GB615697A - New colouring matters of the azamethine series - Google Patents
New colouring matters of the azamethine seriesInfo
- Publication number
- GB615697A GB615697A GB2339946A GB2339946A GB615697A GB 615697 A GB615697 A GB 615697A GB 2339946 A GB2339946 A GB 2339946A GB 2339946 A GB2339946 A GB 2339946A GB 615697 A GB615697 A GB 615697A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iminophthalimidine
- reacted
- nitro
- methoxy
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/04—Isoindoline dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Indole Compounds (AREA)
Abstract
Dichloro-3-iminophthalimidine is obtained by heating 3.4-dichlorophthalimide with urea in presence of ammonium vanadate. Nitro-iminophthalimidines are obtained by heating 4- or 3-nitro-phthalimide with urea in presence of ammonium vanadate. Methoxy-3-iminophthalimidine is obtained by reacting 4-methoxyphthalimide with ammonia to give 4-methoxyphthalimide, which is dehydrated with acetic anhydride to give 4-(or 5-) methoxy-2-cyano-benzamide which is isomerised to the iminophthalimidine by heating. Imino-thiophthalimidine is obtained by passing hydrogen sulphide into a cold suspension of phthalonitrile in aqueous alcoholic sodium hydrogen sulphide.ALSO:Dyes are made by heating iminophthalimidine, thiophthalimide, or iminothiophthalimidine or a nuclear substitution product thereof (e.g. a methoxy-, chloro- or nitro-substitution product-see Group IV (b)) with an aromatic hydrazine or with an aromatic primary amine which contains in its molecular structure in addition to the amino group, a second amino group, or a substituted amino or hydrazino group, or a condensed ring attached to the aromatic nucleus, or a pendant ring attached through a linking group to the aromatic nucleus. Amines or hydrazines specified are m-phenylene diamine, 4,41-diaminoazobenzene, 4,41-diaminostilbene, o-tolidine, 3,31-dichlorbenzidine, 5-chloro - a - naphthylamine, 2-aminoanthracene, 2 - aminoanthraquinone, 1,4 - diaminoanthra - quinone, 3-aminocarbazole, copper-tetra-aminophthalocyanine, 2,4 - dinitrophenylhydrazine. Solvents may be used, e.g. alcohol or acetic acid. The products colour paper and polyvinyl chloride and dye cellulose acetate and nylon. They may be sulphonated to give wool dyes. In examples, iminophthalimidine is reacted with (1) dehydrothio-p-toluidine; (2) p-aminoazobenzene; (3) o-dianisidine hydrochloride; (4) p-phenylenediamine; (5) 2-aminobenzthiazole; (6) phenylhydrazine hydrochloride. Also in examples: (7) dichloro-3-iminophthalimidine is reacted with benzidine; (8) nitro-iminophthalimidine is reacted with p-sulphophenylhydrazine or dehydrothio - p - toluidine; (9) methoxy-3-iminophthalimidine is reacted with o-dianisidine hydrochloride; (10) iminothiophalimidine is reacted with o-dianisidine hydrochloride; (11) thiophthalimide is reacted with phenylhydrazine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2339946A GB615697A (en) | 1946-09-07 | 1946-09-07 | New colouring matters of the azamethine series |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2339946A GB615697A (en) | 1946-09-07 | 1946-09-07 | New colouring matters of the azamethine series |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB615697A true GB615697A (en) | 1949-01-10 |
Family
ID=10194979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2339946A Expired GB615697A (en) | 1946-09-07 | 1946-09-07 | New colouring matters of the azamethine series |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB615697A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2973358A (en) * | 1956-07-13 | 1961-02-28 | Geigy Ag J R | 4, 5, 6, 7-tetrachloro-3-imino-isoindoline-1-one derivatives |
-
1946
- 1946-09-07 GB GB2339946A patent/GB615697A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2973358A (en) * | 1956-07-13 | 1961-02-28 | Geigy Ag J R | 4, 5, 6, 7-tetrachloro-3-imino-isoindoline-1-one derivatives |
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