GB545729A - A solvent extraction process for the separation of ethyl chloride and butane - Google Patents
A solvent extraction process for the separation of ethyl chloride and butaneInfo
- Publication number
- GB545729A GB545729A GB15575/40A GB1557540A GB545729A GB 545729 A GB545729 A GB 545729A GB 15575/40 A GB15575/40 A GB 15575/40A GB 1557540 A GB1557540 A GB 1557540A GB 545729 A GB545729 A GB 545729A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solvent
- ethyl
- ethyl chloride
- butane
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 title abstract 8
- 229960003750 ethyl chloride Drugs 0.000 title abstract 8
- 239000001273 butane Substances 0.000 title abstract 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 title abstract 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 238000000926 separation method Methods 0.000 title abstract 2
- 238000000638 solvent extraction Methods 0.000 title 1
- 239000002904 solvent Substances 0.000 abstract 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 5
- 235000019441 ethanol Nutrition 0.000 abstract 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 3
- 238000011084 recovery Methods 0.000 abstract 3
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 229910000978 Pb alloy Inorganic materials 0.000 abstract 1
- WBLCSWMHSXNOPF-UHFFFAOYSA-N [Na].[Pb] Chemical compound [Na].[Pb] WBLCSWMHSXNOPF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000012296 anti-solvent Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical group CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/24—Lead compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
545,729. Separating ethyl chloride and butane. STANDARD OIL DEVELOPMENT CO. Oct. 23, 1940, No. 15575. Convention date, Nov. 3, 1939. [Class 2 (iii)] Ethyl chloride and butane are separated by treatment with a selective solvent such as methyl, ethyl, isopropyl or mixed alcohols or ethylene or propylene glycol, and particularly an aqueous ethyl alcohol. The process is particularly applicable for the separation of the azeotropic mixture obtained by distillation in the recovery of ethyl chloride in the formation of lead tetraethyl by heating under pressure a sodium lead alloy with excess of ethyl chloride preferably in presence of a catalyst such as pyridine or ethyl bromide. The mixture is fed through inlet 2 into a tower 1 maintained at from -10‹ C. to 100 ‹ C. and at a pressure which may be up to 200 lbs. per square inch, sufficient to maintain the material liquid, into a current of solvent from an inlet 3. The butane phase passes from the top of the tower to a recovery unit 5 where butane is separated preferably by distillation from the solvent. The solvent extract passes from the bottom of the tower to a recovery unit 10 where the ethyl chloride is separated preferably by distillation from the solvent. If ethyl alcohol is used as the solvent, the extract may be passed to a vessel 18 where it is treated with hydrogen chloride to form ethyl chloride from the alcohol. The selectivity of the solvent for ethyl chloride may be increased by addition of anti-solvents such as ethylene glycol or formamide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US545729XA | 1939-11-03 | 1939-11-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB545729A true GB545729A (en) | 1942-06-10 |
Family
ID=21992031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15575/40A Expired GB545729A (en) | 1939-11-03 | 1940-10-23 | A solvent extraction process for the separation of ethyl chloride and butane |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR889592A (en) |
| GB (1) | GB545729A (en) |
-
1940
- 1940-10-23 GB GB15575/40A patent/GB545729A/en not_active Expired
- 1940-11-23 FR FR889592D patent/FR889592A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR889592A (en) | 1944-01-13 |
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