GB598962A - Synthetic resins and their production - Google Patents

Synthetic resins and their production

Info

Publication number
GB598962A
GB598962A GB6718/45A GB671845A GB598962A GB 598962 A GB598962 A GB 598962A GB 6718/45 A GB6718/45 A GB 6718/45A GB 671845 A GB671845 A GB 671845A GB 598962 A GB598962 A GB 598962A
Authority
GB
United Kingdom
Prior art keywords
allyl
vinyl
alcohol
type
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6718/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Development Co
Original Assignee
Shell Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Development Co filed Critical Shell Development Co
Publication of GB598962A publication Critical patent/GB598962A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02Esters of monocarboxylic acids
    • C08F18/04Vinyl esters
    • C08F18/08Vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/20Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

A monomeric mixed ester of a polycarboxylic acid containing at least three carbon atoms in the molecule and in which at least one of the carboxyl hydrogen atoms of the acid has been replaced by the radical of an allyl-type alcohol and at least one other carboxyl hydrogen atom of the acid has been replaced by the radical of a vinyl-type alcohol is polymerized alone or together with an organic compound containing one or more unsaturated carbon to carbon linkages by the action of heat, light and/or catalysts, directly or in solution or dispersion. Among the specified polycarboxylic acids are malonic, succinic, glutaric, adipic, azelaic, methyl succinic, tricarballylic, citric, cyclopentane - 1,2,3 - tricarboxylic, phthalic, terephthalic, naphthalene dicarboxylic acids, diglycolic, dilactic, dihydracrylic acids and those of the class HOOC-R-SO2-R-COOH. Examples of vinyl-type alcohols are vinyl alcohol, iso - propenol, buten - 1 - ol - 2, propen - 1 - ol - 1, buten - 1 - ol - 1, cyclohexen - 1 p - ol - 1 - and cyclopenten - 1 - ol - 1. Among the specified allyl-type alcohols are allyl alcohol, chlorallyl alcohol, buten-1-ol-3, 2-methyl-penten - 1 - ol - 3, octan - 1 - ol - 3, 3 - tolyl - propen-1 - ol - 3, crotyl alcohol, tiglyl alcohol, and 5,7-dimethyl - octadien - 2,7 - ol - 1. Specified mixed allyl-type vinyl-type esters include allyl vinyl malonate, allyl vinyl succinate, allyl vinyl adipate, allyl vinyl phthalate, allyl vinyl diglycolate, methallyl vinylmalonate, allyl isopropenyl malonate, allyl isopropenyl dihydracrylate, diallyl vinyl citrate and divinyl allyl citrate. Typical compounds with which these esters may be copolymerized are styrene, vinyl halides, vinylidene halides, vinyl esters of saturated monocarboxylic acids, methyl acrylate, methyl methacrylate, allyl halides, allyl esters of saturated monocarboxylic acids, alkyds, conjugated butadiene, isoprene, conjugated chlorobutadiene, and diallyl glycolate. The usual polymerization catalysts are specified. The products may be mixed with other synthetic resins, natural resins, drying oils, urea-aldehyde resins, phenol-aldehyde resins, linear super-polyamides and polyesteramides as well as with the usual plasticizers, stabilizers, lubricants, dyes, pigments and fillers. Specification 575,386 is referred to.
GB6718/45A 1944-03-14 1945-03-16 Synthetic resins and their production Expired GB598962A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US598962XA 1944-03-14 1944-03-14

Publications (1)

Publication Number Publication Date
GB598962A true GB598962A (en) 1948-03-02

Family

ID=22025980

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6718/45A Expired GB598962A (en) 1944-03-14 1945-03-16 Synthetic resins and their production

Country Status (4)

Country Link
BE (1) BE476808A (en)
FR (1) FR957567A (en)
GB (1) GB598962A (en)
NL (1) NL70514C (en)

Also Published As

Publication number Publication date
FR957567A (en) 1950-02-23
BE476808A (en)
NL70514C (en)

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