GB583426A - Improvement in curing butadiene copolymers - Google Patents

Improvement in curing butadiene copolymers

Info

Publication number
GB583426A
GB583426A GB20810/44A GB2081044A GB583426A GB 583426 A GB583426 A GB 583426A GB 20810/44 A GB20810/44 A GB 20810/44A GB 2081044 A GB2081044 A GB 2081044A GB 583426 A GB583426 A GB 583426A
Authority
GB
United Kingdom
Prior art keywords
thiuramdisulphide
whiting
disulphide
cure
curing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20810/44A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uniroyal Inc
Original Assignee
United States Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Rubber Co filed Critical United States Rubber Co
Publication of GB583426A publication Critical patent/GB583426A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • C08K5/08Quinones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The rate of cure of a copolymer of butadiene and styrene with a member of the chlorinated class of vulcanizing agents such as tetrachlor parabenzoquinone is reduced by adding a small amount, preferably 0.01-4 per cent. of a thiuramdisulphide to the stock before cure. The thiuramdisulphide has the general structure <FORM:0583426/V/1> in which both the terminal nitrogens are bonded to aliphatic hydrocarbon radicles such as alkyl, cycloalkyl or arylalkyl such as ethyl, butyl, amyl, cyclopentamethylene or benzyl, the preferred compound being a tetra-alkylthiuramdisulphide such as tetramethylthiuram disulphide, or a disubstituted thiuram disulphide such as dibenzyl thiuram disulphide. Other substances which may be added to the mixes are fatty acid coated whiting, fine particle size whiting, mineral rubber, zinc oxide, stearic acid and an oxidizing agent such as lead peroxide.
GB20810/44A 1944-01-15 1944-10-25 Improvement in curing butadiene copolymers Expired GB583426A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US583426XA 1958-10-10 1958-10-10

Publications (1)

Publication Number Publication Date
GB583426A true GB583426A (en) 1946-12-18

Family

ID=22016234

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20810/44A Expired GB583426A (en) 1944-01-15 1944-10-25 Improvement in curing butadiene copolymers

Country Status (2)

Country Link
BE (1) BE583426A (en)
GB (1) GB583426A (en)

Also Published As

Publication number Publication date
BE583426A (en) 1960-02-01

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