GB661882A - Recovery of selenium used in catalytic oxidation of olefines - Google Patents

Recovery of selenium used in catalytic oxidation of olefines

Info

Publication number
GB661882A
GB661882A GB2176248A GB2176248A GB661882A GB 661882 A GB661882 A GB 661882A GB 2176248 A GB2176248 A GB 2176248A GB 2176248 A GB2176248 A GB 2176248A GB 661882 A GB661882 A GB 661882A
Authority
GB
United Kingdom
Prior art keywords
selenium
olefines
heating
recovery
gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2176248A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB2176248A priority Critical patent/GB661882A/en
Publication of GB661882A publication Critical patent/GB661882A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • C01B19/02Elemental selenium or tellurium

Abstract

In the oxidation of olefins, especially propylene and isobutylene, with oxygen-containing gases in the presence of elementary selenium and copper-containing contact material, as described in Specifications 625,330, 648,386, and 658,179, to obtain unsaturated aldehydes, the deposit containing selenium and selenium oxide is heated above 240 DEG , preferably at 240-400 DEG C., to recover elementary selenium. The heating may be effected in the presence of a restricted amount of air, which is driven off by the carbon oxides evolved, or in the presence of inert gases such as nitrogen.ALSO:Selenium is recovered from the deposit containing the element and its oxide which is condensed from the products obtained by oxidizing olefines with oxygen-containing gases in the presence of selenium and copper-containing contact material, by heating above 240 DEG C. preferably at 240-400 DEG C. Heating may be affected in the presence of a restricted amount of air or in an inert gas such as nitrogen.
GB2176248A 1948-08-18 1948-08-18 Recovery of selenium used in catalytic oxidation of olefines Expired GB661882A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2176248A GB661882A (en) 1948-08-18 1948-08-18 Recovery of selenium used in catalytic oxidation of olefines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2176248A GB661882A (en) 1948-08-18 1948-08-18 Recovery of selenium used in catalytic oxidation of olefines

Publications (1)

Publication Number Publication Date
GB661882A true GB661882A (en) 1951-11-28

Family

ID=10168361

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2176248A Expired GB661882A (en) 1948-08-18 1948-08-18 Recovery of selenium used in catalytic oxidation of olefines

Country Status (1)

Country Link
GB (1) GB661882A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1175664B (en) * 1959-09-04 1964-08-13 Asahi Chemical Ind Process for the recovery of selenium from reaction gases containing this, acrolein and acrylonitrile
US4038376A (en) * 1975-08-12 1977-07-26 Atlantic Richfield Company Process for the recovery of selenium from urethanes containing selenium or compounds thereof
GB2190667A (en) * 1986-04-18 1987-11-25 Nippon Sheet Glass Co Ltd Purifying starting materials

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1175664B (en) * 1959-09-04 1964-08-13 Asahi Chemical Ind Process for the recovery of selenium from reaction gases containing this, acrolein and acrylonitrile
US4038376A (en) * 1975-08-12 1977-07-26 Atlantic Richfield Company Process for the recovery of selenium from urethanes containing selenium or compounds thereof
GB2190667A (en) * 1986-04-18 1987-11-25 Nippon Sheet Glass Co Ltd Purifying starting materials
US4801442A (en) * 1986-04-18 1989-01-31 Nippon Sheet Glass Co., Ltd. Method for purifying starting materials for fabricating chalchogenide glass
GB2190667B (en) * 1986-04-18 1989-11-29 Nippon Sheet Glass Co Ltd

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