GB642989A - Acyl polyalkylene-polyamine biguanides - Google Patents
Acyl polyalkylene-polyamine biguanidesInfo
- Publication number
- GB642989A GB642989A GB11784/48A GB1178448A GB642989A GB 642989 A GB642989 A GB 642989A GB 11784/48 A GB11784/48 A GB 11784/48A GB 1178448 A GB1178448 A GB 1178448A GB 642989 A GB642989 A GB 642989A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyalkylene
- polyamine
- carbon atoms
- lower alkyl
- sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6494—Compounds containing a guanyl group R-C-N=, e.g. (bi)guanadine, dicyandiamid amidines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C279/20—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylguanidines
- C07C279/24—Y being a hetero atom
- C07C279/26—X and Y being nitrogen atoms, i.e. biguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
- D06P1/6497—Amides of di- or polyamines; Acylated polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Acyl polyalkylene-polyamine biguanides of the general formula RCONH-(CHR1-CHR11 -NH)X-C(: NH)-NH-C(: NH)-Y, wherein R represents the residue of a fatty acid (preferably containing at least 9 carbon atoms), R1 and R11 represent hydrogen or methyl, a is 2, 3 or 4, Y represents -NH2 or <FORM:0642989/IV (b)/1> X represents halogen or -OSO3-lower alkyl, and the expression "lower alkyl" denotes an alkyl group containing not more than 5 carbon atoms, are manufactured by condensing a fatty acid or an ester (including glycerides) thereof with a 1 : 2-polyalkylene-polyamine, reacting the resulting acyl-1 : 2-polyalkylene-polyamine, or a salt (e.g. hydrochloride, sulphate or phosphate) thereof, with dicyandiamide, and, if desired, treating the product with an alkyl halide or dialkyl sulphate in which the alkyl group contains not more than 5 carbon atoms. The products are useful for the treatment of textiles (see Group IV (c)). In examples: (1) stearic acid is heated with diethylene-triamine and the product is dissolved in dilute hydrochloric acid and refluxed with dicyandiamide in methanol; (2) the product of (1), but prepared somewhat differently, is treated with dimethyl sulphate. Additional starting materials specified are: fatty acids-lauric, palmitic, oleic, ricinoleic, acetic, propionic and butyric; polyalkylene-polyamines-triethylenetetramine and 1 : 2 - dipropylene - triamine; alkylating agents-methyl chloride, ethyl iodide and diethyl sulphate. U.S.A. Specification 1,947,951 is referred to.ALSO:Acyl polyalkylene-polyamine biguanides of the general formula <FORM:0642989/IV (c)/1> (wherein R represents the residue of a fatty acid, R1 and R11 represent hydrogen or methyl, x is 2, 3 or 4, Y represents -NH2 or <FORM:0642989/IV (c)/2> lower alkyl, and the expression "lower alkyl" denotes an alkyl group containing not more than 5 carbon atoms) may be applied to textile fibres (e.g. viscose rayon, cellulose acetate and especially fibres of vegetable origin such as cotton) as dye-fixing agents, or, in the case of compounds in which the radical represented by R in the general formula contains at least 9 carbon atoms, for imparting a soft handle or feel to the material. In examples, dyed or undyed cotton cloth is padded with a 0.25-2.0 per cent aqueous dispersion of stearyl diethylene-triamine biguanide (using the polyglycol ether of octylphenol as dispersing agent), or with an aqueous solution of the methosulphate of the said biguanide derivative.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US642989XA | 1947-07-02 | 1947-07-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB642989A true GB642989A (en) | 1950-09-13 |
Family
ID=22054964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB11784/48A Expired GB642989A (en) | 1947-07-02 | 1948-04-29 | Acyl polyalkylene-polyamine biguanides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB642989A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI626229B (en) * | 2016-09-22 | 2018-06-11 | 中國石油化學工業開發股份有限公司 | Synthesis of biguanid phosphate and bactericide |
| CN113502660A (en) * | 2021-09-10 | 2021-10-15 | 南通三田纺织有限公司 | Cool antibacterial mosquito net fabric and preparation method thereof |
-
1948
- 1948-04-29 GB GB11784/48A patent/GB642989A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI626229B (en) * | 2016-09-22 | 2018-06-11 | 中國石油化學工業開發股份有限公司 | Synthesis of biguanid phosphate and bactericide |
| CN113502660A (en) * | 2021-09-10 | 2021-10-15 | 南通三田纺织有限公司 | Cool antibacterial mosquito net fabric and preparation method thereof |
| CN113502660B (en) * | 2021-09-10 | 2021-11-19 | 南通三田纺织有限公司 | Cool antibacterial mosquito net fabric and preparation method thereof |
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