GB585205A - Curing of polymeric materials - Google Patents

Curing of polymeric materials

Info

Publication number
GB585205A
GB585205A GB2522845A GB2522845A GB585205A GB 585205 A GB585205 A GB 585205A GB 2522845 A GB2522845 A GB 2522845A GB 2522845 A GB2522845 A GB 2522845A GB 585205 A GB585205 A GB 585205A
Authority
GB
Grant status
Application
Patent type
Prior art keywords
example
diisocyanate
acetone
mixtures
glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2522845A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83Chemically modified polymers
    • C08G18/84Chemically modified polymers by aldehydes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83Chemically modified polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers

Abstract

Organic diisocyanate modified polyesteramides are cured by heating in uniform admixture with a cellulose derivative, e.g. cellulose acetate or nitrate and benzyl cellulose, a curing agent, namely, formaldehyde or formaldehyde-liberating substance or a dichromate, and preferably a curing catalyst, namely, an acid or a substance which is substantially neutral, but which develops acidity under curing conditions. The ingredients are mixed by milling dry or in the presence of water or an organic solvent, and 25 to 175 parts of cellulose derivative are used per 100 parts of modified polyester amide. Additional compounding ingredients are fillers, for example, carbon black, iron oxide, clay, asbestos, blanc fixe, whiting, lithopone and mica; resins, for example, urea-formaldehyde and phenol-formaldehyde resins; other plastic materials, for example, natural or synthetic rubbers, vulcanized vegetable oils, dark substitute, white substitute, a Cumar resin, wood rosin and pitch; de-tackifying agents, that is to say, materials which reduce the tendency of the mix to stick to the rolls, for example, stearic acid, paraffin wax, oleic acid, lauric acid and dibutyl ammonium oleate; plasticisers, for example, tricresyl phosphate, dibutyl phthalate, butylphthalyl butyl glycollate, and N - alkyl - toluene - sulphonamides; stabilisers or anti-oxidants, for example, hydroquinone, N : N1 - hexamethylene - bis - ortho - benzamide, N - phenyl - a - naphthylamine, N - phenyl - b - naphthylamine and a : a - bis - (2 - hydroxy-3 : 5-dimethylphenyl) butane, as well as others commonly used in rubber technology. Small quantities of pigments, for example from 1-3 per cent by weight, such as are customarily used in rubber technology or in the coating composition art may also be used to impart colour. The ingredients are mixed and shaped or calendered on to a substrate followed by heating at 100-150 DEG C. Solvents or swelling agents may be incorporated, e.g. acetone, mixtures of benzene and acetone, mixtures of benzene and ethanol, mixtures of benzene and chloroform, mixtures of benzene and methylethyl ketone, mixtures of methyl ethyl ketone and tri-chlorethylene, and mixtures of acetone and the monoethyl ether of ethylene glycol. Polyester and polyamide-forming reactants specified are glycols, for example, ethylene glycol, diethylene glycol, trimethylene glycol, pentamethylene glycol, hexamethylene glycol, dodecamethylene glycol, 1 : 12-octadecanediol and pentaglycol; aliphatic or aromatic amino-alcohols having at least one hydrogen atom attached to the amino nitrogen atom and preferably containing an aliphatic chain of at least two carbon atoms separating the amino and hydroxyl groups, for example b -ethanolamine and 3-aminopropanol; dibasic carboxylic acids or ester-forming derivatives thereof, preferably aliphatic dicarboxylic acids, for example, malonic, succinic, glutaric, adipic, b -methyladipic, pimelic, suberic, azelaic, sebacic, undecanedioic, brassylic, iso-phthalic, hexahydroterephthalic, p-phenylene-diacetic, and acetone-dicarboxylic acids; primary and secondary diamines, for example, ethylene diamine, hexamethylenediamine, 3 - methylhexamethylene diamine, decamethylenediamine, m-phenylene-diamine, N : N1 - dimethylhexamethylene - diamine, N : N1 - diethylhexamethylenediamine and N : N1 - dimethyldecamethylenediamine; monohydroxymonocarboxylic acids or their ester-forming derivatives, for example, glycollic, 6-hydroxycaproic, 10-hydroxydecanoic and 12-hydroxystearic acids; polymerizable monoaminomonocarboxylic acids, or their ester-forming derivatives, for example, 6-aminocaproic acid or its lactam, caprolactam, and 9-aminononanoic, 11-aminoundecanoic and 12-aminostearic acids. Diisocyanates specified are ethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, hexamethylene diisocyanate, decamethylene diisocyanate, p-phenylene diisocyanate, m-phenylene diisocyanate, p : p1-diphenyl diisocyanate, diphenylmethane-4 : 41-diisocyanate, naphthalene diisocyanates and adipyl diisocyanate. Articles and applications specified are gaskets, packings, hose, diaphragms for pumps, flexible containers, the coating of rollers, blankets and stereos for use in the printing industry, protective sheathings for insulated electric cables and other electrical conductors, the coating of balls for games, tyres and flexible materials generally, including fabrics, protective clothing, leather cloth and floor coverings, and generally in the construction of articles requiring the use of a material having physical properties resembling those of rubber, but also having a good resistance to the action of organic fluids and a low permeability to gases and vapours. The compositions may be used as lacquers or finishing compositions or as substitutes for leather or adhesives for wood, metal, fabrics, paper, leather and regenerated cellulose. In the examples, the organic diisocyanate modified polyesteramide, as described in example 7 in Specification 580,524, is milled with hexamethylol-melamine hexamethyl ether, titanium dioxide, and 2 : 4-dichloro-1-naphthol, the mix is dissolved in benzene and acetone, and mixed with (1) cellulose acetate (acetone-soluble), and (2) nitrocellulose (obtainable under the name Collodion Cotton HX 30/50). In example 3, the same modified polyesteramide is mixed with cellulose acetate, carbon black, hexamethylol melamine hexamethyl ether, 2.4-dichloro-1-naphthol, ethylene glycol monoethyl ether and acetone, and used to provide a top-coating for the hydrolysed-leather-organic diisocyanate-modified polyesteramide-coated fabric obtained according to Specification 583,862. Specifications 580,526 and 581,146 also are referred to.
GB2522845A 1944-12-22 1944-12-22 Curing of polymeric materials Expired GB585205A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2522845A GB585205A (en) 1944-12-22 1944-12-22 Curing of polymeric materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2522845A GB585205A (en) 1944-12-22 1944-12-22 Curing of polymeric materials

Publications (1)

Publication Number Publication Date
GB585205A true true GB585205A (en) 1947-01-31

Family

ID=10224281

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2522845A Expired GB585205A (en) 1944-12-22 1944-12-22 Curing of polymeric materials

Country Status (1)

Country Link
GB (1) GB585205A (en)

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0903451A2 (en) * 1997-09-22 1999-03-24 Unilin Beheer B.V. Floor part, method for making such a floor part and device used thereby
US6324803B1 (en) 1993-05-10 2001-12-04 VäLINGE ALUMINUM AB System for joining building boards
US6510665B2 (en) 2000-01-24 2003-01-28 Valinge Aluminum Ab Locking system for mechanical joining of floorboards and method for production thereof
US6532709B2 (en) 1998-06-03 2003-03-18 Valinge Aluminium Ab Locking system and flooring board
US6588166B2 (en) 1995-03-07 2003-07-08 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US6606834B2 (en) 1995-03-07 2003-08-19 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US6715253B2 (en) 2000-04-10 2004-04-06 Valinge Aluminium Ab Locking system for floorboards
US6769218B2 (en) 2001-01-12 2004-08-03 Valinge Aluminium Ab Floorboard and locking system therefor
US7651751B2 (en) 2003-02-14 2010-01-26 Kronotec Ag Building board
US7677001B2 (en) 2003-03-06 2010-03-16 Valinge Innovation Ab Flooring systems and methods for installation
US7678425B2 (en) 2003-03-06 2010-03-16 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
US7739849B2 (en) 2002-04-22 2010-06-22 Valinge Innovation Ab Floorboards, flooring systems and methods for manufacturing and installation thereof
US7757452B2 (en) 2002-04-03 2010-07-20 Valinge Innovation Ab Mechanical locking system for floorboards
US7775007B2 (en) 1993-05-10 2010-08-17 Valinge Innovation Ab System for joining building panels
US7816001B2 (en) 2004-03-11 2010-10-19 Kronotec Ag Insulation board made of a mixture of wood base material and binding fibers
US7827749B2 (en) 2005-12-29 2010-11-09 Flooring Technologies Ltd. Panel and method of manufacture
US7841144B2 (en) 2005-03-30 2010-11-30 Valinge Innovation Ab Mechanical locking system for panels and method of installing same
US7845140B2 (en) 2003-03-06 2010-12-07 Valinge Innovation Ab Flooring and method for installation and manufacturing thereof
US7854986B2 (en) 2005-09-08 2010-12-21 Flooring Technologies Ltd. Building board and method for production
US7856784B2 (en) 1995-03-07 2010-12-28 Pergo AG Flooring panel or wall panel and use thereof
US7877956B2 (en) 1999-07-05 2011-02-01 Pergo AG Floor element with guiding means
US7886497B2 (en) 2003-12-02 2011-02-15 Valinge Innovation Ab Floorboard, system and method for forming a flooring, and a flooring formed thereof
US7908816B2 (en) 2003-03-24 2011-03-22 Kronotec Ag Device for connecting building boards, especially floor panels
US7926234B2 (en) 2002-03-20 2011-04-19 Valinge Innovation Ab Floorboards with decorative grooves
US8003168B2 (en) 2003-09-06 2011-08-23 Kronotec Ag Method for sealing a building panel
US8028486B2 (en) 2001-07-27 2011-10-04 Valinge Innovation Ab Floor panel with sealing means
US8042484B2 (en) 2004-10-05 2011-10-25 Valinge Innovation Ab Appliance and method for surface treatment of a board shaped material and floorboard
US8061104B2 (en) 2005-05-20 2011-11-22 Valinge Innovation Ab Mechanical locking system for floor panels
US8176698B2 (en) 2003-10-11 2012-05-15 Kronotec Ag Panel
US8215078B2 (en) 2005-02-15 2012-07-10 Välinge Innovation Belgium BVBA Building panel with compressed edges and method of making same
US8245477B2 (en) 2002-04-08 2012-08-21 Välinge Innovation AB Floorboards for floorings
US8250825B2 (en) 2001-09-20 2012-08-28 Välinge Innovation AB Flooring and method for laying and manufacturing the same
US8257791B2 (en) 2002-11-12 2012-09-04 Kronotec Ag Process of manufacturing a wood fiberboard, in particular floor panels
US8402709B2 (en) 1995-03-07 2013-03-26 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US8475871B2 (en) 2005-09-08 2013-07-02 Flooring Technologies Ltd. Building board and method for production
US8544233B2 (en) 2000-03-31 2013-10-01 Pergo (Europe) Ab Building panels
US8615952B2 (en) 2010-01-15 2013-12-31 Pergo (Europe) Ab Set of panels comprising retaining profiles with a separate clip and method for inserting the clip
US8627631B2 (en) 2000-06-20 2014-01-14 Flooring Industries Limited, Sarl Floor covering
US8833029B2 (en) 2002-11-12 2014-09-16 Kronotec Ag Floor panel
US8850769B2 (en) 2002-04-15 2014-10-07 Valinge Innovation Ab Floorboards for floating floors
US8978334B2 (en) 2010-05-10 2015-03-17 Pergo (Europe) Ab Set of panels
US9169658B2 (en) 2002-11-15 2015-10-27 Kronotec Ag Floor panel and method of laying a floor panel
US9322183B2 (en) 2004-01-13 2016-04-26 Valinge Innovation Ab Floor covering and locking systems
US9322162B2 (en) 1998-02-04 2016-04-26 Pergo (Europe) Ab Guiding means at a joint
US9365028B2 (en) 2006-02-21 2016-06-14 Flooring Technologies Ltd. Method for finishing a building board and building board
US9464443B2 (en) 1998-10-06 2016-10-11 Pergo (Europe) Ab Flooring material comprising flooring elements which are assembled by means of separate flooring elements

Cited By (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7823359B2 (en) 1993-05-10 2010-11-02 Valinge Innovation Ab Floor panel with a tongue, groove and a strip
US6324803B1 (en) 1993-05-10 2001-12-04 VäLINGE ALUMINUM AB System for joining building boards
US7775007B2 (en) 1993-05-10 2010-08-17 Valinge Innovation Ab System for joining building panels
US6516579B1 (en) 1993-05-10 2003-02-11 Tony Pervan System for joining building boards
US7856784B2 (en) 1995-03-07 2010-12-28 Pergo AG Flooring panel or wall panel and use thereof
US8661762B2 (en) 1995-03-07 2014-03-04 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US6588166B2 (en) 1995-03-07 2003-07-08 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US6606834B2 (en) 1995-03-07 2003-08-19 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US8875465B2 (en) 1995-03-07 2014-11-04 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US9032685B2 (en) 1995-03-07 2015-05-19 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
US8402709B2 (en) 1995-03-07 2013-03-26 Pergo (Europe) Ab Flooring panel or wall panel and use thereof
EP0903451A3 (en) * 1997-09-22 1999-08-04 Unilin Beheer B.V. Floor part, method for making such a floor part and device used thereby
EP0903451A2 (en) * 1997-09-22 1999-03-24 Unilin Beheer B.V. Floor part, method for making such a floor part and device used thereby
US9322162B2 (en) 1998-02-04 2016-04-26 Pergo (Europe) Ab Guiding means at a joint
US6532709B2 (en) 1998-06-03 2003-03-18 Valinge Aluminium Ab Locking system and flooring board
US9464443B2 (en) 1998-10-06 2016-10-11 Pergo (Europe) Ab Flooring material comprising flooring elements which are assembled by means of separate flooring elements
US7877956B2 (en) 1999-07-05 2011-02-01 Pergo AG Floor element with guiding means
US6510665B2 (en) 2000-01-24 2003-01-28 Valinge Aluminum Ab Locking system for mechanical joining of floorboards and method for production thereof
US8011155B2 (en) 2000-01-24 2011-09-06 Valinge Innovation Ab Locking system for mechanical joining of floorboards and method for production thereof
US8234831B2 (en) 2000-01-24 2012-08-07 Välinge Innovation AB Locking system for mechanical joining of floorboards and method for production thereof
US7779596B2 (en) 2000-01-24 2010-08-24 Valinge Innovation Ab Locking system for mechanical joining of floorboards and method for production thereof
US9255414B2 (en) 2000-03-31 2016-02-09 Pergo (Europe) Ab Building panels
US8544233B2 (en) 2000-03-31 2013-10-01 Pergo (Europe) Ab Building panels
US8578675B2 (en) 2000-03-31 2013-11-12 Pergo (Europe) Ab Process for sealing of a joint
US9534397B2 (en) 2000-03-31 2017-01-03 Pergo (Europe) Ab Flooring material
US9611656B2 (en) 2000-03-31 2017-04-04 Pergo (Europe) Ab Building panels
US9260869B2 (en) 2000-03-31 2016-02-16 Pergo (Europe) Ab Building panels
US9316006B2 (en) 2000-03-31 2016-04-19 Pergo (Europe) Ab Building panels
US9677285B2 (en) 2000-03-31 2017-06-13 Pergo (Europe) Ab Building panels
US6715253B2 (en) 2000-04-10 2004-04-06 Valinge Aluminium Ab Locking system for floorboards
US9234356B2 (en) 2000-06-20 2016-01-12 Flooring Industries Limited, Sarl Floor covering
US9624676B2 (en) 2000-06-20 2017-04-18 Flooring Industries Limited, Sarl Floor covering
US9334657B2 (en) 2000-06-20 2016-05-10 Flooring Industries Limted, Sarl Floor covering
US8631625B2 (en) 2000-06-20 2014-01-21 Flooring Industries Limited, Sarl Floor covering
US8904729B2 (en) 2000-06-20 2014-12-09 Flooring Industries Limited, Sarl Floor covering
US9376823B1 (en) 2000-06-20 2016-06-28 Flooring Industries Limited, Sarl Floor covering
US8793958B2 (en) 2000-06-20 2014-08-05 Flooring Industries Limited, Sarl Floor covering
US9388586B1 (en) 2000-06-20 2016-07-12 Flooring Industries Limited, Sarl Floor covering
US9068356B2 (en) 2000-06-20 2015-06-30 Flooring Industries Limited, Sarl Floor covering
US9388585B1 (en) 2000-06-20 2016-07-12 Flooring Industries Limited, Sarl Floor covering
US9394699B1 (en) 2000-06-20 2016-07-19 Flooring Industries Limited, Sarl Floor covering
US9482013B2 (en) 2000-06-20 2016-11-01 Flooring Industries Limited, Sarl Floor covering
US9856657B2 (en) 2000-06-20 2018-01-02 Flooring Industries Limited, Sarl Floor covering
US8627631B2 (en) 2000-06-20 2014-01-14 Flooring Industries Limited, Sarl Floor covering
US6769218B2 (en) 2001-01-12 2004-08-03 Valinge Aluminium Ab Floorboard and locking system therefor
US8584423B2 (en) 2001-07-27 2013-11-19 Valinge Innovation Ab Floor panel with sealing means
US8028486B2 (en) 2001-07-27 2011-10-04 Valinge Innovation Ab Floor panel with sealing means
US8250825B2 (en) 2001-09-20 2012-08-28 Välinge Innovation AB Flooring and method for laying and manufacturing the same
US7926234B2 (en) 2002-03-20 2011-04-19 Valinge Innovation Ab Floorboards with decorative grooves
US8683698B2 (en) 2002-03-20 2014-04-01 Valinge Innovation Ab Method for making floorboards with decorative grooves
US7757452B2 (en) 2002-04-03 2010-07-20 Valinge Innovation Ab Mechanical locking system for floorboards
US8245477B2 (en) 2002-04-08 2012-08-21 Välinge Innovation AB Floorboards for floorings
US8850769B2 (en) 2002-04-15 2014-10-07 Valinge Innovation Ab Floorboards for floating floors
US7739849B2 (en) 2002-04-22 2010-06-22 Valinge Innovation Ab Floorboards, flooring systems and methods for manufacturing and installation thereof
US8257791B2 (en) 2002-11-12 2012-09-04 Kronotec Ag Process of manufacturing a wood fiberboard, in particular floor panels
US8833029B2 (en) 2002-11-12 2014-09-16 Kronotec Ag Floor panel
US9169658B2 (en) 2002-11-15 2015-10-27 Kronotec Ag Floor panel and method of laying a floor panel
US7651751B2 (en) 2003-02-14 2010-01-26 Kronotec Ag Building board
US7845140B2 (en) 2003-03-06 2010-12-07 Valinge Innovation Ab Flooring and method for installation and manufacturing thereof
US7677001B2 (en) 2003-03-06 2010-03-16 Valinge Innovation Ab Flooring systems and methods for installation
US7678425B2 (en) 2003-03-06 2010-03-16 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
US7790293B2 (en) 2003-03-06 2010-09-07 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
US8016969B2 (en) 2003-03-06 2011-09-13 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
US7908816B2 (en) 2003-03-24 2011-03-22 Kronotec Ag Device for connecting building boards, especially floor panels
US8003168B2 (en) 2003-09-06 2011-08-23 Kronotec Ag Method for sealing a building panel
US8176698B2 (en) 2003-10-11 2012-05-15 Kronotec Ag Panel
US7886497B2 (en) 2003-12-02 2011-02-15 Valinge Innovation Ab Floorboard, system and method for forming a flooring, and a flooring formed thereof
US8293058B2 (en) 2003-12-02 2012-10-23 Valinge Innovation Ab Floorboard, system and method for forming a flooring, and a flooring formed thereof
US8613826B2 (en) 2003-12-02 2013-12-24 Valinge Innovation Ab Floorboard, system and method for forming a flooring, and a flooring formed thereof
US9322183B2 (en) 2004-01-13 2016-04-26 Valinge Innovation Ab Floor covering and locking systems
US7816001B2 (en) 2004-03-11 2010-10-19 Kronotec Ag Insulation board made of a mixture of wood base material and binding fibers
US9623433B2 (en) 2004-10-05 2017-04-18 Valinge Innovation Ab Appliance and method for surface treatment of a board shaped material and floorboard
US8042484B2 (en) 2004-10-05 2011-10-25 Valinge Innovation Ab Appliance and method for surface treatment of a board shaped material and floorboard
US8215078B2 (en) 2005-02-15 2012-07-10 Välinge Innovation Belgium BVBA Building panel with compressed edges and method of making same
US7841144B2 (en) 2005-03-30 2010-11-30 Valinge Innovation Ab Mechanical locking system for panels and method of installing same
US8061104B2 (en) 2005-05-20 2011-11-22 Valinge Innovation Ab Mechanical locking system for floor panels
US7854986B2 (en) 2005-09-08 2010-12-21 Flooring Technologies Ltd. Building board and method for production
US8475871B2 (en) 2005-09-08 2013-07-02 Flooring Technologies Ltd. Building board and method for production
US9816278B2 (en) 2005-12-29 2017-11-14 Flooring Technologies Ltd. Panel and method of manufacture
US7827749B2 (en) 2005-12-29 2010-11-09 Flooring Technologies Ltd. Panel and method of manufacture
US9365028B2 (en) 2006-02-21 2016-06-14 Flooring Technologies Ltd. Method for finishing a building board and building board
US9115500B2 (en) 2010-01-15 2015-08-25 Pergo (Europe) Ab Set of panels comprising retaining profiles with a separate clip and method for inserting the clip
US8615952B2 (en) 2010-01-15 2013-12-31 Pergo (Europe) Ab Set of panels comprising retaining profiles with a separate clip and method for inserting the clip
US8631623B2 (en) 2010-01-15 2014-01-21 Pergo (Europe) Ab Set of panels comprising retaining profiles with a separate clip and method for inserting the clip
US9464444B2 (en) 2010-01-15 2016-10-11 Pergo (Europe) Ab Set of panels comprising retaining profiles with a separate clip and method for inserting the clip
US8978334B2 (en) 2010-05-10 2015-03-17 Pergo (Europe) Ab Set of panels
US9593491B2 (en) 2010-05-10 2017-03-14 Pergo (Europe) Ab Set of panels

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