GB545324A - Interpolymers of styrene with heat-blended oil varnishes - Google Patents

Interpolymers of styrene with heat-blended oil varnishes

Info

Publication number
GB545324A
GB545324A GB1542540A GB1542540A GB545324A GB 545324 A GB545324 A GB 545324A GB 1542540 A GB1542540 A GB 1542540A GB 1542540 A GB1542540 A GB 1542540A GB 545324 A GB545324 A GB 545324A
Authority
GB
United Kingdom
Prior art keywords
oil
prepared
resin
varnish
interpolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1542540A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US285192A priority Critical patent/US2225534A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB1542540A priority patent/GB545324A/en
Publication of GB545324A publication Critical patent/GB545324A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F242/00—Copolymers of drying oils with other monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04—Rosin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

545,324. Vinyl polymerization products. DU PONT DE NEMOURS & CO., E. I., FLINT, R. B., and ROTHROCK, H. S. Oct. 18, 1940, No. 15425. [Class 2 (iii)] Synthetic resinous interpolymers are prepared by heating styrene with the product obtained by heat blending a frosting drying oil with a varnish gum or resin. The frosting drying oil may be China wood oil, oiticica oil or Japanese wood oil, or mixtures thereof with non-frosting drying or semi-drying oils, e.g: linseed, soya or castor oil. The varnish gum or resin may be any oil-soluble resin, natural or synthetic, e.g. rosin copals, oil-soluble phenol-formaldehyde resins, ester gums and phenol-modified ester gums, or coumarone-indene resins. Small proportions of other vinyl compounds, e.g. methyl methacrylate or methyl vinyl ketone may be incorporated with the styrene. The interpolymerization may be effected (a) with the aid of polymerization catalysts, e.g. organic peroxides such as benzoyl, acetyl and urea peroxides, ozone or stannic chloride, (b) in the presence of actinic light and (c) in the presence of inert solvents such as benzene, toluene or xylene. The interpolymers are soluble in dioxan, butyl acetate and in aromatic hydrocarbons, may be incorporated with plasticizers, e.g. dibutyl phthalate or dixylyl ethane or with pigments, and may be employed in the preparation of films, enamels and coating compositions. In examples, interpolymers are prepared by heating styrene in xylene solution and in the presence of benzoyl peroxide with a varnish prepared from China wood oil and (1) an oil-soluble rosin-modified phenol formaldehyde resin, (2) p-hydroxydiphenyl-formaldehyde resin ; (3) rosin and (4) p-tertiary amyl phenolformaldehyde resin. In example (5), the varnish comprises a mixture of linseed oil and the varnish of example (1), and in example (6) an enamel is prepared by grinding a mixture of titanium dioxide and antimony oxide with the interpolymer of example (1) in high flash solvent naphtha. Dixylylethane is prepared from xylene and acetylene in the presence of sulphuric acid and mercuric sulphate. Specification 516,344 is referred to.
GB1542540A 1939-07-18 1940-10-18 Interpolymers of styrene with heat-blended oil varnishes Expired GB545324A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US285192A US2225534A (en) 1939-07-18 1939-07-18 Copolymers of styrene with frosting drying oil varnishfs
GB1542540A GB545324A (en) 1940-10-18 1940-10-18 Interpolymers of styrene with heat-blended oil varnishes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1542540A GB545324A (en) 1940-10-18 1940-10-18 Interpolymers of styrene with heat-blended oil varnishes

Publications (1)

Publication Number Publication Date
GB545324A true GB545324A (en) 1942-05-20

Family

ID=10058896

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1542540A Expired GB545324A (en) 1939-07-18 1940-10-18 Interpolymers of styrene with heat-blended oil varnishes

Country Status (1)

Country Link
GB (1) GB545324A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE951770C (en) * 1942-07-28 1956-10-31 Lewis Berger & Sons Ltd Process for the production of coating resins from styrene and mixed esters of polyhydric alcohols
DE975683C (en) * 1946-02-15 1962-05-03 Lewis Berger & Sons Ltd Process for the preparation of polymerization products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE951770C (en) * 1942-07-28 1956-10-31 Lewis Berger & Sons Ltd Process for the production of coating resins from styrene and mixed esters of polyhydric alcohols
DE975683C (en) * 1946-02-15 1962-05-03 Lewis Berger & Sons Ltd Process for the preparation of polymerization products

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