GB652566A - Polymeric products - Google Patents

Polymeric products

Info

Publication number
GB652566A
GB652566A GB26455/48A GB2645548A GB652566A GB 652566 A GB652566 A GB 652566A GB 26455/48 A GB26455/48 A GB 26455/48A GB 2645548 A GB2645548 A GB 2645548A GB 652566 A GB652566 A GB 652566A
Authority
GB
United Kingdom
Prior art keywords
carbon monoxide
agents
monoolefin
fibres
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26455/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB26455/48A priority Critical patent/GB652566A/en
Publication of GB652566A publication Critical patent/GB652566A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02Polyamines
    • C08G73/0206Polyalkylene(poly)amines
    • C08G73/0213Preparatory process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Monoolefin/carbon monoxide polymers in which the ratio of monoolefin to carbon monoxide is from 150 : 1 to 1 : 1 have the oxygen of the carbon monoxide replaced by an amino-nitrogen group by reducing the polymer in the presence of ammonia or a primary or secondary amine. The replacement is preferably effected by bringing into intimate contact, in the presence of a hydrogenation catalyst at a temperature between 50 DEG and 300 DEG C. and a total pressure in excess of 20 atmospheres, the polymer, hydrogen, and ammonia or the primary or secondary amine and, if desired, organic solvents, e.g. benzene, xylene, cyclohexane, decahydronaphthalene, diethyl ether, dioxane and isopropanol. Specified monoolefins are ethylene, propylene, isobutylene and mixtures. Hydrogenation catalysts specified are nickel, cobalt, platinum, ruthenium, palladium and combinations of these metals with dehydrating metal oxides, e.g. combinations of ruthenium or nickel with alumina or thoria. Specified amines are methylamine, dimethylamine, ethylamine, pentylamine, decylamine, dodecylamine, octadecylamine, dibutylamine, diamylamine, didodecylamine, cyclohexylamine, dicyclohexylamine, aniline and diphenylamine. Formamide may be used as a source of ammonia. The monoolefin/carbon monoxide polymers may also contain other polymerizable organic compounds such as vinyl chloride, vinyl acetate, styrene, methyl methacrylate, dimethyl maleate, maleic anhydride, or vinylidene compounds. The Specification includes an example of the preparation of an ethylene/carbon monoxide polymer. Solutions and dispersions of the polymers may be used for impregnating and coating fibrous materials such as textiles, wood pulps and paper, and for the preparation of films and fibres. The polymers may also be used as leather treating agents to improve dye receptivity, as additives for bentonite drilling muds, as peptizing agents for rubber, deflocculating agents for water-repellant waxes, water-repellant finishes, shrinkage reducing agents, acid dyestuff fixing agents, antistatic agents for polyethylenes, anti-fogging agents for glass, as intermediates for oil-soluble dyestuffs for colouring polyethylene films and fibres, and as dispersants for metallic enamels. Specified solvents for the aminepolymers are acetic acid, xylene, benzene, toluene and the solutions may include other ingredients such as formaldehyde, methylene distearamide, copper phthalocyanine dyestuff and titanium dioxide.ALSO:Polyamines made from a monoolefin/carbon monoxide hetoropolymer by replacing the oxygen of the carbon monoxide by an amino-nitrogen group (see Group IV (a)), are used for fixing dyestuffs, e.g. acid dyestuffs in fibres and fabrics, for proofing fabrics against shrinkage, e.g. woollens and sateens, and as intermediates for oil-soluble dyestuffs in the colouring of polyethylene films and fibres. The proofing against shrinkage may be effected by impregnating the fabric with a solution of the polyamine, removing excess liquid by squeezing and drying in air or at 100-135 DEG C. The solvent may be acetic acid and formaldehyde or xylene or benzene and the solution may contain other ingredients such as methylene distearamide. In an example of fabric dyeing, a suspension of blue copper phthalocyanine pigment in a solution of a polyamine in acetic acid is used to make "strike-outs" on cotton broadcloth and "fixed" by drying for 24 hours.
GB26455/48A 1948-10-11 1948-10-11 Polymeric products Expired GB652566A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB26455/48A GB652566A (en) 1948-10-11 1948-10-11 Polymeric products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB26455/48A GB652566A (en) 1948-10-11 1948-10-11 Polymeric products

Publications (1)

Publication Number Publication Date
GB652566A true GB652566A (en) 1951-04-25

Family

ID=22061427

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26455/48A Expired GB652566A (en) 1948-10-11 1948-10-11 Polymeric products

Country Status (1)

Country Link
GB (1) GB652566A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845406A (en) * 1955-03-25 1958-07-29 Phillips Petroleum Co Process for the removal of nickelkieselguhr catalysts from hydrogenated butadiene polymers
WO2013034532A1 (en) * 2011-09-09 2013-03-14 Bayer Intellectual Property Gmbh Method for producing polyamines

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2845406A (en) * 1955-03-25 1958-07-29 Phillips Petroleum Co Process for the removal of nickelkieselguhr catalysts from hydrogenated butadiene polymers
WO2013034532A1 (en) * 2011-09-09 2013-03-14 Bayer Intellectual Property Gmbh Method for producing polyamines

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