GB637739A - Improvements in and relating to the preparation of organo silicon fluorides - Google Patents
Improvements in and relating to the preparation of organo silicon fluoridesInfo
- Publication number
- GB637739A GB637739A GB1371647A GB1371647A GB637739A GB 637739 A GB637739 A GB 637739A GB 1371647 A GB1371647 A GB 1371647A GB 1371647 A GB1371647 A GB 1371647A GB 637739 A GB637739 A GB 637739A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- tetrafluoride
- magnesium bromide
- difluoride
- silicon tetrafluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 organo silicon fluorides Chemical class 0.000 title abstract 4
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 abstract 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- FLAKGKCBSLMHQU-UHFFFAOYSA-N CC[Mg] Chemical compound CC[Mg] FLAKGKCBSLMHQU-UHFFFAOYSA-N 0.000 abstract 1
- 239000007818 Grignard reagent Substances 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- UTKYRSVIVDNUAY-UHFFFAOYSA-N dibenzyl(difluoro)silane Chemical compound C=1C=CC=CC=1C[Si](F)(F)CC1=CC=CC=C1 UTKYRSVIVDNUAY-UHFFFAOYSA-N 0.000 abstract 1
- OJBGGLLCYJYHPG-UHFFFAOYSA-N diethyl(difluoro)silane Chemical compound CC[Si](F)(F)CC OJBGGLLCYJYHPG-UHFFFAOYSA-N 0.000 abstract 1
- BOMPXIHODLVNMC-UHFFFAOYSA-N difluoro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](F)(F)C1=CC=CC=C1 BOMPXIHODLVNMC-UHFFFAOYSA-N 0.000 abstract 1
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000004795 grignard reagents Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 abstract 1
- SCEZYJKGDJPHQO-UHFFFAOYSA-M magnesium;methanidylbenzene;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C1=CC=CC=C1 SCEZYJKGDJPHQO-UHFFFAOYSA-M 0.000 abstract 1
- DQEUYIQDSMINEY-UHFFFAOYSA-M magnesium;prop-1-ene;bromide Chemical compound [Mg+2].[Br-].[CH2-]C=C DQEUYIQDSMINEY-UHFFFAOYSA-M 0.000 abstract 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Silicon Compounds (AREA)
Abstract
Polymeric compounds are obtained by polymerizing allyl silicon fluorides. Diallyldifluoro-and triallylmonofluoro-silanes are mentioned. A resin is obtained by hydrolysing with aqueous sodium carbonate and heating, the product obtained by passing silican tetrafluoride into ethereol ethyl magnesium bromide-probably diethylsilicon difluoride.ALSO:Organo-silicon fluorides of the formula RxSiF(4-x), wherein R represents an alkyl, alkenyl, aryl or arlakyl group directly attached to the silicon atom and x is 1 or 2, are prepared by the reaction of RMgX, wherein R and X have the above significance, with a proportion of silicon tetrafluoride sufficient to produce said organo silicon fluorides in which this result is achieved by continuously adding the Grignard reagent to ether or other inert liquid medium into which silicon tetrafluoride is continuously passed, e.g. the rate of addition of silicon tetrafluoride may be such that the reaction mixture is saturated with silicon tetrafluoride. The products may be separated by distillation. In the examples, silicon tetrafluoride is reacted with phenyl magnesium bromide, ethyl magnesium bromide, benzyl magnesium chloride and allyl magnesium bromide. In the latter case some triallylmonofluorosilane is formed. Diphenylsilicon dihydroxide is obtained by hydrolysing diphenylsilicon difluoride with aqueous sodium hydroxide. Dibenzylsilicon diol and anhydrobisdibenzyl silicone are obtained by the alkaline hydrolysis of dibenzylsilicon difluoride.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU29045D LU29045A1 (en) | 1947-05-21 | ||
| GB1371647A GB637739A (en) | 1947-05-21 | 1947-05-21 | Improvements in and relating to the preparation of organo silicon fluorides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1371647A GB637739A (en) | 1947-05-21 | 1947-05-21 | Improvements in and relating to the preparation of organo silicon fluorides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB637739A true GB637739A (en) | 1950-05-24 |
Family
ID=10028067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1371647A Expired GB637739A (en) | 1947-05-21 | 1947-05-21 | Improvements in and relating to the preparation of organo silicon fluorides |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB637739A (en) |
| LU (1) | LU29045A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116178400A (en) * | 2023-04-28 | 2023-05-30 | 研峰科技(北京)有限公司 | Grignard reagent allyl magnesium bromide preparation process |
-
0
- LU LU29045D patent/LU29045A1/xx unknown
-
1947
- 1947-05-21 GB GB1371647A patent/GB637739A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116178400A (en) * | 2023-04-28 | 2023-05-30 | 研峰科技(北京)有限公司 | Grignard reagent allyl magnesium bromide preparation process |
| CN116178400B (en) * | 2023-04-28 | 2023-12-05 | 研峰科技(北京)股份有限公司 | Grignard reagent allyl magnesium bromide preparation process |
Also Published As
| Publication number | Publication date |
|---|---|
| LU29045A1 (en) |
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