GB540368A - Improvements in and relating to colour couplers and to colour photographic materialscontaining them - Google Patents

Improvements in and relating to colour couplers and to colour photographic materialscontaining them

Info

Publication number
GB540368A
GB540368A GB33070/39A GB3307039A GB540368A GB 540368 A GB540368 A GB 540368A GB 33070/39 A GB33070/39 A GB 33070/39A GB 3307039 A GB3307039 A GB 3307039A GB 540368 A GB540368 A GB 540368A
Authority
GB
United Kingdom
Prior art keywords
emulsion
emulsions
colour
layers
acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33070/39A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB540368A publication Critical patent/GB540368A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/835Macromolecular substances therefor, e.g. mordants
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/388Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor
    • G03C7/3882Processes for the incorporation in the emulsion of substances liberating photographically active agents or colour-coupling substances; Solvents therefor characterised by the use of a specific polymer or latex
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/924Significant dispersive or manipulative operation or step in making or stabilizing colloid system
    • Y10S516/928Mixing combined with non-mixing operation or step, successively or simultaneously, e.g. heating, cooling, ph change, ageing, milling

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

540,368. Colour photography. POTTS, H. E (Eastman Kodak Co.). Dec. 29, 1939, No. 33070. [Class 98 (ii)] A photographic light-sensitive emulsion of a silver salt, such as a silver halide, in a waterinsoluble water-permeable binder, such as cellulose nitrate, acetate, acetate-phthalate, acetatepropionate, acetate-butyrate, or ether, or collodion, or gum mastic, gum dammar, gum sandarach, or gum elemi, or polystyrene, polymethylmethacrylate, or polyvinyl acetate, or coumarone-indene resin, has dispersed therein fine discrete particles of a water-soluble colloid such as gelatine or agar-agar not containing lightsensitive silver salt, but containing a dye, a dye derivative, or a dye-forming substance. Hydrolyzed cellulose organic acid esters may be used for the binder. Multi-emulsion material including at least one emulsion of the above type may be (1) two layers, one of continuous type and one of two-grain type; (2) three layers, (a) each of continuous type, (b) two layers of continuous type and one of one-grain type in any order, or (c) two layers of one-grain type and one of continuous type in any order. Certain of the layers may be of the kind described and claimed in Specifications 524,154, 524,554, and 524,555. The colour processing baths may contain organic liquids or wetting agents to facilitate penetration. The porosity of the binder may be reduced or increased as described in Specification 540,366. Porosity may be decreased by hardening the binder with chromium salts. The emulsions may be treated before coating as described in Specification 540,367. Silver chloride or chlorobromide, if desired further sensitized to blue, may be used for the emulsion to record blue, and silver bromide for the emulsions to record green and red. Basic sensitizing dyes, such as pinacyanole or the neothiazolocarbocyanine from 2:4-dimethylthiazole, may be used for silver halide-cellulose ester emulsions, and acid dyes, such as erythrosin, may be employed with silver halide gelatine emulsions. Anti-halation or filter layers may be provided, and a sound track may be recorded in one or more of the picture emulsions or in a separate emulsion. Examples of colour couplers are 1:4-phenylenebis-3-(1-phenyl-5-pyrazolone) and cyanoacet- #-naphthalide. A transparent or opaque support, such as cellulose nitrate or acetate, or paper, may be employed. In an example, an alcoholic sodium hydroxide solution of 2- lauryl-4-chlorophenol is added to an alkaline gelatine solution and citric acid is added. The dispersion is added to an emulsion containing silver bromide, cellulose acetate propionate, ethylene chloride, and ethyl alcohol red-sensitized with 5-4-(3-ethyl-2-benzothiazolidine)-2-butenylidene-3-n-heptyl-1-phenyl-2-thio-hydantoin, additional ethylene chloride is added, and the emulsion is passed through a colloid mill or homogenizer and is coated on a support. In a second example a similar emulsion is green-sensitized with 5-(3-ethyl-2-benzoxazolylidene)-ethylidene- 3-n-heptyl-l-phenyl-2-thiohydantoin and the colour coupler employed is 2-cyanoacetyl-5-(p-secamylbenzoylamino)-ooumarone. In a third example the emulsion is not specially sensitized and the colour coupler employed is n-propyl-p-benzoylacetaminobenzene sulphonate. A two-layer material may have the red-sensitized emulsion described in the first example coated on a transparent support and the green-sensitive emulsion described in the second example as the upper layer. A three-layer material may have the emulsions described in the first, second and third examples coated as the bottom, middle, and top layers. The material may be processed by colour development of the latest images or after rehalogenation of the developed images or may be processed by reversal. P-phenylenediamine developing agents may be used. An energetic colour developer for emulsions with a cellulose acetate propionate binder has 2-amino-5- diethylamirotoluene hydrochloride as the developagent and also includes sodium hydroxide, sodium metaborate and 6-nitrobenzimidazole. The emulsions may be coated on opposite sides of the support. Specifications 408,273 [Group IV], 458,664, 458,665, 474,353, 475,784, 475,786, 478,933, 478,934, 478,942, 478,983, 478,984, 478,985, 478,986, 478,989, 478,990, 478,991, 493,952, 496,196, 496,245, 509,707, and 537,921 also are referred to.
GB33070/39A 1939-01-23 1939-12-29 Improvements in and relating to colour couplers and to colour photographic materialscontaining them Expired GB540368A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB236780X 1939-01-23
GB281239X 1939-12-28
GB291239X 1939-12-29
GB190140X 1940-01-19
GB230240X 1940-02-23

Publications (1)

Publication Number Publication Date
GB540368A true GB540368A (en) 1941-10-15

Family

ID=27516200

Family Applications (2)

Application Number Title Priority Date Filing Date
GB5549/41A Expired GB540525A (en) 1939-01-23 1939-12-29 Improvements in and relating to sensitive photographic materials
GB33070/39A Expired GB540368A (en) 1939-01-23 1939-12-29 Improvements in and relating to colour couplers and to colour photographic materialscontaining them

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB5549/41A Expired GB540525A (en) 1939-01-23 1939-12-29 Improvements in and relating to sensitive photographic materials

Country Status (6)

Country Link
US (4) US2304940A (en)
BE (1) BE440854A (en)
CH (1) CH236780A (en)
FR (3) FR51566E (en)
GB (2) GB540525A (en)
NL (2) NL63641C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2415382A (en) * 1944-03-31 1947-02-04 Du Pont Photographic elements including hydrophilic color formers
US2772163A (en) * 1953-04-17 1956-11-27 Eastman Kodak Co Photographic emulsions containing couplers and hydrosols
US2787544A (en) * 1954-12-20 1957-04-02 Eastman Kodak Co Method of making photographic packet emulsions
US2843489A (en) * 1955-07-29 1958-07-15 Eastman Kodak Co Mixed packet photographic emulsions with polyvinyl resin continuous phase

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2454043A (en) * 1944-04-04 1948-11-16 Ilford Ltd Gelatino-silver halide photographic elements containing higher fatty alcohols
GB585758A (en) * 1944-10-30 1947-02-24 John Alfred Henry Hart Improvements in or relating to the production of photographic emulsions
US2527267A (en) * 1944-10-30 1950-10-24 Ilford Ltd Photographic layers containing gelatin-sulfonic acid complexes, and their preparation
US2527268A (en) * 1944-10-30 1950-10-24 Ilford Ltd Production of photographic emulsions
US2527262A (en) * 1944-10-30 1950-10-24 Ilford Ltd Photographic layers containing gelatin-anion soap complexes and their preparation
US2576850A (en) * 1945-04-26 1951-11-27 Du Pont Gelling of polymeric compounds
US2428208A (en) * 1945-06-20 1947-09-30 Eastman Kodak Co Dichromate bleach bath containing a wetting agent and method of bleaching therewith
US2478400A (en) * 1945-08-17 1949-08-09 Eastman Kodak Co Silver halide photographic emulsion with developer and color coupler dispersed therein
US2534654A (en) * 1946-01-11 1950-12-19 Polaroid Corp Ultraviolet absorbing filter
US2528496A (en) * 1946-04-30 1950-11-07 Chalkley Lyman Photosensitive leucocyanide composition
US2571725A (en) * 1946-08-15 1951-10-16 Eastman Kodak Co Eliminating stain in photographic color material
US2577127A (en) * 1946-11-23 1951-12-04 Du Pont Photographic element with colloid layer containing color former and nonionic wettingagent
US2565418A (en) * 1947-08-13 1951-08-21 Eastman Kodak Co Method of preparing photographic silver halide emulsions
BE484580A (en) * 1947-08-29
BE551312A (en) * 1955-10-01
US2870012A (en) * 1955-12-23 1959-01-20 Eastman Kodak Co Microdispersions of photographic color couplers
GB852922A (en) * 1957-09-04 1960-11-02 Gen Aniline & Film Corp Color formers containing a m-alkylphenoxyacyl group
GB864060A (en) * 1957-11-01 1961-03-29 Gen Aniline & Film Corp Mixed grain photographic emulsions
US3033680A (en) * 1958-01-13 1962-05-08 Eastman Kodak Co Plasticized gelating compositions
CA684233A (en) * 1959-05-25 1964-04-14 C. Haas Howard Photographic products and processes
JPS5448538A (en) * 1977-09-12 1979-04-17 Konishiroku Photo Ind Co Ltd Color photographic material
JPS55129136A (en) * 1979-03-27 1980-10-06 Fuji Photo Film Co Ltd Emulsifying method
JPS56126830A (en) * 1980-03-11 1981-10-05 Konishiroku Photo Ind Co Ltd Silver halide photographic sensitive material
IT1197427B (en) * 1982-05-14 1988-11-30 Gian Franco Menicucci METHOD FORMULATION METHOD FOR DENTAL AND COMPLEX USE OF ALLOYS SO OBTAINED
US4725529A (en) 1985-04-30 1988-02-16 Konishiroku Photo Industry Co., Ltd. Developing inhibitor arrangment in light-sensitive silver halide color photographic materials
EP0204530B1 (en) 1985-05-31 1991-09-11 Konica Corporation Method for forming direct positive color image
AU591540B2 (en) 1985-12-28 1989-12-07 Konishiroku Photo Industry Co., Ltd. Method of processing light-sensitive silver halide color photographic material
US5700608A (en) * 1995-07-31 1997-12-23 Eastman Kodak Company Process for making photographic emulsions and photographic elements and emulsions containing latent image forming units internally containing sensitizing dye

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2415382A (en) * 1944-03-31 1947-02-04 Du Pont Photographic elements including hydrophilic color formers
US2772163A (en) * 1953-04-17 1956-11-27 Eastman Kodak Co Photographic emulsions containing couplers and hydrosols
US2787544A (en) * 1954-12-20 1957-04-02 Eastman Kodak Co Method of making photographic packet emulsions
US2843489A (en) * 1955-07-29 1958-07-15 Eastman Kodak Co Mixed packet photographic emulsions with polyvinyl resin continuous phase

Also Published As

Publication number Publication date
US2304940A (en) 1942-12-15
US2318788A (en) 1943-05-11
US2279406A (en) 1942-04-14
FR57149E (en) 1952-12-15
CH236780A (en) 1945-03-15
BE440854A (en)
FR51566E (en) 1943-02-05
NL65241C (en)
GB540525A (en) 1941-10-20
FR951528A (en) 1949-10-27
US2311020A (en) 1943-02-16
NL63641C (en)

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