodanine, acetic anhydride, and sodium acetate. 2 - p - Dimethylaminostyryl - 3 - ethyl - 5 - b - naphthylbenzoxazole ethylsulphate is prepared by boiling together 2-methyl-5-(b -naphthyl)-benzoxazole diethylsulphate and p-dimethylaminobenzaldehyde in acetic anhydride. 3 : 31 - Dibenzyl - 5 - b - naphthyl - 9 - ethoxyoxathiacarbocyanine bromide is prepared by heating together 2-(b -ethoxy : b -vinyl)-benzthiazole benzylethyl sulphate, 2 - methylmercapto - 5 - b - naphthylbenzoxazole benzyl p-toluenesulphonate, acetic anhydride, and triethylamine, and treating with aqueous KBr solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2770747A GB675654A (en) | 1947-10-16 | 1947-10-16 | Improvements in and relating to the manufacture of light-sensitive emulsions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2770747A GB675654A (en) | 1947-10-16 | 1947-10-16 | Improvements in and relating to the manufacture of light-sensitive emulsions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB675654A true GB675654A (en) | 1952-07-16 |
Family
ID=10263988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2770747A Expired GB675654A (en) | 1947-10-16 | 1947-10-16 | Improvements in and relating to the manufacture of light-sensitive emulsions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB675654A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5422237A (en) * | 1993-05-11 | 1995-06-06 | Fuji Photo Film Co., Ltd. | Methine compound and silver halide photographic material comprising the same |
US5439789A (en) * | 1993-05-11 | 1995-08-08 | Fuji Photo Film Co., Ltd. | Methine compound and silver halide photographic material comprising the same |
US5534403A (en) * | 1993-04-16 | 1996-07-09 | Fuji Photo Film Co., Ltd. | Silver halide photographic material |
US5593820A (en) * | 1993-12-20 | 1997-01-14 | Fuji Photo Film Co., Ltd. | Silver halide emulsion and silver halide photographic material using the same |
-
1947
- 1947-10-16 GB GB2770747A patent/GB675654A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5534403A (en) * | 1993-04-16 | 1996-07-09 | Fuji Photo Film Co., Ltd. | Silver halide photographic material |
US5422237A (en) * | 1993-05-11 | 1995-06-06 | Fuji Photo Film Co., Ltd. | Methine compound and silver halide photographic material comprising the same |
US5439789A (en) * | 1993-05-11 | 1995-08-08 | Fuji Photo Film Co., Ltd. | Methine compound and silver halide photographic material comprising the same |
US5593820A (en) * | 1993-12-20 | 1997-01-14 | Fuji Photo Film Co., Ltd. | Silver halide emulsion and silver halide photographic material using the same |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB663042A (en) | Improvements in dyes and in photographic materials containing the same | |
GB667206A (en) | Improvements in photographic processes and materials therefor | |
GB675654A (en) | Improvements in and relating to the manufacture of light-sensitive emulsions | |
GB603276A (en) | Photographic developers | |
GB904332A (en) | Improvements in or relating to sensitized photographic emulsions and to new sensitizing dyes | |
GB700734A (en) | Improvements in sensitized photographic emulsions and in sensitizing dyes therefor | |
GB804661A (en) | Improvements in the mordanting of dyes in photographic layers | |
GB649725A (en) | Process for the manufacture of 2-methyl-5-phenylbenzthiazole, methine dyes and sensitized photographic emulsions | |
GB620482A (en) | Trinuclear cyanine dyes and photographic light-sensitive elements containing them | |
GB678626A (en) | Improvements in or relating to carbocyanine dyes | |
GB646896A (en) | An improved process of preparing trinuclear cyanine dyes | |
GB675656A (en) | Improvements in and relating to the manufacture of light sensitive photographic emulsions | |
GB577549A (en) | Improvements in the manufacture of dyes and dye intermediates | |
GB968396A (en) | Improvements in dye sensitized photographic emulsions | |
GB886271A (en) | Improvements in or relating to sensitized photographic emulsions and to new sensitizing dyes | |
GB721203A (en) | Process for sensitizing and supersensitizing photographic emulsions | |
GB636906A (en) | Preparation of quaternising agents for heterocyclic nitrogenous cyanine dyes intermediates and photographic silver halide emulsions containing cyanine dyes quaternated with such agents | |
GB685390A (en) | Improvements in or relating to the sensitization and supersensitization of photographic emulsions | |
GB849741A (en) | Improvements in or relating to hemicyanine dyestuffs | |
GB980234A (en) | Dibromobenzimidazole cyanine dyes | |
GB829790A (en) | Improvements in or relating to merocyanine dyes | |
GB759869A (en) | Method of making photographic emulsions for colour photography | |
GB637815A (en) | Improvements in and relating to a process for preparing polymethine dyestuff-intermediate products and polymethine dyestuffs | |
GB697940A (en) | Manufacture of polymethine dyestuffs and of photographic silver halide emulsions sensitized therewith | |
GB748144A (en) | Improvements in light sensitive photographic materials and compounds for use therein |