GB567379A - Sheet materials of improved resistance to shattering - Google Patents

Sheet materials of improved resistance to shattering

Info

Publication number
GB567379A
GB567379A GB6180/43A GB618043A GB567379A GB 567379 A GB567379 A GB 567379A GB 6180/43 A GB6180/43 A GB 6180/43A GB 618043 A GB618043 A GB 618043A GB 567379 A GB567379 A GB 567379A
Authority
GB
United Kingdom
Prior art keywords
layer
bonded
wire
plasticized
mesh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6180/43A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB567379A publication Critical patent/GB567379A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers

Abstract

567,379. Compound sheet material. BRITISH CELANESE, Ltd. April 17, 1943, No. 6180. Convention date, March 20, 1942. [Class 140] Compound sheet material adapted to be shaped under the influence of heat, comprises a soft layer of transparent thermoplastic material having embedded in it an open-mesh wire fabric adapted to minimise shattering of the material by bullets and at least one hard layer of transparent thermoplastic material bonded to the soft layer, the soft layer being adapted to allow movement of the wire-mesh at temperatures suitable for bending the materialwithout permanently impairing the optical homogeneity of that layer. A hard layer may be bonded on each side of the soft layer. An anti-fogging layer, which may comprise cellulose acetate treated with a saponifying agent either before or after bonding, may be applied to one or both sides of the material. As shown, a soft layer A of thermoplastic material has ernbedded in it an open-mesh wire fabric W, two hard layers B and C of thermoplastic material bonded to opposite faces of A, and an anti-fogging layer D bonded to the outer face of B. A layer D may also be bonded to the outer face of C, or C may be dispensed with and the second layer D bonded directly to A. The individual wire of the fabric may be crimped at intervals as shown at 3. Layer A may comprise highly plasticized cellulose derivative sheets, e.g. cellulose acetate, acetatepropionate, acetate-butyrate, nitrate, or other (e.g. ethyl or benzyl cellulose), or highly plasticized sheets of polyvinyl acetate, copolymers of vinyl acetate and chloride, polymerized vinylidene chloride, poly methyl and/or ethyl acrylate, poly methyl methacrylate, polystyrene, or polyvinyl acetal. Plasticizers specified are dimethoxyethyl phthalate, dimethyl phthalate, diethyl phthalate, triacetin, dibutyl tartrate, methyl phthalyl ethyl glycollate, ethyl p-toluene-sulphonamide, triphenyl phosphate, isobutylene glycol, glycol derivatives (e.g. tri- or tetra-ethylene polyglycol esters and ethers), butyl phthalyl butyl glycollate, a mixture of ethyl o- and p-toluenesulphonamide, ethyl phthalyl ethyl glycollate, chlorinated diphenyls, dibutyl phthalate, and tricresyl phosphate. The soft layer may contain 70-85 parts by weight of plasticizer, and the hard layers less than 50 parts, e.g. 23-45 parts. The hard layer or layers may be of plasticized cellulose acetate and the soft layer of plasticized polyvinyl acetate, the layers being united by the use of mutual solvents. The wire mesh may be formed of fine gauge high-tensile strength steel or alloy and of square or hexagonal mesh. The material may be moulded at about 325‹ F. if of cellulose acetate. The wire mesh may be embedded in the layer as it is formed by casting or extrusion, or two preformed sheets may be bonded together with the wire mesh between. The wire may be precoated with a soft plastic composition. A wire fabric may be placed on a soft preformed sheet and a layer of plastic flowed, brushed, or sprayed thereover. The hard layer may be of the same chemical material as the soft layer, or may be of inherently harder and/or tougher material. It may be built up of two or more layers, the outer being harder and/or tougher than the inner. The two hard layers may be of different composition or thickness. The compound material may have from two to seven layers. One or more layers may contain dyes and/or ultra-violet light absorbers. The material may be made opaque or translucent by addition of fillers and pigments. In example 1, a cellulose acetate sheet highly plasticized with dimethoxyethyl phthalate and having a wire-mesh fabric embedded therein, is bonded between cellulose acetate sheets lightly plasticized with dimethoxyethyl phthalate. In example 2, a polyvinyl acetate sheet highly plasticized with methylphthalyl, ethylglycollate and having wire-mesh fabric embedded therein, is bonded between polyvinyl acetate sheets lightly plasticized with methylphthalyl ethyl glycollate. In example 4, plasticized polyvinyl acetal resin having open-mesh wire fabrio embedded therein, is bonded to a sheet of cellulose acetate plasticized with dimethyl phthalate. In example 3, plasticized polyvinyl acetal resin having wire-mesh fabric embedded therein is bonded between polymerized methyl methacrylate sheets or (in example 15) between polystyrene sheets. The Specification as open to inspection under Sect. 91 refers also to an ethyl cellulose sheet plasticized with methylphthalyl ethylglycollate, together with a stabilizer, and having wiremesh fabric embedded therein bonded between cellulose acetate sheets plasticized with dimethyl phthalate. This subject-matter does not appear in the Specification as accepted.
GB6180/43A 1942-03-20 1943-04-17 Sheet materials of improved resistance to shattering Expired GB567379A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US567379XA 1942-03-20 1942-03-20

Publications (1)

Publication Number Publication Date
GB567379A true GB567379A (en) 1945-02-12

Family

ID=22006294

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6180/43A Expired GB567379A (en) 1942-03-20 1943-04-17 Sheet materials of improved resistance to shattering

Country Status (1)

Country Link
GB (1) GB567379A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013124147A1 (en) * 2012-02-20 2013-08-29 Teijin Aramid Gmbh Composite for producing of an antiballistic article

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013124147A1 (en) * 2012-02-20 2013-08-29 Teijin Aramid Gmbh Composite for producing of an antiballistic article

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