GB635986A - Improvements in or relating to vinyl resin-synthetic rubber compositions and method of preparing same - Google Patents
Improvements in or relating to vinyl resin-synthetic rubber compositions and method of preparing sameInfo
- Publication number
- GB635986A GB635986A GB32205/46A GB3220546A GB635986A GB 635986 A GB635986 A GB 635986A GB 32205/46 A GB32205/46 A GB 32205/46A GB 3220546 A GB3220546 A GB 3220546A GB 635986 A GB635986 A GB 635986A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- butadiene
- prepared
- synthetic rubber
- films
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/005—Processes for mixing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/10—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
A stable aqueous dispersion for the production of films and coatings comprises as the dispersed phase particles of an intimate mixture of a vinyl resin prepared by emulsion polymerization of a mixture consisting mainly of vinyl and/or vinylidene chloride and a synthetic rubber prepared by emulsion polymerization of 1 part of a butadiene-1,3 hydrocarbon with from 0.1 to 2 parts of a copolymerizable unsaturated compound. The vinyl resin is preferably a copolymer of vinyl and/or vinylidene chloride with at least 10 per cent by weight of an ester of acrylic or substituted acrylic acid. Alternative copolymerizable monomers include vinyl acetate and butyrate, styrene, acrylic acid, acrylonitrile, methyl vinyl ketone, vinyl carbazole and methyl vinyl ether. The butadiene component of the synthetic rubber may be butadiene-1,3, isoprene, 2,3-dimethyl butadiene or piperylene or a mixture of these, and the other component is preferably a nitrile of an acrylic acid but may consist of vinylidene chloride, alkyl acrylates and the vinyl compounds mentioned above. The dispersion is formed by mixing the two dispersions, of like electric charge, while stirring. The pH and size of the particles of the two dispersions should preferably be of the same order. Additional ingredients which may be added include plasticizers, e.g. tricresyl phosphate and dioctyl phthalate, pigments and fillers such as carbon black, titanium dioxide and whiting; vinyl resin stabilizers, e.g. lead carbonate or silicate; synthetic rubber stabilizers, e.g. phenyl betanaphthylamine; wetting agents, proteins and other hydrophilic colloids; and vulcanizing agents, e.g. sulphur with butyl zimate or polyalkylene polyamines, or aldehyde-amine condensates. In normal films and coatings, the vinyl resin preferably constitutes 50-90 per cent of the dry polymer content. For films prepared by the coagulant dip method, the proportions are reversed. The dispersions may provide self-sustaining films and coatings on fabric (see Group VIII), paper, wood, glass, metal, rubber and other plastic materials. Specifications 633,630 and 636,535 are referred to. The Specification as open to inspection under Sect. 91 comprises also dispersions containing vinyl resins that are prepared from one or more monomers having the structure <FORM:0635986/IV (a)/1> wherein at least one of X and Y is a negative group such as chlorine, bromine, cyano, phenyl, acyl, carboxy, carbalkoxy and similar negative groups free from olefinic linkages. This subject-matter does not appear in the Specification as accepted.ALSO:A stable aqueous dispersion for the production of films and coatings comprises as the dispersed phase particles of an intimate mixture of a vinyl resin prepared by emulsion polymerization of a mixture consisting mainly of vinyl and/or vinylidene chloride and a synthetic rubber prepared by emulsion polymerisation of 1 part of a butadiene-1, 3 hydrocarbon with 0.1 to 2 parts of a copolymerizable unsaturated compound. The vinyl resin is preferably a copolymer of vinyl and/or vinylidene chloride with at least 10 per cent by weight of an ester of acrylic or substituted acrylic acid. Alternative copolymerisable monomers include vinyl acetate and butyrate, styrene, acrylic acid, acrylonitrile, methyl vinyl ketone, vinyl carbazole and methyl vinyl ether. The butadiene component of the synthetic rubber may be butadiene-1, 3, isoprene, 2, 3-dimethyl butadiene or piperylene or a mixture of these; and the other component is preferably a nitrile of an acrylic acid but may consist of vinylidene chloride, alkyl acrylates and the vinyl compounds mentioned above. The dispersion is formed by mixing the two dispersions, of like electric charge, while stirring. The pH and size of the particles should preferably be of the same order. Additional ingredients which may be added include plasticisers e.g. tricresyl phosphate and dioctyl phthalate; pigments and fillers e.g. carbon black, titanium dioxide and whiting; vinyl resin stabilizers e.g. lead carbonate or silicate; synthetic rubber stabilizers e.g. phenyl beta-naphthylamine; wetting agents, proteins and other hydrophillic colloids; and vulcanizing agents e.g. aldehyde-amine condensates or sulphur with butyl zimate or polyethylene polyamines. Generally the vinyl resin preferably constitutes 50-90 per cent of the dry polymer content. For films prepared by the coagulant dip method, the proportions are reversed. The dispersions may provide self-sustaining films and coatings on fabric (see Group VIII), paper, wood, glass, rubber, metal and other plastic materials. Specifications 633,630 and 636,535, [both in Group IV (a)], are referred to. The Specification as open to inspection under Sect. 91 comprises also dispersions containing vinyl resins that are prepared from one or more monomers having the structure <FORM:0635986/V/1> , wherein at least one of X and Y is a negative group such as chlorine, bromine, cyano, phenyl, acyl, carboxy, carbalkoxy and similar negative groups free from olefinic linkages. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US635986XA | 1944-08-12 | 1944-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB635986A true GB635986A (en) | 1950-04-19 |
Family
ID=22050261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB32205/46A Expired GB635986A (en) | 1944-08-12 | 1946-10-30 | Improvements in or relating to vinyl resin-synthetic rubber compositions and method of preparing same |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE938395C (en) |
FR (1) | FR950206A (en) |
GB (1) | GB635986A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2910448A (en) * | 1956-03-29 | 1959-10-27 | Nat Starch Products Inc | Vinyl resin emulsions containing methoxy polyethylene glycol |
US3393166A (en) * | 1964-10-01 | 1968-07-16 | Polymer Corp | Flame retardant latex foam rubber of a blend of vinylidene halide homopolymer and rubbery vinylidene halide copolymer |
US4228058A (en) * | 1978-07-03 | 1980-10-14 | Syntex (U.S.A.) Inc. | Flame retardant latexes |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2719137A (en) * | 1951-12-06 | 1955-09-27 | Us Rubber Co | Tough, rigid composition of vinyl chloride polymer and rubbery diolefinacrylic ester copolymer |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE615219C (en) * | 1931-07-14 | 1935-06-29 | I G Farbenindustrie Akt Ges | Lacquers |
DE623351C (en) * | 1932-10-19 |
-
1946
- 1946-10-30 GB GB32205/46A patent/GB635986A/en not_active Expired
-
1947
- 1947-07-26 FR FR950206D patent/FR950206A/en not_active Expired
-
1950
- 1950-09-29 DE DEG3896A patent/DE938395C/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2910448A (en) * | 1956-03-29 | 1959-10-27 | Nat Starch Products Inc | Vinyl resin emulsions containing methoxy polyethylene glycol |
US3393166A (en) * | 1964-10-01 | 1968-07-16 | Polymer Corp | Flame retardant latex foam rubber of a blend of vinylidene halide homopolymer and rubbery vinylidene halide copolymer |
US4228058A (en) * | 1978-07-03 | 1980-10-14 | Syntex (U.S.A.) Inc. | Flame retardant latexes |
Also Published As
Publication number | Publication date |
---|---|
FR950206A (en) | 1949-09-21 |
DE938395C (en) | 1956-01-26 |
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