GB672824A - Organo-silicon compounds and a process for their manufacture - Google Patents
Organo-silicon compounds and a process for their manufactureInfo
- Publication number
- GB672824A GB672824A GB3220/50A GB322050A GB672824A GB 672824 A GB672824 A GB 672824A GB 3220/50 A GB3220/50 A GB 3220/50A GB 322050 A GB322050 A GB 322050A GB 672824 A GB672824 A GB 672824A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogen atom
- alkyl
- monocyclic aryl
- silicon compounds
- organo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003961 organosilicon compounds Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- -1 monocyclic aryl radical Chemical group 0.000 abstract 9
- 125000005843 halogen group Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 125000005375 organosiloxane group Chemical group 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000003944 tolyl group Chemical group 0.000 abstract 1
- 125000005023 xylyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
Abstract
Organo siloxanes are obtained by the hydrolysis and condensation of organo silicon compounds of the general formula Y2RSiCH2SiRY2, wherein each R is an alkyl or monocyclic aryl radical and Y is an alkoxy radical or halogen atom.ALSO:The invention comprises organo silicon compounds of the formula Y2RSiCH2SiRY2, wherein each R is an alkyl or monocyclic aryl radical and Y is an alkoxy radical or halogen atom, and a process for the preparation of the above compounds by reacting a compound of the general formula X12RSiCH2SiX13 in the liquid phase with RMgX, wherein each R is an alkyl or monocyclic aryl radical, X is a halogen atom or an alkoxy radical and X1 is a halogen atom, the latter compound being employed in a proportion of between 0.5 and 1.5 mols. per mol. of the former. The group R may be the methyl to octadecyl group, phenyl, tolyl or xylyl group, and the group Y may be chlorine, bromine or ethoxyl. In the examples, the following compounds are prepared: Cl2CH3 SiCH2SiCH3Cl2 and C6H5Cl2SiCH2SiCl2CH3.ALSO:Foam inhibiting agents for aqueous and non-aqueous systems containing organic materials comprise organo silicon compounds of the general formula Y2 R Si CH2 Si RY2, wherein each R is an alkyl or monocyclic aryl radical, and Y is an alkoxy radical or halogen atom.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US672824XA | 1949-03-19 | 1949-03-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB672824A true GB672824A (en) | 1952-05-28 |
Family
ID=22074952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3220/50A Expired GB672824A (en) | 1949-03-19 | 1950-02-08 | Organo-silicon compounds and a process for their manufacture |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB672824A (en) |
-
1950
- 1950-02-08 GB GB3220/50A patent/GB672824A/en not_active Expired
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