GB586141A - Preparation of acrylic and methacrylic resinoid derivatives - Google Patents
Preparation of acrylic and methacrylic resinoid derivativesInfo
- Publication number
- GB586141A GB586141A GB1038444A GB1038444A GB586141A GB 586141 A GB586141 A GB 586141A GB 1038444 A GB1038444 A GB 1038444A GB 1038444 A GB1038444 A GB 1038444A GB 586141 A GB586141 A GB 586141A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mannitol
- dimethylene
- sorbitol
- dianhydro
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
Abstract
A synthetic resinoid substance is obtained by polymerizing the esters formed by treating anhydro derivatives of hexahydric alcohols or derivatives of hexahydric alcohols containing the groupings <FORM:0586141/IV/1> in caustic soda solution with the acid chlorides of acrylic or methacrylic acids, or in pyridine with the anhydrides of these acids. Polymerization is effected by heating the product, when a hard substance is obtained. A less hard material is obtained by mixing the product with methyl methacrylate before polymerization. In the examples, methacrylyl chloride is reacted in caustic soda solution with (1) dimethylene sorbitol to give dimethacrylyl dimethylene sorbitol; (2) dimethylene mannitol; (3) dianhydro mannitol; (4) dianhydro sorbitol; acrylyl chloride is reacted in caustic soda solution with (1) dimethylene mannitol; (2) dianhydro sorbitol; and methacrylic anhydride is reacted in pyridine solution with (1) dimethylene mannitol; (2) dibenzylidene sorbitol; (3) monoacetone mannitol; (4) dianhydro mannitol. The products in each case are polymerized. According to the Provisional Specification, any unsaturated acid may be used to esterify polyhydric alcohols, their anhydrides or hexose derivatives. Dimethacrylyldimethylene mannitol is also acetylated.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1038444A GB586141A (en) | 1944-05-30 | 1944-05-30 | Preparation of acrylic and methacrylic resinoid derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1038444A GB586141A (en) | 1944-05-30 | 1944-05-30 | Preparation of acrylic and methacrylic resinoid derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB586141A true GB586141A (en) | 1947-03-07 |
Family
ID=9966847
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1038444A Expired GB586141A (en) | 1944-05-30 | 1944-05-30 | Preparation of acrylic and methacrylic resinoid derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB586141A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011048739A1 (en) * | 2009-10-19 | 2011-04-28 | 第一工業製薬株式会社 | Cyclic (meth)acrylates and process for preparation thereof |
CN102686620A (en) * | 2009-10-19 | 2012-09-19 | 关西涂料株式会社 | Actinic-radiation curable composition |
WO2013066461A2 (en) | 2011-08-10 | 2013-05-10 | Palmese Giuseppe R | Renewable bio-based (meth) acrylated monomers as vinyl ester cross-linkers |
WO2014147340A1 (en) * | 2013-03-19 | 2014-09-25 | Roquette Freres | Cross-linkable compositions based on compounds of (meth)acrylated derivatives of dianhydrohexitol |
JP2015502963A (en) * | 2011-12-16 | 2015-01-29 | スリーエム イノベイティブ プロパティズ カンパニー | Oxirane-containing bisanhydrohexitol derivatives and uses thereof |
WO2018074305A1 (en) | 2016-10-18 | 2018-04-26 | 三菱瓦斯化学株式会社 | Diol, process for producing diol, di(meth)acrylate, and process for producing di(meth)acrylate |
WO2018178567A1 (en) | 2017-03-28 | 2018-10-04 | Roquette Freres | Acrylic derivatives of 1,4:3,6-dianhydrohexitol |
US11208420B2 (en) | 2016-11-22 | 2021-12-28 | Drexel University | Process to produce blended (meth)acrylate/vinyl ester resin cross-linkers |
-
1944
- 1944-05-30 GB GB1038444A patent/GB586141A/en not_active Expired
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102686620B (en) * | 2009-10-19 | 2014-11-05 | 关西涂料株式会社 | Actinic-radiation curable composition |
JP2011084535A (en) * | 2009-10-19 | 2011-04-28 | Dai Ichi Kogyo Seiyaku Co Ltd | Cyclic (meth)acrylate compound and method for producing the same |
CN102548997A (en) * | 2009-10-19 | 2012-07-04 | 第一工业制药株式会社 | Cyclic (meth)acrylates and process for preparation thereof |
CN102686620A (en) * | 2009-10-19 | 2012-09-19 | 关西涂料株式会社 | Actinic-radiation curable composition |
WO2011048739A1 (en) * | 2009-10-19 | 2011-04-28 | 第一工業製薬株式会社 | Cyclic (meth)acrylates and process for preparation thereof |
CN102548997B (en) * | 2009-10-19 | 2014-11-12 | 第一工业制药株式会社 | Cyclic (meth)acrylates and process for preparation thereof |
WO2013066461A2 (en) | 2011-08-10 | 2013-05-10 | Palmese Giuseppe R | Renewable bio-based (meth) acrylated monomers as vinyl ester cross-linkers |
WO2013066461A3 (en) * | 2011-08-10 | 2013-10-03 | Drexel University | Renewable bio-based (meth) acrylated monomers as vinyl ester cross-linkers |
US9644059B2 (en) | 2011-08-10 | 2017-05-09 | Drexel University | Renewable bio-based (meth)acrylated monomers as vinyl ester cross-linkers |
US9856343B2 (en) | 2011-08-10 | 2018-01-02 | Drexel University | Renewable bio-based (meth)acrylated monomers as vinyl ester cross-linkers |
US10053529B2 (en) | 2011-08-10 | 2018-08-21 | Drexel University | Renewable bio-based (meth)acrylated monomers as vinyl ester cross-linkers |
JP2015502963A (en) * | 2011-12-16 | 2015-01-29 | スリーエム イノベイティブ プロパティズ カンパニー | Oxirane-containing bisanhydrohexitol derivatives and uses thereof |
US9932438B2 (en) | 2011-12-16 | 2018-04-03 | 3M Innovative Properties Company | Oxirane-containing bisanhydrohexitol derivatives and uses thereof |
FR3003574A1 (en) * | 2013-03-19 | 2014-09-26 | Roquette Freres | CROSSLINKABLE COMPOSITIONS BASED ON COMPOUNDS OF DIANHYDROHEXITOL (METH) ACRYLATED DERIVATIVES |
WO2014147340A1 (en) * | 2013-03-19 | 2014-09-25 | Roquette Freres | Cross-linkable compositions based on compounds of (meth)acrylated derivatives of dianhydrohexitol |
WO2018074305A1 (en) | 2016-10-18 | 2018-04-26 | 三菱瓦斯化学株式会社 | Diol, process for producing diol, di(meth)acrylate, and process for producing di(meth)acrylate |
US11208420B2 (en) | 2016-11-22 | 2021-12-28 | Drexel University | Process to produce blended (meth)acrylate/vinyl ester resin cross-linkers |
US11718629B2 (en) | 2016-11-22 | 2023-08-08 | Drexel University | Process to produce blended (meth)acrylate/vinyl ester resin cross-linkers |
WO2018178567A1 (en) | 2017-03-28 | 2018-10-04 | Roquette Freres | Acrylic derivatives of 1,4:3,6-dianhydrohexitol |
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