GB636323A - Polymerization of alpha-haloacrylic compounds - Google Patents
Polymerization of alpha-haloacrylic compoundsInfo
- Publication number
- GB636323A GB636323A GB19629/46A GB1962946A GB636323A GB 636323 A GB636323 A GB 636323A GB 19629/46 A GB19629/46 A GB 19629/46A GB 1962946 A GB1962946 A GB 1962946A GB 636323 A GB636323 A GB 636323A
- Authority
- GB
- United Kingdom
- Prior art keywords
- haloacrylic
- ester
- polyhydric alcohol
- esters
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title 1
- 150000002148 esters Chemical class 0.000 abstract 17
- 150000005846 sugar alcohols Polymers 0.000 abstract 10
- 239000002253 acid Substances 0.000 abstract 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- -1 propyl alcohols Chemical class 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 3
- 235000011187 glycerol Nutrition 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical class OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 3
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 abstract 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 abstract 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 2
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- 239000004348 Glyceryl diacetate Substances 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- 150000001734 carboxylic acid salts Chemical class 0.000 abstract 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 2
- 238000006704 dehydrohalogenation reaction Methods 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- 230000007717 exclusion Effects 0.000 abstract 2
- 235000019443 glyceryl diacetate Nutrition 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 abstract 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 238000010992 reflux Methods 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000002689 maleic acids Chemical class 0.000 abstract 1
- 150000002691 malonic acids Chemical class 0.000 abstract 1
- 125000005486 naphthalic acid group Chemical group 0.000 abstract 1
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical class [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 abstract 1
- 235000011056 potassium acetate Nutrition 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 235000011091 sodium acetates Nutrition 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/22—Esters containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US607270A US2499811A (en) | 1945-07-26 | 1945-07-26 | Polymerization of alpha-haloacrylic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB636323A true GB636323A (en) | 1950-04-26 |
Family
ID=24431543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19629/46A Expired GB636323A (en) | 1945-07-26 | 1946-07-01 | Polymerization of alpha-haloacrylic compounds |
Country Status (6)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2704770A (en) * | 1952-04-23 | 1955-03-22 | Gen Aniline & Film Corp | Chromatographic purification of monomeric alpha-chloroacrylates |
| US2683705A (en) * | 1952-05-16 | 1954-07-13 | Gen Aniline & Film Corp | Polymerization of alpha-chloroacrylates |
| US3304198A (en) * | 1963-10-28 | 1967-02-14 | Allied Chem | Process for preparing oleophobic and hydrophobic fiber and fiber prepared therewith |
| US4107411A (en) * | 1973-07-18 | 1978-08-15 | Solvay & Cie. | Method of preparing salts of poly-alpha-hydroxyacrylic acid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2282088A (en) * | 1940-06-12 | 1942-05-05 | Pittsburgh Plate Glass Co | Chloracrylic esters |
-
1945
- 1945-07-26 US US607270A patent/US2499811A/en not_active Expired - Lifetime
-
1946
- 1946-07-01 GB GB19629/46A patent/GB636323A/en not_active Expired
- 1946-07-25 CH CH263985D patent/CH263985A/de unknown
- 1946-07-25 BE BE466849D patent/BE466849A/xx unknown
- 1946-07-26 FR FR931412D patent/FR931412A/fr not_active Expired
-
1949
- 1949-01-01 DE DEP29257D patent/DE834142C/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR931412A (fr) | 1948-02-23 |
| DE834142C (de) | 1952-03-17 |
| US2499811A (en) | 1950-03-07 |
| BE466849A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1946-08-31 |
| CH263985A (de) | 1949-09-30 |
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