GB629659A - Anti-static textile materials - Google Patents

Anti-static textile materials

Info

Publication number
GB629659A
GB629659A GB29565/46A GB2956546A GB629659A GB 629659 A GB629659 A GB 629659A GB 29565/46 A GB29565/46 A GB 29565/46A GB 2956546 A GB2956546 A GB 2956546A GB 629659 A GB629659 A GB 629659A
Authority
GB
United Kingdom
Prior art keywords
phosphate
oil
lauryl
ethyl
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29565/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Publication of GB629659A publication Critical patent/GB629659A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/15—Antistatic agents not otherwise provided for
    • Y10S260/16—Antistatic agents containing a metal, silicon, boron or phosphorus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31—Surface property or characteristic of web, sheet or block
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
    • Y10T442/2451—Phosphorus containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2869—Coated or impregnated regenerated cellulose fiber fabric

Abstract

Textile fibres, yarns, threads, or fabrics are lubricated and rendered resistant to the accumulation of static electricity by applying to them a composition comprising 99-90 per cent of a textile lubricating oil and 1-10 per cent of a dialkyl acid o-phosphate wherein one of the alkyl groups has 6-18 carbon atoms and the other has 1-4 carbon atoms, and retaining in the materials about 0.1-10.0 per cent of the phosphate compound based on the weight of the materials. Lauryl ethyl, lauryl methyl, hexyl ethyl, stearyl ethyl, octyl butyl, and other dialkyl o-phosphates are specified. The oil may be animal, vegetable, or mineral, e.g. light mineral oil, castor, teaseed, soya bean, olive, sperm, blown sperm, blown olive, or sulphonated castor oil. If desired, the composition may be in the form of an emulsion with water. Emulsifying agents, blending agents, dyes, or other substances may be included in the composition. In an example, the composition comprises mineral oil, olive oil, and lauryl ethyl acid o-phosphate.ALSO:The Specification as open to inspection under Sect. 91 comprises incorporating in a solution of an organic derivative of cellulose, prior to forming it into artificial filaments, a small proportion of a dialkyl acid o-phosphate in which one of the alkyl groups contains 6-18 carbon atoms and the other contains 1-4 carbon atoms. The proportion of phosphate incorporated may be such that the formed filaments contain 0.1-5 per cent or more of this substance which renders the filaments resistant to the accumulation of static electricity. In examples, filaments are obtained by wet or dry spinning methods from a solution of cellulose acetate in acetone containing 2.5-5.0 per cent of lauryl ethyl acid o-phosphate based on the weight of cellulose acetate. Other phosphates specified are lauryl methyl, lauryl butyl, hexyl ethyl, stearyl ethyl, and octyl butyl acid o-phosphates. This subject-matter does not appear in the Specification as accepted.ALSO:Textile materials such as fibres, yarns, threads, or fabrics, are rendered resistant to the accumulation of static electricity by applying to them a dressing or finishing composition comprising 99-90 per cent of a textile lubricating oil and 1-10 per cent of a dialkyl acid o-phosphate wherein one of the alkyl groups has 6-18 carbon atoms and the other has 1-4 carbon atoms, and retaining in the materials a proportion of about 0.1 per cent to about 10 per cent of dialkyl acid o-phosphate based on the weight of the treated materials. Lauryl ethyl acid o-phosphate is preferred but hexyl ethyl, lauryl methyl, lauryl propyl, stearyl ethyl, octyl butyl, and other dialkyl o-phosphates may be used. The oil may be animal, vegetable, or mineral, e.g. light mineral, olive, castor, teaseed, soya bean, or sperm oil, blown olive or sperm oil, or sulphonated castor oil. If desired the composition may be in the form of an emulsion with water. Emulsifying agents, blending agents, dyes or other colouring matter, or other substances may be applied to the textile materials simultaneously with the oil and phosphate composition. The textile materials treated may be of cotton, wool, silk, flax, regenerated cellulose, nylon, casein, cellulose esters, or cellulose ethers. In an example, a yarn of cellulose acetate, as it is drawn from the spinning cell passes across a wick moistened with light mineral oil containing lauryl ethyl acid o-phosphate. In another example, cellulose acetate yarn is treated with an aqueous emulsion of olive oil and lauryl ethyl acid o-phosphate. Cotton yarns are treated with a solution comprising mineral oil, olive oil, and the phosphate compound. The Specification as open to inspection under Sect. 91 comprises also the treatment of textile materials with dialkyl acid o-phosphate in the absence of textile lubricating oil. This subject-matter does not appear in the Specification as accepted.
GB29565/46A 1945-12-06 1946-10-03 Anti-static textile materials Expired GB629659A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US633266A US2498408A (en) 1945-12-06 1945-12-06 Antistatic textile materials

Publications (1)

Publication Number Publication Date
GB629659A true GB629659A (en) 1949-09-26

Family

ID=24538948

Family Applications (1)

Application Number Title Priority Date Filing Date
GB29565/46A Expired GB629659A (en) 1945-12-06 1946-10-03 Anti-static textile materials

Country Status (4)

Country Link
US (1) US2498408A (en)
BE (1) BE469632A (en)
FR (1) FR937525A (en)
GB (1) GB629659A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE975308C (en) * 1953-12-21 1961-11-02 Boehme Fettchemie G M B H Antistatic rendering of finished textile fabrics or knitted fabrics made from fully synthetic fiber material

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2575382A (en) * 1949-12-21 1951-11-20 Celanese Corp Fiber lubricant composition
US2743193A (en) * 1953-08-10 1956-04-24 Eastman Kodak Co Treated cellulose organic acid ester fibers
US2978440A (en) * 1955-11-29 1961-04-04 Union Carbide Corp Anti-static vinyl chloride copolymer containing salts of dialkyl phosphates
US3144671A (en) * 1958-04-04 1964-08-18 Dow Chemical Co Dust cloth
US3341343A (en) * 1963-11-12 1967-09-12 Gen Anilline & Film Corp Hydrophobic polymeric resin containing phosphate ester antistatic agent and process for producing antistatic properties

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR706182A (en) * 1929-12-18 1931-06-19 I G Farbenindustrie Ag Soc Auxiliary agents for the textile industry
US2005619A (en) * 1934-11-10 1935-06-18 Du Pont Esters of acids of phosphorus
US2080299A (en) * 1935-04-12 1937-05-11 Du Pont Inhibiting corrosion of metals
US2345734A (en) * 1939-07-18 1944-04-04 Eastman Kodak Co Self-emulsifying phosphated and phosphited oils as antistatic lubricants

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE975308C (en) * 1953-12-21 1961-11-02 Boehme Fettchemie G M B H Antistatic rendering of finished textile fabrics or knitted fabrics made from fully synthetic fiber material

Also Published As

Publication number Publication date
US2498408A (en) 1950-02-21
FR937525A (en) 1948-08-19
BE469632A (en) 1900-01-01

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