GB639055A - Vitreous enamelling materials and processes - Google Patents

Vitreous enamelling materials and processes

Info

Publication number
GB639055A
GB639055A GB13257/47A GB1325747A GB639055A GB 639055 A GB639055 A GB 639055A GB 13257/47 A GB13257/47 A GB 13257/47A GB 1325747 A GB1325747 A GB 1325747A GB 639055 A GB639055 A GB 639055A
Authority
GB
United Kingdom
Prior art keywords
metal
h2so4
hno3
water
mnso4
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13257/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Poor and Co
Original Assignee
Poor and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Poor and Co filed Critical Poor and Co
Publication of GB639055A publication Critical patent/GB639055A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D3/00—Chemical treatment of the metal surfaces prior to coating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/9335—Product by special process
    • Y10S428/936—Chemical deposition, e.g. electroless plating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/9335—Product by special process
    • Y10S428/937—Sprayed metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12472—Microscopic interfacial wave or roughness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
    • Y10T428/12604—Film [e.g., glaze, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/1266—O, S, or organic compound in metal component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/1266—O, S, or organic compound in metal component
    • Y10T428/12667—Oxide of transition metal or Al
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12681—Ga-, In-, Tl- or Group VA metal-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12931—Co-, Fe-, or Ni-base components, alternative to each other
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12951—Fe-base component
    • Y10T428/12972—Containing 0.01-1.7% carbon [i.e., steel]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)
  • Glass Compositions (AREA)
  • Chemically Coating (AREA)

Abstract

Ferrous metals are given a fine grain etch in an acid bath in which is dissolved an oxidizing compound of a metal above ferrous iron in the electro-chemical series, and coated with a non-volatile metal which is reducing in relation to ferrous iron or a compound which liberates such metal under vitreous enamel firing conditions, and a vitreous enamel is fired on the resultant metal (see Group XXIII). In one example sheets of S.A.E. 1020 cold reduced steel ore (a) etched in 4 per cent H2SO4 containing a solution of Mn(NO3)2 for 3-10 minutes at 130-150 DEG F, the preferred percentage of Mn being 0.05-0.5 and of nitrate 0.1-1.0, (b) rinsed with water and immersed for 5-15 minutes at 180-190 DEG F in a mixture containing Ni SO4.6H2O 3 ozs., Ni Cl2. 6H2O 0.7 oz., H3BO3 0.3 oz. with one gallon of water and 3.8-38 gms. Zn SO4 or Cd SO4 with or without 3.8 gms. lauryl sulphate, the pH being adjusted to 1.8-2.0 with H2SO4, rinsed, scrubbed and dried and (c) sprayed with enamel dried and fired. In other examples H2SO4, MnSO4. 4H2O, and HNO3, or Li2CO3, HNO3, and water, or MnSO4. 4H2O, Na2CO3, HNO3, and H2SO4 are used at step (a) above. Preferred metals for step (b) above are As. Sb, Co, Ni, or alloys of these. and they may be applied by electro-plating or by vaporizing the metal. The Specification gives the composition of suitable enamels, and also of various stocks to which the invention may be applied.
GB13257/47A 1946-08-09 1947-05-16 Vitreous enamelling materials and processes Expired GB639055A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US639055XA 1946-08-09 1946-08-09
US231646A US2768904A (en) 1946-08-09 1951-06-14 Vitreous enameling process
US533030A US2963784A (en) 1946-08-09 1955-09-07 Base stock for vitreous enamel coatings

Publications (1)

Publication Number Publication Date
GB639055A true GB639055A (en) 1950-06-21

Family

ID=32397837

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13257/47A Expired GB639055A (en) 1946-08-09 1947-05-16 Vitreous enamelling materials and processes

Country Status (2)

Country Link
US (2) US2768904A (en)
GB (1) GB639055A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2981633A (en) * 1958-10-20 1961-04-25 Pfizer & Co C Process for treating ferrous metals
US2981634A (en) * 1958-10-20 1961-04-25 Pfizer & Co C Process for treating ferrous metals
US2994369A (en) * 1959-04-02 1961-08-01 Pittsburgh Plate Glass Co Nickel plating chemical composition
US3011907A (en) * 1960-08-24 1961-12-05 Pfizer & Co C Process for treating ferrous metals
US3011906A (en) * 1960-08-24 1961-12-05 Pfizer & Co C Process for treating ferrous metals
US7622196B2 (en) * 2006-08-11 2009-11-24 Applied Technology Laboratories Llc Metal cladding composition, additive, method and system

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1061066A (en) * 1907-03-11 1913-05-06 George A Goodson Plated metallic body.
US1702766A (en) * 1924-08-05 1929-02-19 Guardian Metals Company Composite metal plate
US1805143A (en) * 1929-12-13 1931-05-12 Hommel Oscar Enamel ware
US1931704A (en) * 1931-03-02 1933-10-24 Dura Co Process of protecting ferrous metals
US2032256A (en) * 1932-09-06 1936-02-25 American Rolling Mill Co Metal articles for coating
NL41462C (en) * 1932-12-07
US1946766A (en) * 1933-04-08 1934-02-13 Albert H Shonkwiler Finishing ferrous sheet material
US2101950A (en) * 1934-03-21 1937-12-14 American Rolling Mill Co Preparing metal for enameling
US2206597A (en) * 1934-04-07 1940-07-02 American Rolling Mill Co Coating metal articles
US2156298A (en) * 1936-04-18 1939-05-02 Boehler & Co Ag Geb Welded article
US2398881A (en) * 1939-05-20 1946-04-23 Western Electric Co Coated article
US2279935A (en) * 1939-10-07 1942-04-14 Belding Harvey Ross Vitreous enamel coated steel article and method of making the same
BE436887A (en) * 1939-10-31 1900-01-01
US2283170A (en) * 1939-11-30 1942-05-19 Batcheller Clements Method of coloring etched stainless steel
US2495762A (en) * 1945-06-04 1950-01-31 George N Hibben Enameled article
US2495835A (en) * 1945-10-15 1950-01-31 George N Hibben Light-colored enameled steel article
US2639264A (en) * 1949-04-13 1953-05-19 Poor & Co Vitreous enameling processes and products
US2495837A (en) * 1949-04-27 1950-01-31 George N Hibben Enameled articles
US2775531A (en) * 1949-05-10 1956-12-25 Univ Ohio State Res Found Method of coating a metal surface

Also Published As

Publication number Publication date
US2963784A (en) 1960-12-13
US2768904A (en) 1956-10-30

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