GB600839A - Production of nuclear methylated phenols from anisole - Google Patents
Production of nuclear methylated phenols from anisoleInfo
- Publication number
- GB600839A GB600839A GB1436745A GB1436745A GB600839A GB 600839 A GB600839 A GB 600839A GB 1436745 A GB1436745 A GB 1436745A GB 1436745 A GB1436745 A GB 1436745A GB 600839 A GB600839 A GB 600839A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anisole
- production
- methylated phenols
- nuclear methylated
- phenols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RDOXTESZEPMUJZ-UHFFFAOYSA-N Anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 title abstract 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002989 phenols Chemical class 0.000 title abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001896 cresols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by exchange of hydrocarbon groups, which may be substituted, from the same of other compounds, e.g. transalkylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/01—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis
- C07C37/055—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis the substituted group being bound to oxygen, e.g. ether group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Anisole is converted into phenol, mixed cresols and higher methylated phenols, by vapour phase contact at atmospheric pressure and at about 320 DEG C. with activated alumina as catalyst. A detailed example is given.
Publications (1)
Publication Number | Publication Date |
---|---|
GB600839A true GB600839A (en) | 1948-04-20 |
Family
ID=1730688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1436745A Expired GB600839A (en) | 1945-06-07 | Production of nuclear methylated phenols from anisole |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB600839A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4301308A (en) * | 1977-02-28 | 1981-11-17 | Societe Italiana Resine S.I.R. S.P.A. | Process for the preparation of o-cresol and 2,6-xylenol |
US4381413A (en) * | 1981-07-24 | 1983-04-26 | Conoco Inc. | Process for converting anisoles to ortho-methylated phenolic products |
EP0364378A1 (en) * | 1988-10-14 | 1990-04-18 | Rhone-Poulenc Chimie | Process for the preparation of methyl hydroquinone |
WO2014083426A1 (en) * | 2012-11-30 | 2014-06-05 | Toyota Jidosha Kabushiki Kaisha | Method for demeshylating or demethoxylating aromatic compound having methoxy group and catalyst used in the method |
-
1945
- 1945-06-07 GB GB1436745A patent/GB600839A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4301308A (en) * | 1977-02-28 | 1981-11-17 | Societe Italiana Resine S.I.R. S.P.A. | Process for the preparation of o-cresol and 2,6-xylenol |
US4381413A (en) * | 1981-07-24 | 1983-04-26 | Conoco Inc. | Process for converting anisoles to ortho-methylated phenolic products |
EP0364378A1 (en) * | 1988-10-14 | 1990-04-18 | Rhone-Poulenc Chimie | Process for the preparation of methyl hydroquinone |
FR2637893A1 (en) * | 1988-10-14 | 1990-04-20 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF METHYLHYDROQUINONE |
WO2014083426A1 (en) * | 2012-11-30 | 2014-06-05 | Toyota Jidosha Kabushiki Kaisha | Method for demeshylating or demethoxylating aromatic compound having methoxy group and catalyst used in the method |
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