GB665474A - Cation modified clay - Google Patents
Cation modified clayInfo
- Publication number
- GB665474A GB665474A GB3363348A GB3363348A GB665474A GB 665474 A GB665474 A GB 665474A GB 3363348 A GB3363348 A GB 3363348A GB 3363348 A GB3363348 A GB 3363348A GB 665474 A GB665474 A GB 665474A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bentonite
- reacting
- hydrochloric acid
- onium
- reacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B41/00—Special methods of performing the coupling reaction
- C09B41/001—Special methods of performing the coupling reaction characterised by the coupling medium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B63/00—Lakes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/42—Clays
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Clays having base exchange properties are reacted first with "onium" compounds and then with organic compounds having radicals reactable with the organic radical of the onium compound. "Onium" compounds specified are ammonium, phosphonium, and arsenoniom, sulphonium, oxonium, selenonium, stannonium, and iodonium compounds. Clays specified are montmorilonites, e.g. bentonites, hectorite, and nontronite; illite, attapulgite, fuller's earth and the synthetic permutites. Reactable organic compounds are those used in condensation, polymerization and esterification reactions, e.g. aldehydes, ketones, polycarboxylic acids and their anhydrides, dyes and dye intermediates; synthetic resins, natural and synthetic rubbers. The products are thermoplastic and thermosetting resins, pigments, and synthetic rubbers. In examples: (1) 26.3 gs. octadecadienylamine was dissolved in hot water and 10 gs. 37 per cent HCl. An aqueous slurry of 100 gs. Wyoming bentonite was added to the solution with agitation. The flocculent precipitate of octadecadienylammonium bentonite was filtered, washed and dried and mixed with 1 gm. benzoyl peroxide. On moulding at 150 DEG C. under pressure a plastic product was obtained; (2) aniline bentonite, formed by interaction of bentonite, aniline and hydrochloric acid was reacted with formaldehyde to give a yellow precipitate which in admixture with zinc stearate was moulded to give a thermosetting solid; (3) the reaction product of bentonite, triethylene tetramine and acetic acid was mixed with dimethylol urea and zinc stearate on hot differential rolls and the sheet obtained cooled, ground and moulded at 165 DEG C.; (4) a pigment was obtained by reacting alpha-naphthylamine hydrochloride with the tetrazonium bentonite obtained by reacting bentonite, and benzidine in HCl solution; (5) a pigment was similarly obtained from bentonite, melamine hydrochloride and Ponceau red. In examples (6)-(9) the bentonite was replaced by fuller's earth, synthetic zeolite, magnesium bentonite and nontronite; (10) an alkyd resin was obtained by reacting glycine bentonite with glycerol and phthalic anhydride; (11) a similar resin was obtained by reacting triethanolamine bentonite, phthalic anhydride, soya bean fatty acids, fumaric acid and glycerine; (12) the triethanol amine bentonite of (11) was reacted with stearic acid at 280 DEG C., and (13) with adipic acid, (14) with stearic acid; (15) triethylenetriamine was reacted with illite; (16) and (17) trithenol ethyl arsonium and stibonium iodide were used to replace the triethanol amine of example (11).ALSO:Clays having base exchange properties are reacted first with "onium" compounds and then with organic compounds having radicals reactable with the organic radical of the onium compound (see Group IV (a)). "Onium" compounds specified are ammonium, phosphonium arsonium, sulphonium, oxonium, selenonium, stannonium and iodonium compounds. Clays specified are montmorilonites, e.g. bentonites, hectorite, and nontronite, illite, attapulgite, fuller's earth and the synthetic permutites. In examples, bentonite is reacted with (1) octadecadienylamine and hydrochloric acid to give octadecadienylammonium bentonite; (2) aniline and hydrochloric acid to give phenyl ammonium bentonite; (3) triethylene tetramine and acetic acid; (4) benzidine and hydrochloric acid, followed by tetrazotization of the benzidene bentonite, and coupling with a -naphthylamine to give a pigment; (5) melamine and hydrochloric acid, followed by reacting the melamine bentonite with Ponceau Red; (6) glycine and hydrochloric acid; (7) triethanolamine and hydrochloric acid, and the triethanolamine bentonite is reacted with stearic or adipic acids; (8) triethanolethyl arsonium or stibonium iodide and hydrochloric acid. In (5) above, the bentonite may be replaced by fuller's earth (attapulgite), a synthetic zeolite, a magnesium bentonite, or nontronite.ALSO:Products suitable for use as dyes or pigments are obtained by reacting clays, having base exchange capacity, with an onium compound and with an organic compound having affinity to the organic portion of the onium radical, e.g. dyes and dye intermediates. In examples: (4) a pigment is obtained by reacting alphanaphthylamine hydrochloride with tetrazonium bentonite obtained by reacting bentonite and benzidine in HCl solution; (5) a pigment is similarly obtained from bentonite, melamine HCl, and Ponceau red. Bentonite may be replaced by other montmorilonites, illite, attapulgite, fuller's earth and synthetic permutites.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3363348A GB665474A (en) | 1948-12-31 | 1948-12-31 | Cation modified clay |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3363348A GB665474A (en) | 1948-12-31 | 1948-12-31 | Cation modified clay |
Publications (1)
Publication Number | Publication Date |
---|---|
GB665474A true GB665474A (en) | 1952-01-23 |
Family
ID=10355431
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3363348A Expired GB665474A (en) | 1948-12-31 | 1948-12-31 | Cation modified clay |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB665474A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3003990A (en) * | 1957-05-31 | 1961-10-10 | Exxon Research Engineering Co | Rubber compounded and heat treated with coated filler |
US3267065A (en) * | 1961-06-07 | 1966-08-16 | American Tansul Company | Vinyl amine modified clay process |
FR2495171A1 (en) * | 1980-11-17 | 1982-06-04 | Nl Industries Inc | ORGANOPHILIC CLAY COMPLEXES, PROCESS FOR THEIR PREPARATION AND NONAQUEOUS FLUID SYSTEMS CONTAINING THEM |
WO2004000948A1 (en) * | 2002-06-19 | 2003-12-31 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Organo-clay complexes |
CZ297358B6 (en) * | 2000-12-15 | 2006-11-15 | Agrolinz Melamin Gmbh | Polymer modified inorganic particles |
EP2664657A1 (en) * | 2012-05-16 | 2013-11-20 | Borealis Agrolinz Melamine GmbH | Multistep process for obtaining modified inorganic particles |
WO2013081564A3 (en) * | 2011-11-04 | 2013-12-05 | Kirveli Aziz | Natural, hydrophobic (air loving), active, modified zeolite based products and production methods thereof |
CN103450704A (en) * | 2013-08-01 | 2013-12-18 | 安徽省安邦矿物有限公司 | Synthesis method for attapulgite/bisphenol A hybrid pigment |
EP2703450A1 (en) * | 2012-09-04 | 2014-03-05 | Borealis Agrolinz Melamine GmbH | Advanced multistep process for obtaining modified inorganic particles |
-
1948
- 1948-12-31 GB GB3363348A patent/GB665474A/en not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3003990A (en) * | 1957-05-31 | 1961-10-10 | Exxon Research Engineering Co | Rubber compounded and heat treated with coated filler |
US3267065A (en) * | 1961-06-07 | 1966-08-16 | American Tansul Company | Vinyl amine modified clay process |
FR2495171A1 (en) * | 1980-11-17 | 1982-06-04 | Nl Industries Inc | ORGANOPHILIC CLAY COMPLEXES, PROCESS FOR THEIR PREPARATION AND NONAQUEOUS FLUID SYSTEMS CONTAINING THEM |
CZ297358B6 (en) * | 2000-12-15 | 2006-11-15 | Agrolinz Melamin Gmbh | Polymer modified inorganic particles |
WO2004000948A1 (en) * | 2002-06-19 | 2003-12-31 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Organo-clay complexes |
WO2013081564A3 (en) * | 2011-11-04 | 2013-12-05 | Kirveli Aziz | Natural, hydrophobic (air loving), active, modified zeolite based products and production methods thereof |
EP2664657A1 (en) * | 2012-05-16 | 2013-11-20 | Borealis Agrolinz Melamine GmbH | Multistep process for obtaining modified inorganic particles |
WO2013171237A1 (en) * | 2012-05-16 | 2013-11-21 | Borealis Agrolinz Melamine Gmbh | Multistep process for obtaining modified inorganic particles |
EP2703450A1 (en) * | 2012-09-04 | 2014-03-05 | Borealis Agrolinz Melamine GmbH | Advanced multistep process for obtaining modified inorganic particles |
WO2014037317A1 (en) | 2012-09-04 | 2014-03-13 | Borealis Agrolinz Melamine Gmbh | Advanced multistep process for obtaining modified inorganic particles |
CN103450704A (en) * | 2013-08-01 | 2013-12-18 | 安徽省安邦矿物有限公司 | Synthesis method for attapulgite/bisphenol A hybrid pigment |
CN103450704B (en) * | 2013-08-01 | 2016-03-16 | 安徽省安邦矿物有限公司 | The synthetic method of a kind of attapulgite/dihydroxyphenyl propane hybrid pigment |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB665474A (en) | Cation modified clay | |
US2149273A (en) | Polyamides | |
US4946508A (en) | Disazo pyrazolone pigment compositions | |
US3869439A (en) | Pigments comprising salts or complexes of polyvalent metals and azo-barbituric acid | |
GB1237967A (en) | ||
US3391097A (en) | Epoxy resins from 1, 1'-methylene bis | |
GB1404348A (en) | Disazo pigments and processes for their manufacture and use | |
GB924693A (en) | Improvements in or relating to carboxylic acid polyester salts as suspending agents for lacquers or other film forming suspensions | |
US2466744A (en) | Curing catalysts for aminoplasts | |
DE1644111A1 (en) | New disazo dye pigments and methods of making them | |
US3923774A (en) | Quinazolone containing phenyl-azo-pyridine compounds | |
CA1054607A (en) | Iminoisoindolinone pigments | |
US4184035A (en) | Process for neutralizing halogenated acid intermediates for polyester production | |
US2731438A (en) | Triazine-aldehyde-polysiloxane resinous composition and process for preparing | |
US2582670A (en) | Method of vulcanizing rubber and products thereof | |
US1834849A (en) | Condensation product of alpha, beta disubstituted acroleins with primary aromatic amines | |
US2640047A (en) | Reaction products of a polyhalogenated compound and a triazine derivative and methods of preparing the same | |
DE2361433C2 (en) | Poorly soluble disazo compounds, their preparation and use | |
US4444977A (en) | Curable oxirane formulations | |
US2504003A (en) | Ammonium salt of polymeric nu-hydroxymethyl amic acids and waterrepellent compositions containing them | |
GB488910A (en) | Improvements in vulcanisation of rubber | |
US2543727A (en) | Moisture settable printing ink | |
GB1020445A (en) | Coating compositions | |
US4052378A (en) | Red pigment obtained by coupling diazotized 4-aminonaphthalimide with 2,6-dihydroxy-3-cyano-4-methylpyridine | |
US2493703A (en) | Azo guanamines |